Ceramic materials
Encyclopedia
Ceramic materials are inorganic, non-metallic
materials and things made from them. They may be crystalline or partly crystalline. They are formed by the action of heat and subsequent cooling. Clay
was one of the earliest materials used to produce ceramic
s, but many different ceramic materials are now used in domestic, industrial and building products.
material may be defined as any inorganic crystalline oxide material. It is solid and inert. Ceramic materials are brittle, hard, strong in compression, weak in shearing and tension. They withstand chemical erosion that occurs in an acidic or caustic environment. In many cases withstanding erosion from the acid and bases applied to it. Ceramics generally can withstand very high temperatures such as temperatures that range from 1,000 °C to 1,600 °C (1,800 °F to 3,000 °F). Exceptions include inorganic materials that do not have oxygen such as silicon carbide. Glass by definition is not a ceramic because it is an amorphous solid (non-crystalline). However, glass involves several steps of the ceramic process and its mechanical properties behave similarly to ceramic materials.
Traditional ceramic raw materials include clay minerals such as kaolinite, more recent materials include aluminium oxide, more commonly known as alumina. The modern ceramic materials, which are classified as advanced ceramics, include silicon carbide and tungsten carbide. Both are valued for their abrasion resistance, and hence find use in applications such as the wear plates of crushing equipment in mining operations. Advanced ceramics are also used in the medicine, electrical and electronics industries.
to form a solid body. Ceramic forming techniques
include shaping by hand (sometimes including a rotation process called "throwing"), slip casting
, tape casting
(used for making very thin ceramic capacitors, etc.), injection moulding, dry pressing, and other variations. (See also Ceramic forming techniques. Details of these processes are described in the two books listed below.) A few methods use a hybrid between the two approaches.
.
, dielectric constant
, and the optical properties exhibited by transparent materials.
Physical properties of chemical compounds which provide evidence of chemical composition include odor, color, volume, density (mass / volume), melting point, boiling point, heat capacity, physical form at room temperature (solid, liquid or gas), hardness, porosity, and index of refraction.
Ceramography
is the art and science of preparation, examination and evaluation of ceramic microstructures. Evaluation and characterization of ceramic microstructures is often implemented on similar spatial scales to that used commonly in the emerging field of nanotechnology: from tens of angstrom
s (A) to tens of micrometers (µm). This is typically somewhere between the minimum wavelength of visible light and the resolution limit of the naked eye.
The microstructure includes most grains, secondary phases, grain boundaries, pores, micro-cracks, structural defects and hardness microindentions. Most bulk mechanical, optical, thermal, electrical and magnetic properties are significantly affected by the observed microstructure. The fabrication method and process conditions are generally indicated by the microstructure. The root cause of many ceramic failures is evident in the cleaved and polished microstructure. Physical properties which constitute the field of materials science
and engineering
include the following:
of materials such as: elasticity
/ plasticity
, tensile strength
, compressive strength
, shear strength
, fracture toughness
& ductility
(low in brittle
materials), and indentation hardness
.
Fracture mechanics
is the field of mechanics concerned with the study of the formation and subsequent propagation of microcracks in materials. It uses methods of analytical solid mechanics to calculate the thermodynamic driving force on a crack and the methods of experimental solid mechanics to characterize the material's resistance to fracture and catastrophic failure.
In modern materials science
, fracture mechanics is an important tool in improving the mechanical performance of materials and components. It applies the physics
of stress and strain
, in particular the theories of elasticity
and plasticity
, to the microscopic crystallographic defects found in real materials in order to predict the macroscopic mechanical failure of bodies. Fractography
is widely used with fracture mechanics to understand the causes of failures and also verify the theoretical failure
predictions with real life failures.
Thus, since cracks and other microstructural defects can lower the strength of a structure beyond that which might be predicted by the theory of crystalline objects, a different property of the material—above and beyond conventional strength—is needed to describe the fracture resistance of engineering materials. This is the reason for the need for fracture mechanics: the evaluation of the strength of flawed structures.
In this context, Fracture toughness
is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. Fracture toughness is a quantitative way of expressing a material's resistance to brittle
fracture when a crack is present. If a material has a large value of fracture toughness it will probably undergo ductile fracture. Brittle fracture is very characteristic of materials with a low fracture toughness value. Fracture mechanics
, which leads to the concept of fracture toughness, was largely based on the work of A. A. Griffith who, amongst other things, studied the behaviour of cracks in brittle materials.
Ceramic materials are usually ionic
or covalent bonded materials, and can be crystal
line or amorphous
. A material held together by either type of bond will tend to fracture before any plastic deformation takes place, which results in poor toughness
in these materials. Additionally, because these materials tend to be porous, the pore
s and other microscopic imperfections act as stress concentrators
, decreasing the toughness further, and reducing the tensile strength
. These combine to give catastrophic failure
s, as opposed to the normally much more gentle failure mode
s of metals.
These materials do show plastic deformation
. However, due to the rigid structure of the crystalline materials, there are very few available slip systems for dislocation
s to move, and so they deform very slowly. With the non-crystalline (glassy) materials, viscous
flow is the dominant source of plastic deformation, and is also very slow. It is therefore neglected in many applications of ceramic materials.
s. Most of these are transition metal oxides
that are II-VI semiconductors, such as zinc oxide
.
While there are prospects of mass producting blue LED
s from zinc oxide
, ceramicists are most interested in the electrical properties that show grain boundary effects.
One of the most widely used of these is the varistor. These are devices that exhibit the property that resistance drops sharply at a certain threshold voltage
. Once the voltage across the device reaches the threshold, there is a breakdown
of the electrical structure in the vicinity of the grain boundaries
, which results in its electrical resistance
dropping from several megohms down to a few hundred ohms. The major advantage of these is that they can dissipate a lot of energy, and they self reset – after the voltage across the device drops below the threshold, its resistance returns to being high.
This makes them ideal for surge-protection
applications. As there is control over the threshold voltage and energy tolerance, they find use in all sorts of applications. The best demonstration of their ability can be found in electrical substation
s, where they are employed to protect the infrastructure from lightning
strikes. They have rapid response, are low maintenance, and do not appreciably degrade from use, making them virtually ideal devices for this application.
Semiconducting ceramics are also employed as gas sensors. When various gases are passed over a polycrystalline ceramic, its electrical resistance changes. With tuning to the possible gas mixtures, very inexpensive devices can be produced.
, a link between electrical and mechanical response, is exhibited by a large number of ceramic materials, including the quartz used to measure time
in watches and other electronics. Such devices use both properties of piezoelectrics, using electricity to produce a mechanical motion (powering the device) and then using this mechanical motion to produce electricity (generating a signal). The unit of time measured is the natural interval required for electricity to be converted into mechanical energy and back again.
The piezoelectric effect is generally stronger in materials that also exhibit pyroelectricity
, and all pyroelectric materials are also piezoelectric. These materials can be used to inter convert between thermal, mechanical, and/or electrical energy; for instance, after synthesis in a furnace, a pyroelectric crystal allowed to cool under no applied stress generally builds up a static charge of thousands of volts. Such materials are used in motion sensors, where the tiny rise in temperature from a warm body entering the room is enough to produce a measurable voltage in the crystal.
In turn, pyroelectricity is seen most strongly in materials which also display the ferroelectric effect, in which a stable electric dipole can be oriented or reversed by applying an electrostatic field. Pyroelectricity is also a necessary consequence of ferroelectricity. This can be used to store information in ferroelectric capacitor
s, elements of ferroelectric RAM
.
The most common such materials are lead zirconate titanate
and barium titanate
. Aside from the uses mentioned above, their strong piezoelectric response is exploited in the design of high-frequency loudspeaker
s, transducers for sonar
, and actuators for atomic force
and scanning tunneling microscope
s.
titanate
s. The critical transition temperature can be adjusted over a wide range by variations in chemistry. In such materials, current will pass through the material until joule heating
brings it to the transition temperature, at which point the circuit will be broken and current flow will cease. Such ceramics are used as self-controlled heating elements in, for example, the rear-window defrost circuits of automobiles.
