Scattering
Encyclopedia
Scattering is a general physical process where some forms of radiation
, such as light
, sound
, or moving particles, are forced to deviate from a straight trajectory
by one or more localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of reflected radiation from the angle predicted by the law of reflection. Reflections that undergo scattering are often called diffuse reflection
s and unscattered reflections are called specular (mirror-like) reflections
The types of non-uniformities which can cause scattering, sometimes known as scatterers or scattering centers, are too numerous to list, but a small sample includes particle
s, bubble
s, droplets, density
fluctuations in fluid
s, crystallite
s in polycrystalline solids, defects in monocrystalline solids, surface roughness
, cell
s in organisms, and textile fiber
s in clothing. The effects of such features on the path of almost any type of propagating wave or moving particle can be described in the framework of scattering theory
.
Some areas where scattering and scattering theory are significant include radar sensing, medical ultrasound, semiconductor wafer inspection, polymerization
process monitoring, acoustic tiling, free-space communications, and computer-generated imagery
.
With multiple scattering, the randomness of the interaction tends to be averaged out by the large number of scattering events, so that the final path of the radiation appears to be a deterministic distribution of intensity. This is exemplified by a light beam passing through thick fog
. Multiple scattering is highly analogous to diffusion
, and the terms multiple scattering and diffusion are interchangeable in many contexts. Optical elements designed to produce multiple scattering are thus known as diffusers. Coherent backscattering
, an enhancement of backscattering that occurs when coherent radiation is multiply scattered by a random medium, is usually attributed to weak localization
.
Not all single scattering is random, however. A well-controlled laser beam can be exactly positioned to scatter off a microscopic particle with a deterministic outcome, for instance. Such situations are encountered in radar scattering as well, where the targets tend to be macroscopic objects such as people or aircraft.
Similarly, multiple scattering can sometimes have somewhat random outcomes, particularly with coherent radiation. The random fluctuations in the multiply scattered intensity of coherent radiation are called speckles. Speckle also occurs if multiple parts of a coherent wave scatter from different centers. In certain rare circumstances, multiple scattering may only involve a small number of interactions such that the randomness is not completely averaged out. These systems are considered to be some of the most difficult to model accurately.
The description of scattering and the distinction between single and multiple scattering are often highly involved with wave–particle duality
.
is a framework for studying and understanding the scattering of waves
and particles
. Prosaically, wave scattering corresponds to the collision and scattering of a wave with some material object, for instance sunlight
scattered by rain drops to form a rainbow
. Scattering also includes the interaction of billiard balls on a table, the Rutherford scattering
(or angle change) of alpha particle
s by gold
nuclei
, the Bragg scattering (or diffraction) of electrons and X-rays by a cluster of atoms, and the inelastic scattering of a fission fragment as it traverses a thin foil. More precisely, scattering consists of the study of how solutions of partial differential equations, propagating freely "in the distant past", come together and interact with one another or with a boundary condition, and then propagate away "to the distant future".
Electromagnetic waves
are one of the best known and most commonly encountered forms of radiation that undergo scattering. Scattering of light
and radio waves (especially in radar
) is particularly important. Several different aspects of electromagnetic scattering are distinct enough to have conventional names. Major forms of elastic light scattering (involving negligible energy transfer) are Rayleigh scattering
and Mie scattering
. Inelastic scattering includes Brillouin scattering
, Raman scattering
, inelastic X-ray
scattering and Compton scattering
.
Light scattering is one of the two major physical processes that contribute to the visible appearance of most objects, the other being absorption. Surfaces described as white owe their appearance to multiple scattering of light by internal or surface inhomogeneities in the object, for example by the boundaries of transparent microscopic crystals that make up a stone or by the microscopic fibers in a sheet of paper. More generally, the gloss
(or lustre
or sheen
) of the surface is determined by scattering. Highly scattering surfaces are described as being dull or having a matte finish, while the absence of surface scattering leads to a glossy appearance, as with polished metal or stone. Spectral absorption, the selective absorption of certain colors, determines the color of most objects with some modification by elastic scattering. The apparent blue color of veins in skin is a common example where both spectral absorption and scattering play important and complex roles in the coloration. Light scattering can also create color without absorption, often shades of blue, as with the sky (Rayleigh scattering
), the human blue iris
, and the feathers of some birds (Prum et al. 1998). However, resonant light scattering in nanoparticles can produce many different highly saturated and vibrant hues, especially when surface plasmon resonance
is involved (Roqué et al. 2006).
