Lead zirconate titanate
Encyclopedia
Lead zirconate titanate (Pb
[ ] 0≤x≤1), also called PZT, is a ceramic
perovskite
material that shows a marked piezoelectric effect
. PZT-based compounds are composed of the chemical elements lead
and zirconium
and the chemical compound titanate
which are combined under extremely high temperatures. A filter is then used to remove the particulates
. PZT-based compounds are used in the manufacturing of ultrasound
transducer
s, in the manufacturing of ceramic
capacitor
s, STM
/AFM actuators (tubes), and the like.
PZT was developed by Yutaka Takagi, Gen Shirane and Etsuro Sawaguchi, physicists
at the Tokyo Institute of Technology
, around 1952.
PZT is a hazardous material, registered as CAS registry number
, EC-No
235-727-4, and
.
Being piezoelectric
, it develops a voltage
(or potential difference) across two of its faces when compressed (useful for sensor applications), or physically changes shape when an external electric field is applied (useful for actuator applications).
The dielectric constant of PZT can range from 300 to 3850 depending upon orientation and doping.
Being pyroelectric, this material develops a voltage difference across two of its faces when it experiences a temperature change. As a result, it can be used as a sensor for detecting heat.
It is also ferroelectric
, which means it has a spontaneous electric polarization
(electric dipole
) which can be reversed in the presence of an electric field.
The material features an extremely large dielectric constant
at the morphotropic phase boundary (MPB) near x = 0.52.
transducer
s and other sensor
s and actuator
s, as well as high-value ceramic capacitor
s and FRAM
chips. PZT is also used in the manufacture of ceramic resonator
s for reference timing in electronic circuitry. In 1975 Sandia National Laboratories
was working on anti-flash goggles to protect aircrew from burns and blindness in case of a nuclear explosion. The PLZT lenses could turn opaque in less than 150 microseconds.
Commercially, it is usually not used in its pure form, rather it is doped
with either acceptor dopants, which create oxygen (anion) vacancies, or donor dopants, which create metal (cation) vacancies and facilitate domain wall motion in the material. In general, acceptor doping creates hard PZT while donor doping creates soft PZT. Hard and soft PZT's generally differ in their piezoelectric constants. Piezoelectric constants are proportional to the polarization or to the electrical field generated per unit of mechanical stress, or alternatively is the mechanical strain produced by per unit of electric field applied. In general, soft PZT has a higher piezoelectric constant, but larger losses in the material due to internal friction. In hard PZT, domain wall motion is pinned by the impurities thereby lowering the losses in the material, but at the expense of a reduced piezoelectric constant.
. The increased piezoelectric response and poling efficiency near to x = 0.52 is due to the increased number of allowable domain states at the MPB. At this boundary, the 6 possible domain states from the tetragonal phase <100> and the 8 possible domain states from the rhombohedral phase <111> are equally favorable energetically, thereby allowing a maximum 14 possible domain states.
Like structurally similar lead scandium tantalate
and barium strontium titanate, PZT can be used for manufacture of uncooled staring array infrared imaging sensors for thermographic camera
s. Both thin film
(usually obtained by chemical vapor deposition
) and bulk structures are used. The formula of the material used usually approaches Pb1.1(Zr0.3Ti0.7)O3 (called PZT 30/70). Its properties may be modified by doping it with lanthanum
, resulting in lanthanum-doped lead zirconate titanate (PLZT, also called lead lanthanum zirconate titanate), with formula Pb0.83La0.17(Zr0.3Ti0.7)0.9575O3 (PLZT 17/30/70).
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
Ceramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
perovskite
Perovskite
A perovskite structure is any material with the same type of crystal structure as calcium titanium oxide , known as the perovskite structure, or XIIA2+VIB4+X2−3 with the oxygen in the face centers. Perovskites take their name from this compound, which was first discovered in the Ural mountains of...
material that shows a marked piezoelectric effect
Piezoelectricity
Piezoelectricity is the charge which accumulates in certain solid materials in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure...
. PZT-based compounds are composed of the chemical elements lead
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
and zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...
and the chemical compound titanate
Titanate
In chemistry, titanate usually refers to inorganic compounds composed of titanium oxides. In some cases, the term is used more generally for any titanium-containing anion, e.g. [TiCl6]2- and [Ti7]2-. This article focuses on the oxides....
which are combined under extremely high temperatures. A filter is then used to remove the particulates
Particulates
Particulates – also known as particulate matter , suspended particulate matter , fine particles, and soot – are tiny subdivisions of solid matter suspended in a gas or liquid. In contrast, aerosol refers to particles and/or liquid droplets and the gas together. Sources of particulate matter can be...