At the transition temperature, the material's dielectric
response becomes theoretically infinite. While a lack of temperature control would rule out any practical use of the material near its critical temperature, the dielectric effect remains exceptionally strong even at much higher temperatures. Titanates with critical temperatures far below room temperature have become synonymous with "ceramic" in the context of ceramic capacitors for just this reason.
focus on the response of a material to incoming lightwaves of a range of wavelengths. Frequency selective optical filters can be utilized to alter or enhance the brightness and contrast of a digital image. Guided lightwave transmission via frequency selective waveguides involves the emerging field of fiber optics
and the ability of certain glassy compositions as a transmission medium
for a range of frequencies simultaneously (multi-mode optical fiber
) with little or no interference
between competing wavelengths or frequencies. This resonant mode
of energy
and data transmission
via electromagnetic (light) wave propagation
, though low powered, is virtually lossless. Optical waveguides are used as components in Integrated optical circuits (e.g. light-emitting diodes, LEDs) or as the transmission medium in local and long haul optical communication
systems. Also of value to the emerging materials scientist is the sensitivity of materials to radiation in the thermal infrared
(IR) portion of the electromagnetic spectrum. This heat-seeking ability is responsible for such diverse optical phenomena as Night-vision and IR luminescence
.
Thus, there is an increasing need in the military
sector for high-strength, robust materials which have the capability to transmit light
(electromagnetic waves) in the visible
(0.4 – 0.7 micrometers) and mid-infrared
(1 – 5 micrometers) regions of the spectrum
. These materials are needed for applications requiring transparent
armor, including next-generation high-speed missiles and pods, as well as protection against improvised explosive devices (IED).
In the 1960s, scientists at General Electric (GE) discovered that under the right manufacturing conditions, some ceramics, especially aluminium oxide
(alumina), could be made translucent. These translucent materials were transparent enough to be used for containing the electrical plasma
generated in high-pressure
sodium
street lamps. During the past two decades, additional types of transparent ceramics have been developed for applications such as nose cones for heat-seeking missiles, windows for fighter aircraft
, and scintillation counter
s for computed tomography
scanners
.
In the early 1970s, Thomas Soules pioneered computer modeling of light transmission through translucent ceramic alumina. His model showed that microscopic pores
in ceramic, mainly trapped at the junctions of microcrystalline grains
, caused light to scatter
and prevented true transparency. The volume fraction of these microscopic pores had to be less than 1% for high-quality optical transmission.
This is basically a particle size
effect. Opacity
results from the incoherent scattering of light at surfaces and interfaces
. In addition to pores, most of the interfaces in a typical metal or ceramic object are in the form of grain boundaries which separate tiny regions of crystalline order. When the size of the scattering center (or grain boundary) is reduced below the size of the wavelength of the light being scattered, the scattering no longer occurs to any significant extent.
In the formation of polycrystalline
materials (metals and ceramics) the size of the crystalline grains is determined largely by the size of the crystalline particles present in the raw material during formation (or pressing) of the object. Moreover, the size of the grain boundaries scales directly with particle size. Thus a reduction of the original particle size below the wavelength
of visible light (~ 0.5 micrometers for shortwave violet) eliminates any light scattering
, resulting in a transparent
material.
Recently, Japanese scientists have developed techniques to produce ceramic parts that rival the transparency
of traditional crystals (grown from a single seed) and exceed the fracture toughness
of a single crystal. In particular, scientists at the Japanese firm Konoshima Ltd., a producer of ceramic construction materials and industrial chemicals, have been looking for markets for their transparent ceramics.
Livermore researchers realized that these ceramics might greatly benefit high-powered lasers used in the National Ignition Facility (NIF) Programs Directorate. In particular, a Livermore research team began to acquire advanced transparent ceramics from Konoshima to determine if they could meet the optical requirements needed for Livermore’s Solid-State Heat Capacity Laser (SSHCL). Livermore researchers have also been testing applications of these materials for applications such as advanced drivers for laser-driven fusion
power plants.
, brick
s and tile
s, (2) cement
s and (3) glass
. A composite material
of ceramic and metal
is known as cermet
.
Nonmetal
Nonmetal, or non-metal, is a term used in chemistry when classifying the chemical elements. On the basis of their general physical and chemical properties, every element in the periodic table can be termed either a metal or a nonmetal...
materials and things made from them. They may be crystalline or partly crystalline. They are formed by the action of heat and subsequent cooling. Clay
Clay
Clay is a general term including many combinations of one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are mostly composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure.- Formation :Clay minerals...
was one of the earliest materials used to produce ceramic
Ceramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
s, but many different ceramic materials are now used in domestic, industrial and building products.
Types of ceramic materials
A ceramicCeramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
material may be defined as any inorganic crystalline oxide material. It is solid and inert. Ceramic materials are brittle, hard, strong in compression, weak in shearing and tension. They withstand chemical erosion that occurs in an acidic or caustic environment. In many cases withstanding erosion from the acid and bases applied to it. Ceramics generally can withstand very high temperatures such as temperatures that range from 1,000 °C to 1,600 °C (1,800 °F to 3,000 °F). Exceptions include inorganic materials that do not have oxygen such as silicon carbide. Glass by definition is not a ceramic because it is an amorphous solid (non-crystalline). However, glass involves several steps of the ceramic process and its mechanical properties behave similarly to ceramic materials.
Traditional ceramic raw materials include clay minerals such as kaolinite, more recent materials include aluminium oxide, more commonly known as alumina. The modern ceramic materials, which are classified as advanced ceramics, include silicon carbide and tungsten carbide. Both are valued for their abrasion resistance, and hence find use in applications such as the wear plates of crushing equipment in mining operations. Advanced ceramics are also used in the medicine, electrical and electronics industries.
Crystalline ceramics
Crystalline ceramic materials are not amenable to a great range of processing. Methods for dealing with them tend to fall into one of two categories - either make the ceramic in the desired shape, by reaction in situ, or by "forming" powders into the desired shape, and then sinteringSintering
Sintering is a method used to create objects from powders. It is based on atomic diffusion. Diffusion occurs in any material above absolute zero, but it occurs much faster at higher temperatures. In most sintering processes, the powdered material is held in a mold and then heated to a temperature...
to form a solid body. Ceramic forming techniques
Ceramic forming techniques
Ceramic forming techniques are ways of forming ceramic shapes. This can be used to make everyday tableware from teapots, to engineering ceramics such as computer parts. Methods for forming powders of ceramic raw materials into complex shapes are desirable in many areas of technology...
include shaping by hand (sometimes including a rotation process called "throwing"), slip casting
Slipcasting
Slipcasting is a technique for the mass-production of pottery, especially for shapes not easily made on a wheel. A liquid clay body slip is poured into plaster moulds and allowed to form a layer, the cast, on the inside cavity of the mould...
, tape casting
Tape casting
Tape casting is a casting process used in the manufacture of thin ceramic tapes from ceramic slurry.The tapes thus produced can be used for a variety of purposes, including the manufacture of electronic components such as ceramic capacitors....
(used for making very thin ceramic capacitors, etc.), injection moulding, dry pressing, and other variations. (See also Ceramic forming techniques. Details of these processes are described in the two books listed below.) A few methods use a hybrid between the two approaches.
Non-crystalline ceramics
Non-crystalline ceramics, being glasses, tend to be formed from melts. The glass is shaped when either fully molten, by casting, or when in a state of toffee-like viscosity, by methods such as blowing to a mold. If later heat-treatments cause this glass to become partly crystalline, the resulting material is known as a glass-ceramicGlass-ceramic
Glass-ceramics are polycrystalline material produced through controlled crystallization of base glass. Glass-ceramic materials share many properties with both glasses and ceramics...
.
Properties of ceramics
The physical properties of any ceramic substance are a direct result of its crystalline structure and chemical composition. Solid state chemistry reveals the fundamental connection between microstructure and properties such as localized density variations, grain size distribution, type of porosity and second-phase content, which can all be correlated with ceramic properties such as mechanical strength σ by the Hall-Petch equation, hardness, toughnessToughness
In materials science and metallurgy, toughness is the ability of a material to absorb energy and plastically deform without fracturing; Material toughness is defined as the amount of energy per volume that a material can absorb before rupturing...
, dielectric constant
Dielectric constant
The relative permittivity of a material under given conditions reflects the extent to which it concentrates electrostatic lines of flux. In technical terms, it is the ratio of the amount of electrical energy stored in a material by an applied voltage, relative to that stored in a vacuum...
, and the optical properties exhibited by transparent materials.
Physical properties of chemical compounds which provide evidence of chemical composition include odor, color, volume, density (mass / volume), melting point, boiling point, heat capacity, physical form at room temperature (solid, liquid or gas), hardness, porosity, and index of refraction.