Models of light scattering can be divided into three domains based on a dimensionless size parameter, α which is defined as
where πDp is the circumference of a particle and λ is the wavelength of incident radiation. Based on the value of α, these domains are:
: Rayleigh scattering
(small particle compared to wavelength of light)
: Mie scattering (particle about the same size as wavelength of light)
: Geometric scattering (particle much larger than wavelength of light)
Rayleigh scattering
is a process in which electromagnetic radiation (including light) is scattered by a small spherical volume of variant refractive index, such as a particle, bubble, droplet, or even a density fluctuation. This effect was first modeled successfully by Lord Rayleigh, from whom it gets its name. In order for Rayleigh's model to apply, the sphere must be much smaller in diameter than the wavelength
(λ) of the scattered wave; typically the upper limit is taken to be about 1/10 the wavelength. In this size regime, the exact shape of the scattering center is usually not very significant and can often be treated as a sphere of equivalent volume. The inherent scattering that radiation undergoes passing through a pure gas is due to microscopic density fluctuations as the gas molecules move around, which are normally small enough in scale for Rayleigh's model to apply. This scattering mechanism is the primary cause of the blue color of the Earth's sky on a clear day, as the shorter blue wavelengths of sunlight passing overhead are more strongly scattered than the longer red wavelengths according to Rayleigh's famous 1/λ4 relation. Along with absorption, such scattering is a major cause of the attenuation of radiation by the atmosphere
. The degree of scattering varies as a function of the ratio of the particle diameter to the wavelength of the radiation, along with many other factors including polarization, angle, and coherence
.
For larger diameters, the problem of electromagnetic scattering by spheres was first solved by Gustav Mie
, and scattering by spheres larger than the Rayleigh range is therefore usually known as Mie scattering
. In the Mie regime, the shape of the scattering center becomes much more significant and the theory only applies well to spheres and, with some modification, spheroids and ellipsoids. Closed-form solutions for scattering by certain other simple shapes exist, but no general closed-form solution is known for arbitrary shapes.
Both Mie and Rayleigh scattering are considered elastic scattering processes, in which the energy (and thus wavelength and frequency) of the light is not substantially changed. However, electromagnetic radiation scattered by moving scattering centers does undergo a Doppler shift, which can be detected and used to measure the velocity of the scattering center/s in forms of techniques such as LIDAR
and radar
. This shift involves a slight change in energy.
At values of the ratio of particle diameter to wavelength more than about 10, the laws of geometric optics are mostly sufficient to describe the interaction of light with the particle, and at this point the interaction is not usually described as scattering.
For modeling of scattering in cases where the Rayleigh and Mie models do not apply such as irregularly shaped particles, there are many numerical methods that can be used. The most common are finite-element methods
which solve Maxwell's equations
to find the distribution of the scattered electromagnetic field. Sophisticated software packages exist which allow the user to specify the refractive index or indices of the scattering feature in space, creating a 2- or sometimes 3-dimensional model of the structure. For relatively large and complex structures, these models usually require substantial execution times on a computer.
Radiation
In physics, radiation is a process in which energetic particles or energetic waves travel through a medium or space. There are two distinct types of radiation; ionizing and non-ionizing...
, such as light
Light
Light or visible light is electromagnetic radiation that is visible to the human eye, and is responsible for the sense of sight. Visible light has wavelength in a range from about 380 nanometres to about 740 nm, with a frequency range of about 405 THz to 790 THz...
, sound
Sound
Sound is a mechanical wave that is an oscillation of pressure transmitted through a solid, liquid, or gas, composed of frequencies within the range of hearing and of a level sufficiently strong to be heard, or the sensation stimulated in organs of hearing by such vibrations.-Propagation of...