. PZT-based compounds are used in the manufacturing of ultrasound
Ultrasound
Ultrasound is cyclic sound pressure with a frequency greater than the upper limit of human hearing. Ultrasound is thus not separated from "normal" sound based on differences in physical properties, only the fact that humans cannot hear it. Although this limit varies from person to person, it is...
transducer
Transducer
A transducer is a device that converts one type of energy to another. Energy types include electrical, mechanical, electromagnetic , chemical, acoustic or thermal energy. While the term transducer commonly implies the use of a sensor/detector, any device which converts energy can be considered a...
s, in the manufacturing of ceramic
Ceramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
capacitor
Capacitor
A capacitor is a passive two-terminal electrical component used to store energy in an electric field. The forms of practical capacitors vary widely, but all contain at least two electrical conductors separated by a dielectric ; for example, one common construction consists of metal foils separated...
s, STM
Scanning tunneling microscope
A scanning tunneling microscope is an instrument for imaging surfaces at the atomic level. Its development in 1981 earned its inventors, Gerd Binnig and Heinrich Rohrer , the Nobel Prize in Physics in 1986. For an STM, good resolution is considered to be 0.1 nm lateral resolution and...
/AFM actuators (tubes), and the like.
PZT was developed by Yutaka Takagi, Gen Shirane and Etsuro Sawaguchi, physicists
Physics
Physics is a natural science that involves the study of matter and its motion through spacetime, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.Physics is one of the oldest academic...
at the Tokyo Institute of Technology
Tokyo Institute of Technology
The Tokyo Institute of Technology is a public research university located in Greater Tokyo Area, Japan. Tokyo Tech is the largest institution for higher education in Japan dedicated to science and technology. Tokyo Tech enrolled 4,850 undergaraduates and 5006 graduate students for 2009-2010...
, around 1952.
PZT is a hazardous material, registered as CAS registry number
CAS registry number
CAS Registry Numbersare unique numerical identifiers assigned by the "Chemical Abstracts Service" toevery chemical described in the...
, EC-No
EC-No
The European Commission number, or EC number, also known as EC-No and EC#, is the seven-digit code that is assigned to chemical substances that are commercially available within the European Union...
235-727-4, and
Important Properties
Its properties make PZT-based compounds one of the most prominent and useful electroceramicsElectroceramics
Electroceramics is a class of ceramic materials used primarily for their electrical properties.While ceramics have traditionally been admired and used for their mechanical, thermal and chemical stability, their unique electrical, optical and magnetic properties have become of increasing importance...
.
Being piezoelectric
Piezoelectricity
Piezoelectricity is the charge which accumulates in certain solid materials in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure...
, it develops a voltage
Voltage
Voltage, otherwise known as electrical potential difference or electric tension is the difference in electric potential between two points — or the difference in electric potential energy per unit charge between two points...
(or potential difference) across two of its faces when compressed (useful for sensor applications), or physically changes shape when an external electric field is applied (useful for actuator applications).
The dielectric constant of PZT can range from 300 to 3850 depending upon orientation and doping.
Being pyroelectric, this material develops a voltage difference across two of its faces when it experiences a temperature change. As a result, it can be used as a sensor for detecting heat.
It is also ferroelectric
Ferroelectricity
Ferroelectricity is a property of certain materials which possess a spontaneous electric polarization that can be reversed by the application of an external electric field. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was...
, which means it has a spontaneous electric polarization
Polarization density
In classical electromagnetism, polarization density is the vector field that expresses the density of permanent or induced electric dipole moments in a dielectric material. When a dielectric is placed in an external electric field, its molecules gain electric dipole moment and the dielectric is...
(electric dipole
Electric dipole moment
In physics, the electric dipole moment is a measure of the separation of positive and negative electrical charges in a system of charges, that is, a measure of the charge system's overall polarity with SI units of Coulomb-meter...
) which can be reversed in the presence of an electric field.
The material features an extremely large dielectric constant
Dielectric constant
The relative permittivity of a material under given conditions reflects the extent to which it concentrates electrostatic lines of flux. In technical terms, it is the ratio of the amount of electrical energy stored in a material by an applied voltage, relative to that stored in a vacuum...
at the morphotropic phase boundary (MPB) near x = 0.52.