Ceramography
Ceramography
Ceramography is the art and science of preparation, examination and evaluation of ceramic microstructures. Ceramography can be thought of as the metallography of ceramics. The microstructure is the structure level of approximately 0.1 to 100 µm, between the minimum wavelength of visible light and...
is the art and science of preparation, examination and evaluation of ceramic microstructures. Evaluation and characterization of ceramic microstructures is often implemented on similar spatial scales to that used commonly in the emerging field of nanotechnology: from tens of angstrom
Ångström
The angstrom or ångström, is a unit of length equal to 1/10,000,000,000 of a meter . Its symbol is the Swedish letter Å....
s (A) to tens of micrometers (µm). This is typically somewhere between the minimum wavelength of visible light and the resolution limit of the naked eye.
The microstructure includes most grains, secondary phases, grain boundaries, pores, micro-cracks, structural defects and hardness microindentions. Most bulk mechanical, optical, thermal, electrical and magnetic properties are significantly affected by the observed microstructure. The fabrication method and process conditions are generally indicated by the microstructure. The root cause of many ceramic failures is evident in the cleaved and polished microstructure. Physical properties which constitute the field of materials science
Materials science
Materials science is an interdisciplinary field applying the properties of matter to various areas of science and engineering. This scientific field investigates the relationship between the structure of materials at atomic or molecular scales and their macroscopic properties. It incorporates...
and engineering
Engineering
Engineering is the discipline, art, skill and profession of acquiring and applying scientific, mathematical, economic, social, and practical knowledge, in order to design and build structures, machines, devices, systems, materials and processes that safely realize improvements to the lives of...
include the following:
Mechanical properties
Mechanical properties are important in structural and building materials as well as textile fabrics. They include the many properties used to describe the strengthStrength of materials
In materials science, the strength of a material is its ability to withstand an applied stress without failure. The applied stress may be tensile, compressive, or shear. Strength of materials is a subject which deals with loads, deformations and the forces acting on a material. A load applied to a...
of materials such as: elasticity
Elasticity (physics)
In physics, elasticity is the physical property of a material that returns to its original shape after the stress that made it deform or distort is removed. The relative amount of deformation is called the strain....
/ plasticity
Plasticity (physics)
In physics and materials science, plasticity describes the deformation of a material undergoing non-reversible changes of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the...
, tensile strength
Tensile strength
Ultimate tensile strength , often shortened to tensile strength or ultimate strength, is the maximum stress that a material can withstand while being stretched or pulled before necking, which is when the specimen's cross-section starts to significantly contract...
, compressive strength
Compressive strength
Compressive strength is the capacity of a material or structure to withstand axially directed pushing forces. When the limit of compressive strength is reached, materials are crushed. Concrete can be made to have high compressive strength, e.g...
, shear strength
Shear strength
Shear strength in engineering is a term used to describe the strength of a material or component against the type of yield or structural failure where the material or component fails in shear. A shear load is a force that tends to produce a sliding failure on a material along a plane that is...
, fracture toughness
Fracture toughness
In materials science, fracture toughness is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. The fracture toughness of a material is determined from the...
& ductility
Ductility
In materials science, ductility is a solid material's ability to deform under tensile stress; this is often characterized by the material's ability to be stretched into a wire. Malleability, a similar property, is a material's ability to deform under compressive stress; this is often characterized...
(low in brittle
Brittle
A material is brittle if, when subjected to stress, it breaks without significant deformation . Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Breaking is often accompanied by a snapping sound. Brittle materials include most ceramics and glasses ...
materials), and indentation hardness
Indentation hardness
Indentation hardness tests are used to determine the hardness of a material to deformation. Several such tests exist, wherein the examined material is indented until an impression is formed; these tests can be performed on a macroscopic or microscopic scale....
.
Fracture mechanics
Fracture mechanics
Fracture mechanics is the field of mechanics concerned with the study of the propagation of cracks in materials. It uses methods of analytical solid mechanics to calculate the driving force on a crack and those of experimental solid mechanics to characterize the material's resistance to fracture.In...
is the field of mechanics concerned with the study of the formation and subsequent propagation of microcracks in materials. It uses methods of analytical solid mechanics to calculate the thermodynamic driving force on a crack and the methods of experimental solid mechanics to characterize the material's resistance to fracture and catastrophic failure.
In modern materials science
Materials science
Materials science is an interdisciplinary field applying the properties of matter to various areas of science and engineering. This scientific field investigates the relationship between the structure of materials at atomic or molecular scales and their macroscopic properties. It incorporates...
, fracture mechanics is an important tool in improving the mechanical performance of materials and components. It applies the physics
Physics
Physics is a natural science that involves the study of matter and its motion through spacetime, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.Physics is one of the oldest academic...
of stress and strain
Deformation (mechanics)
Deformation in continuum mechanics is the transformation of a body from a reference configuration to a current configuration. A configuration is a set containing the positions of all particles of the body...
, in particular the theories of elasticity
Elasticity (physics)
In physics, elasticity is the physical property of a material that returns to its original shape after the stress that made it deform or distort is removed. The relative amount of deformation is called the strain....
and plasticity
Plasticity (physics)
In physics and materials science, plasticity describes the deformation of a material undergoing non-reversible changes of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the...
, to the microscopic crystallographic defects found in real materials in order to predict the macroscopic mechanical failure of bodies. Fractography
Fractography
Fractography is the study of fracture surfaces of materials. Fractographic methods are routinely used to determine the cause of failure in engineering structures, especially in product failure and the practice of forensic engineering or failure analysis...
is widely used with fracture mechanics to understand the causes of failures and also verify the theoretical failure
Failure
Failure refers to the state or condition of not meeting a desirable or intended objective, and may be viewed as the opposite of success. Product failure ranges from failure to sell the product to fracture of the product, in the worst cases leading to personal injury, the province of forensic...
predictions with real life failures.
Thus, since cracks and other microstructural defects can lower the strength of a structure beyond that which might be predicted by the theory of crystalline objects, a different property of the material—above and beyond conventional strength—is needed to describe the fracture resistance of engineering materials. This is the reason for the need for fracture mechanics: the evaluation of the strength of flawed structures.
In this context, Fracture toughness
Fracture toughness
In materials science, fracture toughness is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. The fracture toughness of a material is determined from the...
is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. Fracture toughness is a quantitative way of expressing a material's resistance to brittle
Brittle
A material is brittle if, when subjected to stress, it breaks without significant deformation . Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Breaking is often accompanied by a snapping sound. Brittle materials include most ceramics and glasses ...
fracture when a crack is present. If a material has a large value of fracture toughness it will probably undergo ductile fracture. Brittle fracture is very characteristic of materials with a low fracture toughness value. Fracture mechanics
Fracture mechanics
Fracture mechanics is the field of mechanics concerned with the study of the propagation of cracks in materials. It uses methods of analytical solid mechanics to calculate the driving force on a crack and those of experimental solid mechanics to characterize the material's resistance to fracture.In...
, which leads to the concept of fracture toughness, was largely based on the work of A. A. Griffith who, amongst other things, studied the behaviour of cracks in brittle materials.
Ceramic materials are usually ionic
Ionic bond
An ionic bond is a type of chemical bond formed through an electrostatic attraction between two oppositely charged ions. Ionic bonds are formed between a cation, which is usually a metal, and an anion, which is usually a nonmetal. Pure ionic bonding cannot exist: all ionic compounds have some...
or covalent bonded materials, and can be crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...
line or amorphous
Amorphous solid
In condensed matter physics, an amorphous or non-crystalline solid is a solid that lacks the long-range order characteristic of a crystal....
. A material held together by either type of bond will tend to fracture before any plastic deformation takes place, which results in poor toughness
Toughness
In materials science and metallurgy, toughness is the ability of a material to absorb energy and plastically deform without fracturing; Material toughness is defined as the amount of energy per volume that a material can absorb before rupturing...
in these materials. Additionally, because these materials tend to be porous, the pore
Porosity
Porosity or void fraction is a measure of the void spaces in a material, and is a fraction of the volume of voids over the total volume, between 0–1, or as a percentage between 0–100%...
s and other microscopic imperfections act as stress concentrators
Stress concentration
A stress concentration is a location in an object where stress is concentrated. An object is strongest when force is evenly distributed over its area, so a reduction in area, e.g. caused by a crack, results in a localized increase in stress...
, decreasing the toughness further, and reducing the tensile strength
Tensile strength
Ultimate tensile strength , often shortened to tensile strength or ultimate strength, is the maximum stress that a material can withstand while being stretched or pulled before necking, which is when the specimen's cross-section starts to significantly contract...