, or moving particles, are forced to deviate from a straight trajectory
Trajectory
A trajectory is the path that a moving object follows through space as a function of time. The object might be a projectile or a satellite, for example. It thus includes the meaning of orbit—the path of a planet, an asteroid or a comet as it travels around a central mass...
by one or more localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of reflected radiation from the angle predicted by the law of reflection. Reflections that undergo scattering are often called diffuse reflection
Diffuse reflection
Diffuse reflection is the reflection of light from a surface such that an incident ray is reflected at many angles rather than at just one angle as in the case of specular reflection...
s and unscattered reflections are called specular (mirror-like) reflections
The types of non-uniformities which can cause scattering, sometimes known as scatterers or scattering centers, are too numerous to list, but a small sample includes particle
Particle
A particle is, generally, a small localized object to which can be ascribed physical properties. It may also refer to:In chemistry:* Colloidal particle, part of a one-phase system of two or more components where the particles aren't individually visible.In physics:* Subatomic particle, which may be...
s, bubble
Bubble
-Physical bubbles:* Liquid bubble, globule of one substance encased in another, usually air in a liquid* Soap bubble, a bubble formed by soapy water * Antibubble, a droplet of liquid surrounded by a thin film of gas-Arts and literature:...
s, droplets, density
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...
fluctuations in fluid
Fluid
In physics, a fluid is a substance that continually deforms under an applied shear stress. Fluids are a subset of the phases of matter and include liquids, gases, plasmas and, to some extent, plastic solids....
s, crystallite
Crystallite
Crystallites are small, often microscopic crystals that, held together through highly defective boundaries, constitute a polycrystalline solid. Metallurgists often refer to crystallites as grains.- Details :...
s in polycrystalline solids, defects in monocrystalline solids, surface roughness
Roughness
Surface roughness, often shortened to roughness, is a measure of the texture of a surface. It is quantified by the vertical deviations of a real surface from its ideal form. If these deviations are large, the surface is rough; if they are small the surface is smooth...
, cell
Cell (biology)
The cell is the basic structural and functional unit of all known living organisms. It is the smallest unit of life that is classified as a living thing, and is often called the building block of life. The Alberts text discusses how the "cellular building blocks" move to shape developing embryos....
s in organisms, and textile fiber
Fiber
Fiber is a class of materials that are continuous filaments or are in discrete elongated pieces, similar to lengths of thread.They are very important in the biology of both plants and animals, for holding tissues together....
s in clothing. The effects of such features on the path of almost any type of propagating wave or moving particle can be described in the framework of scattering theory
Scattering theory
In mathematics and physics, scattering theory is a framework for studying and understanding the scattering of waves and particles. Prosaically, wave scattering corresponds to the collision and scattering of a wave with some material object, for instance sunlight scattered by rain drops to form a...
.
Some areas where scattering and scattering theory are significant include radar sensing, medical ultrasound, semiconductor wafer inspection, polymerization
Polymerization
In polymer chemistry, polymerization is a process of reacting monomer molecules together in a chemical reaction to form three-dimensional networks or polymer chains...
process monitoring, acoustic tiling, free-space communications, and computer-generated imagery
Computer-generated imagery
Computer-generated imagery is the application of the field of computer graphics or, more specifically, 3D computer graphics to special effects in art, video games, films, television programs, commercials, simulators and simulation generally, and printed media...
.
Single and multiple scattering
When radiation is only scattered by one localized scattering center, this is called single scattering. It is very common that scattering centers are grouped together, and in those cases the radiation may scatter many times, which is known as multiple scattering. The main difference between the effects of single and multiple scattering is that single scattering can usually be treated as a random phenomenon and multiple scattering is usually more deterministic. Because the location of a single scattering center is not usually well known relative to the path of the radiation, the outcome, which tends to depend strongly on the exact incoming trajectory, appears random to an observer. This type of scattering would be exemplified by an electron being fired at an atomic nucleus. In that case, the atom's exact position relative to the path of the electron is unknown and would be immeasurable, so the exact direction of the electron after the collision is unknown, plus the quantum-mechanical nature of this particular interaction also makes the interaction random. Single scattering is therefore often described by probability distributions.With multiple scattering, the randomness of the interaction tends to be averaged out by the large number of scattering events, so that the final path of the radiation appears to be a deterministic distribution of intensity. This is exemplified by a light beam passing through thick fog
Fog
Fog is a collection of water droplets or ice crystals suspended in the air at or near the Earth's surface. While fog is a type of stratus cloud, the term "fog" is typically distinguished from the more generic term "cloud" in that fog is low-lying, and the moisture in the fog is often generated...