Uses
PZT is used to make ultrasoundUltrasound
Ultrasound is cyclic sound pressure with a frequency greater than the upper limit of human hearing. Ultrasound is thus not separated from "normal" sound based on differences in physical properties, only the fact that humans cannot hear it. Although this limit varies from person to person, it is...
transducer
Transducer
A transducer is a device that converts one type of energy to another. Energy types include electrical, mechanical, electromagnetic , chemical, acoustic or thermal energy. While the term transducer commonly implies the use of a sensor/detector, any device which converts energy can be considered a...
s and other sensor
Sensor
A sensor is a device that measures a physical quantity and converts it into a signal which can be read by an observer or by an instrument. For example, a mercury-in-glass thermometer converts the measured temperature into expansion and contraction of a liquid which can be read on a calibrated...
s and actuator
Actuator
An actuator is a type of motor for moving or controlling a mechanism or system. It is operated by a source of energy, usually in the form of an electric current, hydraulic fluid pressure or pneumatic pressure, and converts that energy into some kind of motion. An actuator is the mechanism by which...
s, as well as high-value ceramic capacitor
Capacitor
A capacitor is a passive two-terminal electrical component used to store energy in an electric field. The forms of practical capacitors vary widely, but all contain at least two electrical conductors separated by a dielectric ; for example, one common construction consists of metal foils separated...
s and FRAM
Ferroelectric RAM
Ferroelectric RAM is a random-access memory similar in construction to DRAM but uses a ferroelectric layer instead of a dielectric layer to achieve non-volatility. FeRAM is one of a growing number of alternative non-volatile memory technologies that offer the same functionality as Flash memory...
chips. PZT is also used in the manufacture of ceramic resonator
Ceramic resonator
A ceramic resonator is an electronic component that when combined with other appropriate components, can produce oscillations at a specific frequency...
s for reference timing in electronic circuitry. In 1975 Sandia National Laboratories
Sandia National Laboratories
The Sandia National Laboratories, managed and operated by the Sandia Corporation , are two major United States Department of Energy research and development national laboratories....
was working on anti-flash goggles to protect aircrew from burns and blindness in case of a nuclear explosion. The PLZT lenses could turn opaque in less than 150 microseconds.
Commercially, it is usually not used in its pure form, rather it is doped
Doping (semiconductor)
In semiconductor production, doping intentionally introduces impurities into an extremely pure semiconductor for the purpose of modulating its electrical properties. The impurities are dependent upon the type of semiconductor. Lightly and moderately doped semiconductors are referred to as extrinsic...
with either acceptor dopants, which create oxygen (anion) vacancies, or donor dopants, which create metal (cation) vacancies and facilitate domain wall motion in the material. In general, acceptor doping creates hard PZT while donor doping creates soft PZT. Hard and soft PZT's generally differ in their piezoelectric constants. Piezoelectric constants are proportional to the polarization or to the electrical field generated per unit of mechanical stress, or alternatively is the mechanical strain produced by per unit of electric field applied. In general, soft PZT has a higher piezoelectric constant, but larger losses in the material due to internal friction. In hard PZT, domain wall motion is pinned by the impurities thereby lowering the losses in the material, but at the expense of a reduced piezoelectric constant.
Varieties of PZTs
One of the commonly studied chemical composition is PbLead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
. The increased piezoelectric response and poling efficiency near to x = 0.52 is due to the increased number of allowable domain states at the MPB. At this boundary, the 6 possible domain states from the tetragonal phase <100> and the 8 possible domain states from the rhombohedral phase <111> are equally favorable energetically, thereby allowing a maximum 14 possible domain states.
Like structurally similar lead scandium tantalate
Lead scandium tantalate
Lead scandium tantalate is a ferroelectric ceramic material with perovskite structure. It has the formula PbO3. The x is usually about 0.5....
and barium strontium titanate, PZT can be used for manufacture of uncooled staring array infrared imaging sensors for thermographic camera
Thermographic camera
A thermographic camera or infrared camera is a device that forms an image using infrared radiation, similar to a common camera that forms an image using visible light...
s. Both thin film
Thin film
A thin film is a layer of material ranging from fractions of a nanometer to several micrometers in thickness. Electronic semiconductor devices and optical coatings are the main applications benefiting from thin film construction....
(usually obtained by chemical vapor deposition
Chemical vapor deposition
Chemical vapor deposition is a chemical process used to produce high-purity, high-performance solid materials. The process is often used in the semiconductor industry to produce thin films. In a typical CVD process, the wafer is exposed to one or more volatile precursors, which react and/or...
) and bulk structures are used. The formula of the material used usually approaches Pb1.1(Zr0.3Ti0.7)O3 (called PZT 30/70). Its properties may be modified by doping it with lanthanum
Lanthanum
Lanthanum is a chemical element with the symbol La and atomic number 57.Lanthanum is a silvery white metallic element that belongs to group 3 of the periodic table and is the first element of the lanthanide series. It is found in some rare-earth minerals, usually in combination with cerium and...
, resulting in lanthanum-doped lead zirconate titanate (PLZT, also called lead lanthanum zirconate titanate), with formula Pb0.83La0.17(Zr0.3Ti0.7)0.9575O3 (PLZT 17/30/70).