. These combine to give catastrophic failure
Catastrophic failure
A catastrophic failure is a sudden and total failure of some system from which recovery is impossible. Catastrophic failures often lead to cascading systems failure....
s, as opposed to the normally much more gentle failure mode
Failure mode
Failure causes are defects in design, process, quality, or part application, which are the underlying cause of a failure or which initiate a process which leads to failure. Where failure depends on the user of the product or process, then human error must be considered.-Component failure:A part...
s of metals.
These materials do show plastic deformation
Plasticity (physics)
In physics and materials science, plasticity describes the deformation of a material undergoing non-reversible changes of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the...
. However, due to the rigid structure of the crystalline materials, there are very few available slip systems for dislocation
Dislocation
In materials science, a dislocation is a crystallographic defect, or irregularity, within a crystal structure. The presence of dislocations strongly influences many of the properties of materials...
s to move, and so they deform very slowly. With the non-crystalline (glassy) materials, viscous
Viscosity
Viscosity is a measure of the resistance of a fluid which is being deformed by either shear or tensile stress. In everyday terms , viscosity is "thickness" or "internal friction". Thus, water is "thin", having a lower viscosity, while honey is "thick", having a higher viscosity...
flow is the dominant source of plastic deformation, and is also very slow. It is therefore neglected in many applications of ceramic materials.
Semiconductors
Some ceramics are semiconductorSemiconductor
A semiconductor is a material with electrical conductivity due to electron flow intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 103 to 10−8 siemens per centimeter...
s. Most of these are transition metal oxides
Transition metal oxides
Transition metal oxides comprise a class of materials that contain transition elements and oxygen. They include insulators as well as metals. Often the same material may display both types of transport properties, hence a Metal-Insulator transition, obtained by varying either temperature or...
that are II-VI semiconductors, such as zinc oxide
Zinc oxide
Zinc oxide is an inorganic compound with the formula ZnO. It is a white powder that is insoluble in water. The powder is widely used as an additive into numerous materials and products including plastics, ceramics, glass, cement, rubber , lubricants, paints, ointments, adhesives, sealants,...
.
While there are prospects of mass producting blue LED
LEd
LEd is a TeX/LaTeX editing software working under Microsoft Windows. It is a freeware product....
s from zinc oxide
Zinc oxide
Zinc oxide is an inorganic compound with the formula ZnO. It is a white powder that is insoluble in water. The powder is widely used as an additive into numerous materials and products including plastics, ceramics, glass, cement, rubber , lubricants, paints, ointments, adhesives, sealants,...
, ceramicists are most interested in the electrical properties that show grain boundary effects.
One of the most widely used of these is the varistor. These are devices that exhibit the property that resistance drops sharply at a certain threshold voltage
Threshold voltage
The threshold voltage of a MOSFET is usually defined as the gate voltage where an inversion layer forms at the interface between the insulating layer and the substrate of the transistor. The purpose of the inversion layer's forming is to allow the flow of electrons through the gate-source junction...
. Once the voltage across the device reaches the threshold, there is a breakdown
Electrical breakdown
The term electrical breakdown or electric breakdown has several similar but distinctly different meanings. For example, the term can apply to the failure of an electric circuit....
of the electrical structure in the vicinity of the grain boundaries
Grain boundary
A grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material...
, which results in its electrical resistance
Electrical resistance
The electrical resistance of an electrical element is the opposition to the passage of an electric current through that element; the inverse quantity is electrical conductance, the ease at which an electric current passes. Electrical resistance shares some conceptual parallels with the mechanical...
dropping from several megohms down to a few hundred ohms. The major advantage of these is that they can dissipate a lot of energy, and they self reset – after the voltage across the device drops below the threshold, its resistance returns to being high.
This makes them ideal for surge-protection
Surge protector
A surge protector is an appliance designed to protect electrical devices from voltage spikes. A surge protector attempts to limit the voltage supplied to an electric device by either blocking or by shorting to ground any unwanted voltages above a safe threshold...
applications. As there is control over the threshold voltage and energy tolerance, they find use in all sorts of applications. The best demonstration of their ability can be found in electrical substation
Electrical substation
A substation is a part of an electrical generation, transmission, and distribution system. Substations transform voltage from high to low, or the reverse, or perform any of several other important functions...
s, where they are employed to protect the infrastructure from lightning
Lightning
Lightning is an atmospheric electrostatic discharge accompanied by thunder, which typically occurs during thunderstorms, and sometimes during volcanic eruptions or dust storms...
strikes. They have rapid response, are low maintenance, and do not appreciably degrade from use, making them virtually ideal devices for this application.
Semiconducting ceramics are also employed as gas sensors. When various gases are passed over a polycrystalline ceramic, its electrical resistance changes. With tuning to the possible gas mixtures, very inexpensive devices can be produced.
Superconductivity
Under some conditions, such as extremely low temperature, some ceramics exhibit high temperature superconductivity. The exact reason for this is not known, but there are two major families of superconducting ceramics.Ferroelectricity and supersets
PiezoelectricityPiezoelectricity
Piezoelectricity is the charge which accumulates in certain solid materials in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure...
, a link between electrical and mechanical response, is exhibited by a large number of ceramic materials, including the quartz used to measure time
Crystal oscillator
A crystal oscillator is an electronic oscillator circuit that uses the mechanical resonance of a vibrating crystal of piezoelectric material to create an electrical signal with a very precise frequency...
in watches and other electronics. Such devices use both properties of piezoelectrics, using electricity to produce a mechanical motion (powering the device) and then using this mechanical motion to produce electricity (generating a signal). The unit of time measured is the natural interval required for electricity to be converted into mechanical energy and back again.
The piezoelectric effect is generally stronger in materials that also exhibit pyroelectricity
Pyroelectricity
Pyroelectricity is the ability of certain materials to generate a temporary voltage when they are heated or cooled. The change in temperature modifies the positions of the atoms slightly within the crystal structure, such that the polarization of the material changes. This polarization change...
, and all pyroelectric materials are also piezoelectric. These materials can be used to inter convert between thermal, mechanical, and/or electrical energy; for instance, after synthesis in a furnace, a pyroelectric crystal allowed to cool under no applied stress generally builds up a static charge of thousands of volts. Such materials are used in motion sensors, where the tiny rise in temperature from a warm body entering the room is enough to produce a measurable voltage in the crystal.
In turn, pyroelectricity is seen most strongly in materials which also display the ferroelectric effect, in which a stable electric dipole can be oriented or reversed by applying an electrostatic field. Pyroelectricity is also a necessary consequence of ferroelectricity. This can be used to store information in ferroelectric capacitor
Ferroelectric capacitor
Ferroelectric capacitor is a capacitor based on a ferroelectric material. In contrast, traditional capacitors are based on dielectric materials. Ferroelectric devices are used in digital electronics as part of ferroelectric RAM, or in analog electronics as tunable capacitors .In memory...
s, elements of ferroelectric RAM
Ferroelectric RAM
Ferroelectric RAM is a random-access memory similar in construction to DRAM but uses a ferroelectric layer instead of a dielectric layer to achieve non-volatility. FeRAM is one of a growing number of alternative non-volatile memory technologies that offer the same functionality as Flash memory...
.
The most common such materials are lead zirconate titanate
Lead zirconate titanate
Lead zirconate titanate , also called PZT, is a ceramic perovskite material that shows a marked piezoelectric effect. PZT-based compounds are composed of the chemical elements lead and zirconium and the chemical compound titanate which are combined under extremely high temperatures. A filter is...
and barium titanate
Barium titanate
Barium titanate is the inorganic compound with the chemical formula BaTiO3. Barium titanate is a white powder and transparent as larger crystals...
. Aside from the uses mentioned above, their strong piezoelectric response is exploited in the design of high-frequency loudspeaker
Loudspeaker
A loudspeaker is an electroacoustic transducer that produces sound in response to an electrical audio signal input. Non-electrical loudspeakers were developed as accessories to telephone systems, but electronic amplification by vacuum tube made loudspeakers more generally useful...
s, transducers for sonar
Sonar
Sonar is a technique that uses sound propagation to navigate, communicate with or detect other vessels...
