Zirconium dioxide
Overview
 
Zirconium dioxide sometimes known as zirconia (not to be confused with zircon
Zircon
Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is 1–x4x–y...

), is a white crystalline oxide
Oxide
An oxide is a chemical compound that contains at least one oxygen atom in its chemical formula. Metal oxides typically contain an anion of oxygen in the oxidation state of −2....

 of zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...

. Its most naturally occurring form, with a monoclinic crystalline structure, is the rare mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

 baddeleyite
Baddeleyite
Baddeleyite is a rare zirconium oxide mineral , occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. Baddeleyite is a refractory mineral, with a melting point of...

. The high temperature cubic
Cubic crystal system
In crystallography, the cubic crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals....

 crystalline form is rarely found in nature as mineral tazheranite (Zr,Ti,Ca)O2 (and a doubtful mineral arkelite). This form, also called cubic zirconia
Cubic zirconia
Cubic zirconia is the cubic crystalline form of zirconium dioxide . The synthesized material is hard, optically flawless and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zirconium silicate...

, is synthesized in various colours for use as a gemstone
Gemstone
A gemstone or gem is a piece of mineral, which, in cut and polished form, is used to make jewelry or other adornments...

 and a diamond simulant
Diamond simulant
The high price of gem-grade diamonds, as well as significant ethical concerns of the diamond trade, have created a large demand for materials with similar gemological characteristics, known as diamond simulants or imitations. Simulants are distinct from synthetic diamond, which unlike simulants is...

.
Zirconium dioxide is one of the most studied ceramic
Ceramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...

 materials.
 
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