, and actuators for atomic force
Atomic force microscope
Atomic force microscopy or scanning force microscopy is a very high-resolution type of scanning probe microscopy, with demonstrated resolution on the order of fractions of a nanometer, more than 1000 times better than the optical diffraction limit...
and scanning tunneling microscope
Scanning tunneling microscope
A scanning tunneling microscope is an instrument for imaging surfaces at the atomic level. Its development in 1981 earned its inventors, Gerd Binnig and Heinrich Rohrer , the Nobel Prize in Physics in 1986. For an STM, good resolution is considered to be 0.1 nm lateral resolution and...
s.
Positive thermal coefficient
Increases in temperature can cause grain boundaries to suddenly become insulating in some semiconducting ceramic materials, mostly mixtures of heavy metalHeavy metals
A heavy metal is a member of a loosely-defined subset of elements that exhibit metallic properties. It mainly includes the transition metals, some metalloids, lanthanides, and actinides. Many different definitions have been proposed—some based on density, some on atomic number or atomic weight,...
titanate
Titanate
In chemistry, titanate usually refers to inorganic compounds composed of titanium oxides. In some cases, the term is used more generally for any titanium-containing anion, e.g. [TiCl6]2- and [Ti7]2-. This article focuses on the oxides....
s. The critical transition temperature can be adjusted over a wide range by variations in chemistry. In such materials, current will pass through the material until joule heating
Joule heating
Joule heating, also known as ohmic heating and resistive heating, is the process by which the passage of an electric current through a conductor releases heat. It was first studied by James Prescott Joule in 1841. Joule immersed a length of wire in a fixed mass of water and measured the temperature...
brings it to the transition temperature, at which point the circuit will be broken and current flow will cease. Such ceramics are used as self-controlled heating elements in, for example, the rear-window defrost circuits of automobiles.
At the transition temperature, the material's dielectric
Dielectric
A dielectric is an electrical insulator that can be polarized by an applied electric field. When a dielectric is placed in an electric field, electric charges do not flow through the material, as in a conductor, but only slightly shift from their average equilibrium positions causing dielectric...
response becomes theoretically infinite. While a lack of temperature control would rule out any practical use of the material near its critical temperature, the dielectric effect remains exceptionally strong even at much higher temperatures. Titanates with critical temperatures far below room temperature have become synonymous with "ceramic" in the context of ceramic capacitors for just this reason.
Optical properties
Optically transparent materialsOptics
Optics is the branch of physics which involves the behavior and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behavior of visible, ultraviolet, and infrared light...
focus on the response of a material to incoming lightwaves of a range of wavelengths. Frequency selective optical filters can be utilized to alter or enhance the brightness and contrast of a digital image. Guided lightwave transmission via frequency selective waveguides involves the emerging field of fiber optics
Optics
Optics is the branch of physics which involves the behavior and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behavior of visible, ultraviolet, and infrared light...
and the ability of certain glassy compositions as a transmission medium
Transmission medium
A transmission medium is a material substance that can propagate energy waves...
for a range of frequencies simultaneously (multi-mode optical fiber
Multi-mode optical fiber
Multi-mode optical fiber is a type of optical fiber mostly used for communication over short distances, such as within a building or on a campus...
) with little or no interference
Adjacent-channel interference
Adjacent-channel interference is interference caused by extraneous power from a signal in an adjacent channel. ACI may be caused by inadequate filtering , improper tuning or poor frequency control .ACI is distinguished from crosstalk.Broadcast...
between competing wavelengths or frequencies. This resonant mode
Normal mode
A normal mode of an oscillating system is a pattern of motion in which all parts of the system move sinusoidally with the same frequency and with a fixed phase relation. The frequencies of the normal modes of a system are known as its natural frequencies or resonant frequencies...
of energy
Energy
In physics, energy is an indirectly observed quantity. It is often understood as the ability a physical system has to do work on other physical systems...
and data transmission
Data transmission
Data transmission, digital transmission, or digital communications is the physical transfer of data over a point-to-point or point-to-multipoint communication channel. Examples of such channels are copper wires, optical fibres, wireless communication channels, and storage media...
via electromagnetic (light) wave propagation
Wave propagation
Wave propagation is any of the ways in which waves travel.With respect to the direction of the oscillation relative to the propagation direction, we can distinguish between longitudinal wave and transverse waves....
, though low powered, is virtually lossless. Optical waveguides are used as components in Integrated optical circuits (e.g. light-emitting diodes, LEDs) or as the transmission medium in local and long haul optical communication
Optical communication
Optical communication is any form of telecommunication that uses light as the transmission medium.An optical communication system consists of a transmitter, which encodes a message into an optical signal, a channel, which carries the signal to its destination, and a receiver, which reproduces the...
systems. Also of value to the emerging materials scientist is the sensitivity of materials to radiation in the thermal infrared
Infrared
Infrared light is electromagnetic radiation with a wavelength longer than that of visible light, measured from the nominal edge of visible red light at 0.74 micrometres , and extending conventionally to 300 µm...
(IR) portion of the electromagnetic spectrum. This heat-seeking ability is responsible for such diverse optical phenomena as Night-vision and IR luminescence
Luminescence
Luminescence is emission of light by a substance not resulting from heat; it is thus a form of cold body radiation. It can be caused by chemical reactions, electrical energy, subatomic motions, or stress on a crystal. This distinguishes luminescence from incandescence, which is light emitted by a...
.
Thus, there is an increasing need in the military
Military
A military is an organization authorized by its greater society to use lethal force, usually including use of weapons, in defending its country by combating actual or perceived threats. The military may have additional functions of use to its greater society, such as advancing a political agenda e.g...
sector for high-strength, robust materials which have the capability to transmit light
Light
Light or visible light is electromagnetic radiation that is visible to the human eye, and is responsible for the sense of sight. Visible light has wavelength in a range from about 380 nanometres to about 740 nm, with a frequency range of about 405 THz to 790 THz...
(electromagnetic waves) in the visible
Visible spectrum
The visible spectrum is the portion of the electromagnetic spectrum that is visible to the human eye. Electromagnetic radiation in this range of wavelengths is called visible light or simply light. A typical human eye will respond to wavelengths from about 390 to 750 nm. In terms of...
(0.4 – 0.7 micrometers) and mid-infrared
Infrared
Infrared light is electromagnetic radiation with a wavelength longer than that of visible light, measured from the nominal edge of visible red light at 0.74 micrometres , and extending conventionally to 300 µm...
(1 – 5 micrometers) regions of the spectrum
Spectrum
A spectrum is a condition that is not limited to a specific set of values but can vary infinitely within a continuum. The word saw its first scientific use within the field of optics to describe the rainbow of colors in visible light when separated using a prism; it has since been applied by...
. These materials are needed for applications requiring transparent
Transparency and translucency
In the field of optics, transparency is the physical property of allowing light to pass through a material; translucency only allows light to pass through diffusely. The opposite property is opacity...
armor, including next-generation high-speed missiles and pods, as well as protection against improvised explosive devices (IED).
In the 1960s, scientists at General Electric (GE) discovered that under the right manufacturing conditions, some ceramics, especially aluminium oxide
Aluminium oxide
Aluminium oxide is an amphoteric oxide with the chemical formula 23. It is commonly referred to as alumina, or corundum in its crystalline form, as well as many other names, reflecting its widespread occurrence in nature and industry...
(alumina), could be made translucent. These translucent materials were transparent enough to be used for containing the electrical plasma
Plasma (physics)
In physics and chemistry, plasma is a state of matter similar to gas in which a certain portion of the particles are ionized. Heating a gas may ionize its molecules or atoms , thus turning it into a plasma, which contains charged particles: positive ions and negative electrons or ions...
generated in high-pressure
Pressure
Pressure is the force per unit area applied in a direction perpendicular to the surface of an object. Gauge pressure is the pressure relative to the local atmospheric or ambient pressure.- Definition :...
sodium
Sodium
Sodium is a chemical element with the symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal and is a member of the alkali metals; its only stable isotope is 23Na. It is an abundant element that exists in numerous minerals, most commonly as sodium chloride...
street lamps. During the past two decades, additional types of transparent ceramics have been developed for applications such as nose cones for heat-seeking missiles, windows for fighter aircraft
Aircraft
An aircraft is a vehicle that is able to fly by gaining support from the air, or, in general, the atmosphere of a planet. An aircraft counters the force of gravity by using either static lift or by using the dynamic lift of an airfoil, or in a few cases the downward thrust from jet engines.Although...
, and scintillation counter
Scintillation counter
A scintillation counter measures ionizing radiation. The sensor, called a scintillator, consists of a transparent crystal, usually phosphor, plastic , or organic liquid that fluoresces when struck by ionizing radiation. A sensitive photomultiplier tube measures the light from the crystal...
s for computed tomography
Tomography
Tomography refers to imaging by sections or sectioning, through the use of any kind of penetrating wave. A device used in tomography is called a tomograph, while the image produced is a tomogram. The method is used in radiology, archaeology, biology, geophysics, oceanography, materials science,...
scanners
Scanners
Scanners is a 1981 science-fiction horror film written and directed by David Cronenberg and starring Jennifer O'Neill, Stephen Lack, Michael Ironside, and Patrick McGoohan...
.
In the early 1970s, Thomas Soules pioneered computer modeling of light transmission through translucent ceramic alumina. His model showed that microscopic pores
Porosity
Porosity or void fraction is a measure of the void spaces in a material, and is a fraction of the volume of voids over the total volume, between 0–1, or as a percentage between 0–100%...
in ceramic, mainly trapped at the junctions of microcrystalline grains
Crystallite
Crystallites are small, often microscopic crystals that, held together through highly defective boundaries, constitute a polycrystalline solid. Metallurgists often refer to crystallites as grains.- Details :...
, caused light to scatter
Scattering
Scattering is a general physical process where some forms of radiation, such as light, sound, or moving particles, are forced to deviate from a straight trajectory by one or more localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of...
and prevented true transparency. The volume fraction of these microscopic pores had to be less than 1% for high-quality optical transmission.
This is basically a particle size
Particle size (grain size)
Particle size, also called grain size, refers to the diameter of individual grains of sediment, or the lithified particles in clastic rocks. The term may also be applied to other granular materials. This is different from the crystallite size, which is the size of a single crystal inside the...
effect. Opacity
Opacity (optics)
Opacity is the measure of impenetrability to electromagnetic or other kinds of radiation, especially visible light. In radiative transfer, it describes the absorption and scattering of radiation in a medium, such as a plasma, dielectric, shielding material, glass, etc...
results from the incoherent scattering of light at surfaces and interfaces
Interface (chemistry)
An interface is a surface forming a common boundary among two different phases, such as an insoluble solid and a liquid, two immiscible liquids or a liquid and an insoluble gas. The importance of the interface depends on which type of system is being treated: the bigger the quotient area/volume,...
. In addition to pores, most of the interfaces in a typical metal or ceramic object are in the form of grain boundaries which separate tiny regions of crystalline order. When the size of the scattering center (or grain boundary) is reduced below the size of the wavelength of the light being scattered, the scattering no longer occurs to any significant extent.
In the formation of polycrystalline
Polycrystalline
Polycrystalline materials are solids that are composed of many crystallites of varying size and orientation. The variation in direction can be random or directed, possibly due to growth and processing conditions. Fiber texture is an example of the latter.Almost all common metals, and many ceramics...
materials (metals and ceramics) the size of the crystalline grains is determined largely by the size of the crystalline particles present in the raw material during formation (or pressing) of the object. Moreover, the size of the grain boundaries scales directly with particle size. Thus a reduction of the original particle size below the wavelength
Wavelength
In physics, the wavelength of a sinusoidal wave is the spatial period of the wave—the distance over which the wave's shape repeats.It is usually determined by considering the distance between consecutive corresponding points of the same phase, such as crests, troughs, or zero crossings, and is a...
of visible light (~ 0.5 micrometers for shortwave violet) eliminates any light scattering
Scattering
Scattering is a general physical process where some forms of radiation, such as light, sound, or moving particles, are forced to deviate from a straight trajectory by one or more localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of...
, resulting in a transparent
Transparency and translucency
In the field of optics, transparency is the physical property of allowing light to pass through a material; translucency only allows light to pass through diffusely. The opposite property is opacity...
material.
Recently, Japanese scientists have developed techniques to produce ceramic parts that rival the transparency
Transparency and translucency
In the field of optics, transparency is the physical property of allowing light to pass through a material; translucency only allows light to pass through diffusely. The opposite property is opacity...
of traditional crystals (grown from a single seed) and exceed the fracture toughness
Fracture toughness
In materials science, fracture toughness is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. The fracture toughness of a material is determined from the...
of a single crystal. In particular, scientists at the Japanese firm Konoshima Ltd., a producer of ceramic construction materials and industrial chemicals, have been looking for markets for their transparent ceramics.
Livermore researchers realized that these ceramics might greatly benefit high-powered lasers used in the National Ignition Facility (NIF) Programs Directorate. In particular, a Livermore research team began to acquire advanced transparent ceramics from Konoshima to determine if they could meet the optical requirements needed for Livermore’s Solid-State Heat Capacity Laser (SSHCL). Livermore researchers have also been testing applications of these materials for applications such as advanced drivers for laser-driven fusion
Nuclear fusion
Nuclear fusion is the process by which two or more atomic nuclei join together, or "fuse", to form a single heavier nucleus. This is usually accompanied by the release or absorption of large quantities of energy...
power plants.
Examples of ceramics materials
Until the 1950s, the most important ceramic materials were (1) potteryPottery
Pottery is the material from which the potteryware is made, of which major types include earthenware, stoneware and porcelain. The place where such wares are made is also called a pottery . Pottery also refers to the art or craft of the potter or the manufacture of pottery...
, brick
Brick
A brick is a block of ceramic material used in masonry construction, usually laid using various kinds of mortar. It has been regarded as one of the longest lasting and strongest building materials used throughout history.-History:...
s and tile
Tile
A tile is a manufactured piece of hard-wearing material such as ceramic, stone, metal, or even glass. Tiles are generally used for covering roofs, floors, walls, showers, or other objects such as tabletops...
s, (2) cement
Cement
In the most general sense of the word, a cement is a binder, a substance that sets and hardens independently, and can bind other materials together. The word "cement" traces to the Romans, who used the term opus caementicium to describe masonry resembling modern concrete that was made from crushed...
s and (3) glass
Glass
Glass is an amorphous solid material. Glasses are typically brittle and optically transparent.The most familiar type of glass, used for centuries in windows and drinking vessels, is soda-lime glass, composed of about 75% silica plus Na2O, CaO, and several minor additives...
. A composite material
Composite material
Composite materials, often shortened to composites or called composition materials, are engineered or naturally occurring materials made from two or more constituent materials with significantly different physical or chemical properties which remain separate and distinct at the macroscopic or...
of ceramic and metal
Metal
A metal , is an element, compound, or alloy that is a good conductor of both electricity and heat. Metals are usually malleable and shiny, that is they reflect most of incident light...
is known as cermet
Cermet
A cermet is a composite material composed of ceramic and metallic materials. A cermet is ideally designed to have the optimal properties of both a ceramic, such as high temperature resistance and hardness, and those of a metal, such as the ability to undergo plastic deformation. The metal is used...
.
- Barium titanateBarium titanateBarium titanate is the inorganic compound with the chemical formula BaTiO3. Barium titanate is a white powder and transparent as larger crystals...
(often mixed with strontium titanateStrontium titanateStrontium titanate is an oxide of strontium and titanium with the chemical formula SrTiO3. At room temperature, it is a centrosymmetric paraelectric material with a perovskite structure...
) displays ferroelectricityFerroelectricityFerroelectricity is a property of certain materials which possess a spontaneous electric polarization that can be reversed by the application of an external electric field. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was...
, meaning that its mechanical, electrical, and thermal responses are coupled to one another and also history-dependent. It is widely used in electromechanicalElectromechanicsIn engineering, electromechanics combines the sciences of electromagnetism, of electrical engineering and mechanics. Mechanical engineering in this context refers to the larger discipline which includes chemical engineering, and other related disciplines. Electrical engineering in this context...
transducerTransducerA transducer is a device that converts one type of energy to another. Energy types include electrical, mechanical, electromagnetic , chemical, acoustic or thermal energy. While the term transducer commonly implies the use of a sensor/detector, any device which converts energy can be considered a...
s, ceramic capacitorCapacitorA capacitor is a passive two-terminal electrical component used to store energy in an electric field. The forms of practical capacitors vary widely, but all contain at least two electrical conductors separated by a dielectric ; for example, one common construction consists of metal foils separated...
s, and data storageFerroelectric RAMFerroelectric RAM is a random-access memory similar in construction to DRAM but uses a ferroelectric layer instead of a dielectric layer to achieve non-volatility. FeRAM is one of a growing number of alternative non-volatile memory technologies that offer the same functionality as Flash memory...
elements. Grain boundaryCrystalliteCrystallites are small, often microscopic crystals that, held together through highly defective boundaries, constitute a polycrystalline solid. Metallurgists often refer to crystallites as grains.- Details :...
conditions can create PTC effects in heating elementHeating elementA heating element converts electricity into heat through the process of Joule heating. Electric current through the element encounters resistance, resulting in heating of the element....
s. - Bismuth strontium calcium copper oxideBismuth strontium calcium copper oxideBismuth strontium calcium copper oxide, or BSCCO , is a family of high-temperature superconductors having the generalized chemical formula Bi2Sr2Can-1CunO2n+4+x, with n=2 being the most commonly studied compound...
, a high-temperature superconductor - Boron nitrideBoron nitrideBoron nitride is a chemical compound with chemical formula BN, consisting of equal numbers of boron and nitrogen atoms. BN is isoelectronic to a similarly structured carbon lattice and thus exists in various crystalline forms...
is structurally isoelectronic to carbon and takes on similar physical forms: a graphiteGraphiteThe mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Ancient Greek γράφω , "to draw/write", for its use in pencils, where it is commonly called lead . Unlike diamond , graphite is an electrical conductor, a semimetal...
-like one used as a lubricantLubricantA lubricant is a substance introduced to reduce friction between moving surfaces. It may also have the function of transporting foreign particles and of distributing heat...
, and a diamondDiamondIn mineralogy, diamond is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions...
-like one used as an abrasive. - EarthenwareEarthenwareEarthenware is a common ceramic material, which is used extensively for pottery tableware and decorative objects.-Types of earthenware:Although body formulations vary between countries and even between individual makers, a generic composition is 25% ball clay, 28% kaolin, 32% quartz, and 15%...
used for domestic ware such as plates and mugs. - FerriteFerrite (magnet)Ferrites are chemical compounds consisting of ceramic materials with iron oxide as their principal component. Many of them are magnetic materials and they are used to make permanent magnets, ferrite cores for transformers, and in various other applications.Many ferrites are spinels with the...
is used in the magnetic coreMagnetic coreA magnetic core is a piece of magnetic material with a high permeability used to confine and guide magnetic fields in electrical, electromechanical and magnetic devices such as electromagnets, transformers, electric motors, inductors and magnetic assemblies. It is made of ferromagnetic metal such...
s of electrical transformerTransformerA transformer is a device that transfers electrical energy from one circuit to another through inductively coupled conductors—the transformer's coils. A varying current in the first or primary winding creates a varying magnetic flux in the transformer's core and thus a varying magnetic field...
s and magnetic core memoryMagnetic core memoryMagnetic-core memory was the predominant form of random-access computer memory for 20 years . It uses tiny magnetic toroids , the cores, through which wires are threaded to write and read information. Each core represents one bit of information...
. - Lead zirconate titanateLead zirconate titanateLead zirconate titanate , also called PZT, is a ceramic perovskite material that shows a marked piezoelectric effect. PZT-based compounds are composed of the chemical elements lead and zirconium and the chemical compound titanate which are combined under extremely high temperatures. A filter is...
(PZT) was developed at the United StatesUnited StatesThe United States of America is a federal constitutional republic comprising fifty states and a federal district...
National Bureau of StandardsNational Institute of Standards and TechnologyThe National Institute of Standards and Technology , known between 1901 and 1988 as the National Bureau of Standards , is a measurement standards laboratory, otherwise known as a National Metrological Institute , which is a non-regulatory agency of the United States Department of Commerce...
in 1954. PZT is used as an ultrasonic transducerUltrasonic sensorUltrasonic sensors work on a principle similar to radar or sonar which evaluate attributes of a target by interpreting the echoes from radio or sound waves respectively. Ultrasonic sensors generate high frequency sound waves and evaluate the echo which is received back by the sensor...
, as its piezoelectric properties greatly exceed those of Rochelle salt. - Magnesium diborideMagnesium diborideMagnesium diboride is a simple ionic binary compound that has proven to be an inexpensive and useful superconducting material.Its superconductivity was announced in the journal Nature in March 2001. Its critical temperature of is the highest amongst conventional superconductors...
(MgMagnesiumMagnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...
B2) is an unconventional superconductorUnconventional superconductorUnconventional superconductors are materials that display superconductivity which does not conform to either the conventional BCS theory or the Nikolay Bogolyubov's theory or its extensions....
. - PorcelainPorcelainPorcelain is a ceramic material made by heating raw materials, generally including clay in the form of kaolin, in a kiln to temperatures between and...
is used for a wide range of household and industrial products. - SialonSialonSialon ceramics are a specialist class of high temperature refractory materials, with high strength , good thermal shock resistance and exceptional resistance to wetting or corrosion by molten non-ferrous metals, compared to other refractory materials such as, for example, alumina. A typical use...
(Silicon Aluminium Oxynitride) has high strength; high thermal, shock, chemical and wear resistance, and low density. These ceramics are used in non-ferrous molten metal handling, weld pins and the chemical industry. - Silicon carbideSilicon carbideSilicon carbide , also known as carborundum, is a compound of silicon and carbon with chemical formula SiC. It occurs in nature as the extremely rare mineral moissanite. Silicon carbide powder has been mass-produced since 1893 for use as an abrasive...
(SiC) is used as a susceptorSusceptorA susceptor is a material used for its ability to absorb electromagnetic energy and convert it to heat . This energy is typically radiofrequency or microwave radiation used in industrial heating processes, and also occasionally in microwave cooking...
in microwave furnaces, a commonly used abrasive, and as a refractoryRefraction (metallurgy)In metallurgy, refraction is a property of metals that indicates their ability to withstand heat. Metals with a high degree of refraction are referred to as refractory. These metals derive their high melting points from their strong intermolecular forces...
material. - Silicon nitrideSilicon nitrideSilicon nitride is a chemical compound of silicon and nitrogen. If powdered silicon is heated between 1300° and 1400°C in an atmosphere of nitrogen, trisilicon tetranitride, Si3N4, is formed. The silicon sample weight increases progressively due to the chemical combination of silicon and nitrogen...
(Si3NNitrogenNitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...
4) is used as an abrasiveAbrasiveAn abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away...
powder. - Steatite (magnesium silicates) is used as an electrical insulator.
- Titanium carbideTitanium carbideTitanium carbide, TiC, is an extremely hard refractory ceramic material, similar to tungsten carbide.It is commercially used in tool bits. It has the appearance of black powder with NaCl-type face centered cubic crystal structure...
Used in space shuttle re-entry shields and scratchproof watches. - Uranium oxideUranium oxideUranium oxide is an oxide of the element uranium.The metal uranium forms several oxides:* Uranium dioxide or uranium oxide * Uranium trioxide or uranium oxide...
(UUraniumUranium is a silvery-white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons...
O2), used as fuelNuclear fuelNuclear fuel is a material that can be 'consumed' by fission or fusion to derive nuclear energy. Nuclear fuels are the most dense sources of energy available...
in nuclear reactorNuclear reactorA nuclear reactor is a device to initiate and control a sustained nuclear chain reaction. Most commonly they are used for generating electricity and for the propulsion of ships. Usually heat from nuclear fission is passed to a working fluid , which runs through turbines that power either ship's...
s. - Yttrium barium copper oxideYttrium barium copper oxideYttrium barium copper oxide, often abbreviated YBCO, is a crystalline chemical compound with the formula YBa2Cu3O7. This material, a famous "high-temperature superconductor", achieved prominence because it was the first material to achieve superconductivity above the boiling point of liquid...
(YBaBariumBarium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...
2CuCopperCopper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
3OOxygenOxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
7-x), another high temperature superconductorSuperconductivitySuperconductivity is a phenomenon of exactly zero electrical resistance occurring in certain materials below a characteristic temperature. It was discovered by Heike Kamerlingh Onnes on April 8, 1911 in Leiden. Like ferromagnetism and atomic spectral lines, superconductivity is a quantum...
. - Zinc oxideZinc oxideZinc oxide is an inorganic compound with the formula ZnO. It is a white powder that is insoluble in water. The powder is widely used as an additive into numerous materials and products including plastics, ceramics, glass, cement, rubber , lubricants, paints, ointments, adhesives, sealants,...
(ZnZincZinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...
O), which is a semiconductorSemiconductorA semiconductor is a material with electrical conductivity due to electron flow intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 103 to 10−8 siemens per centimeter...
, and used in the construction of varistorVaristorA varistor is an electronic component with a "diode-like" nonlinear current–voltage characteristic. The name is a portmanteau of variable resistor...
s. - Zirconium dioxideZirconium dioxideZirconium dioxide , sometimes known as zirconia , is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the rare mineral baddeleyite. The high temperature cubic crystalline form is rarely found in nature as mineral tazheranite O2...
(zirconia), which in pure form undergoes many phase changes between room temperature and practical sinteringSinteringSintering is a method used to create objects from powders. It is based on atomic diffusion. Diffusion occurs in any material above absolute zero, but it occurs much faster at higher temperatures. In most sintering processes, the powdered material is held in a mold and then heated to a temperature...
temperatures, can be chemically "stabilized" in several different forms. Its high oxygen ion conductivity recommends it for use in fuel cellFuel cellA fuel cell is a device that converts the chemical energy from a fuel into electricity through a chemical reaction with oxygen or another oxidizing agent. Hydrogen is the most common fuel, but hydrocarbons such as natural gas and alcohols like methanol are sometimes used...
s and automotive oxygen sensorOxygen sensorAn oxygen sensor, or lambda sensor, is an electronic device that measures the proportion of oxygen in the gas or liquid being analyzed. It was developed by the Robert Bosch GmbH company during the late 1960s under the supervision of Dr. Günter Bauman...
s. In another variant, metastable structures can impart transformation tougheningFracture toughnessIn materials science, fracture toughness is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. The fracture toughness of a material is determined from the...
for mechanical applications; most ceramic knifeCeramic knifeA ceramic knife is a knife made out of very hard and tough ceramic, often zirconium dioxide . These knives are usually produced by dry pressing zirconia powder and firing them through solid-state sintering. The resultant blade is sharpened by grinding the edges with a diamond-dust-coated grinding...
blades are made of this material. - Partially stabilised zirconia (PSZ) is much less brittle than other ceramics and is used for metal forming tools, valves and liners, abrasive slurries, kitchen knives and bearings subject to severe abrasion.
See also
- CeramicCeramicA ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
- Ceramic artCeramic artIn art history, ceramics and ceramic art mean art objects such as figures, tiles, and tableware made from clay and other raw materials by the process of pottery. Some ceramic products are regarded as fine art, while others are regarded as decorative, industrial or applied art objects, or as...
- Ceramic engineeringCeramic engineeringCeramic engineering is the science and technology of creating objects from inorganic, non-metallic materials. This is done either by the action of heat, or at lower temperatures using precipitation reactions from high purity chemical solutions...
- Ceramic Matrix CompositeCeramic Matrix CompositeCeramic matrix composites are a subgroup of composite materials as well as a subgroup of technical ceramics. They consist of ceramic fibers embedded in a ceramic matrix, thus forming a ceramic fiber reinforced ceramic material...
- Ceramics processing
- ColloidColloidA colloid is a substance microscopically dispersed evenly throughout another substance.A colloidal system consists of two separate phases: a dispersed phase and a continuous phase . A colloidal system may be solid, liquid, or gaseous.Many familiar substances are colloids, as shown in the chart below...
- Colloidal crystalColloidal crystalA colloidal crystal is an ordered array of colloid particles, analogous to a standard crystal whose repeating subunits are atoms or molecules. A natural example of this phenomenon can be found in the gem opal, where spheres of silica assume a close-packed locally periodic structure under moderate...
- NanotechnologyNanotechnologyNanotechnology is the study of manipulating matter on an atomic and molecular scale. Generally, nanotechnology deals with developing materials, devices, or other structures possessing at least one dimension sized from 1 to 100 nanometres...
- NanomaterialsNanomaterialsNanomaterials is a field that takes a materials science-based approach to nanotechnology. It studies materials with morphological features on the nanoscale, and especially those that have special properties stemming from their nanoscale dimensions...
- NanoparticleNanoparticleIn nanotechnology, a particle is defined as a small object that behaves as a whole unit in terms of its transport and properties. Particles are further classified according to size : in terms of diameter, coarse particles cover a range between 10,000 and 2,500 nanometers. Fine particles are sized...
- Photonic crystalPhotonic crystalPhotonic crystals are periodic optical nanostructures that are designed to affect the motion of photons in a similar way that periodicity of a semiconductor crystal affects the motion of electrons...
- Sol-gel
- Thin-film opticsThin-film opticsThin-film optics is the branch of optics that deals with very thin structured layers of different materials. In order to exhibit thin-film optics, the thickness of the layers of material must be on the order of the wavelengths of visible light...
- Transparency and translucencyTransparency and translucencyIn the field of optics, transparency is the physical property of allowing light to pass through a material; translucency only allows light to pass through diffusely. The opposite property is opacity...
Further reading
- Greskovich, G., et al., Polycrystalline Ceramic Lasers, J. Appl. Phys., Vol. 44, p. 4599 (1973)
- Yoldas, B.E. Monolithic Glass Formation by Chemical Polymerization, J. Mater. Sci., Vol.10, p. 1856 (1975), Deposition and Properties of Optical Oxide Coatings from Polymerized Solutions, Applied Optics, Vol. 21, p. 2960 (1982), An Aqueous Sol–Gel Route to Prepare Transparent Hybrid Materials, J. Mater. Chem., Vol. 17, p. 4430 (2007)
- Ikesue, A., et al., Fabrication and Optical Properties of High Performance Polycrystalline Ceramics of Solid State Lasers, J. Am. Ceram. Soc, Vol. 78, p. 1033 (1995), Polycrystalline Lasers, Optical Materials, Vol. 19, p. 183 (2002)
- Tachiwaki, T., et al., Novel Synthesis of YAG leading to Transparent Ceramics, Solid State Communications, Vol. 119, p. 603 (2001)
- Rabinovitch, Y., et al., Transparent Polycrystalline Neodymium-Doped YAG, Optical Materials, Vol.24, p. 345 (2003)
- Wen, L.,et al., Synthesis of Nanocrystalline Yttria Powder and Fabrication of Transparent YAG Ceramics, J. European Ceramic Soc., Vol. 24, p. 2681, (2004)
- Pradhan, A.K., et al., Synthesis of Neodymium-doped YAG Nanocrystlalline Powders Leading to Transparent Ceramics, Materials Research Bulletin, Vol. 39, p. 1291 (2004)
- Jiang, H., et al., Transparent Electro-Optic Ceramics and Devices, Proc. SPIE, Vol. 5644, p. 380 (2005), www.bostonati.com/whitepapers/SPIE04paper.pdf
- Huie, J.C. and Gentilman, R., Characterization of Transparent Polycrystalline YAG Fabricated from Nanopowders, Window and Dome Technologies and Materials IX, Proc. SPIE, Vol. 5786, p. 251 (2005)
- Barnakov, Yu. A., et al., Simple Route to Nd:YAG Transparent Ceramics, Materials Research Bulletin, Vol. 35, p. 238 (2006)
- Barnakov, Y.A., et al., The Progress Towards Transparent Ceramics Fabrication, Proc. SPIE, Vol. 6552, p. 111 (2007)
- Yamashita, I., et al., Transparent Ceramics, J. Am. Ceram. Soc., Vol. 91, p. 813 (2008)
- M.W. Barsoum, Fundamentals of Ceramics, McGraw-Hill Co., Inc., 1997, ISBN 978-0070055216.
- W.D. Kingery, H.K. Bowen and D.R. Uhlmann, Introduction to Ceramics, John Wiley & Sons, Inc., 1976, ISBN 0-471-47860-1.
- M.N. Rahaman, Ceramic Processing and Sintering, 2nd Ed., Marcel Dekker Inc., 2003, ISBN 0-8247-0988-8.
- J.S. Reed, Introduction to the Principles of Ceramic Processing, John Wiley & Sons, Inc., 1988, ISBN 0-471-84554-X.
- D.W. Richerson, Modern Ceramic Engineering, 2nd Ed., Marcel Dekker Inc., 1992, ISBN 0-8247-8634-3.
- Onoda, G.Y., Hench, L.L. Eds., Ceramic Processing Before Firing, Wiley & Sons, New York (1979)
External links
- Advanced Ceramics – The Evolution, Classification, Properties, Production, Firing, Finishing and Design of Advanced Ceramics
- Introduction, Scientific Principles, Properties and Processing of Ceramics
- The American Ceramic Society
- CERAM Research Ltd (formerly The British Ceramic Research Association)
- Worldwide Ceramics Directory
- How pottery is made
- How sanitaryware is made