. Multiple scattering is highly analogous to diffusion
Diffusion
Molecular diffusion, often called simply diffusion, is the thermal motion of all particles at temperatures above absolute zero. The rate of this movement is a function of temperature, viscosity of the fluid and the size of the particles...
, and the terms multiple scattering and diffusion are interchangeable in many contexts. Optical elements designed to produce multiple scattering are thus known as diffusers. Coherent backscattering
Coherent backscattering
In physics, coherent backscattering is observed when coherent radiation propagates through a medium which has a large number of scattering centers of size comparable to the wavelength of the radiation....
, an enhancement of backscattering that occurs when coherent radiation is multiply scattered by a random medium, is usually attributed to weak localization
Weak localization
Weak localization is a physical effect which occurs in disordered electronic systems at very low temperatures. The effect manifests itself as a positive correction to the resistivity of a metal or semiconductor....
.
Not all single scattering is random, however. A well-controlled laser beam can be exactly positioned to scatter off a microscopic particle with a deterministic outcome, for instance. Such situations are encountered in radar scattering as well, where the targets tend to be macroscopic objects such as people or aircraft.
Similarly, multiple scattering can sometimes have somewhat random outcomes, particularly with coherent radiation. The random fluctuations in the multiply scattered intensity of coherent radiation are called speckles. Speckle also occurs if multiple parts of a coherent wave scatter from different centers. In certain rare circumstances, multiple scattering may only involve a small number of interactions such that the randomness is not completely averaged out. These systems are considered to be some of the most difficult to model accurately.
The description of scattering and the distinction between single and multiple scattering are often highly involved with wave–particle duality
Wave–particle duality
Wave–particle duality postulates that all particles exhibit both wave and particle properties. A central concept of quantum mechanics, this duality addresses the inability of classical concepts like "particle" and "wave" to fully describe the behavior of quantum-scale objects...
.
Scattering theory
Scattering theoryScattering theory
In mathematics and physics, scattering theory is a framework for studying and understanding the scattering of waves and particles. Prosaically, wave scattering corresponds to the collision and scattering of a wave with some material object, for instance sunlight scattered by rain drops to form a...
is a framework for studying and understanding the scattering of waves
WAVES
The WAVES were a World War II-era division of the U.S. Navy that consisted entirely of women. The name of this group is an acronym for "Women Accepted for Volunteer Emergency Service" ; the word "emergency" implied that the acceptance of women was due to the unusual circumstances of the war and...
and particles
Elementary particle
In particle physics, an elementary particle or fundamental particle is a particle not known to have substructure; that is, it is not known to be made up of smaller particles. If an elementary particle truly has no substructure, then it is one of the basic building blocks of the universe from which...
. Prosaically, wave scattering corresponds to the collision and scattering of a wave with some material object, for instance sunlight
Sunlight
Sunlight, in the broad sense, is the total frequency spectrum of electromagnetic radiation given off by the Sun. On Earth, sunlight is filtered through the Earth's atmosphere, and solar radiation is obvious as daylight when the Sun is above the horizon.When the direct solar radiation is not blocked...
scattered by rain drops to form a rainbow
Rainbow
A rainbow is an optical and meteorological phenomenon that causes a spectrum of light to appear in the sky when the Sun shines on to droplets of moisture in the Earth's atmosphere. It takes the form of a multicoloured arc...
. Scattering also includes the interaction of billiard balls on a table, the Rutherford scattering
Rutherford scattering
In physics, Rutherford scattering is a phenomenon that was explained by Ernest Rutherford in 1911, and led to the development of the Rutherford model of the atom, and eventually to the Bohr model. It is now exploited by the materials analytical technique Rutherford backscattering...
(or angle change) of alpha particle
Alpha particle
Alpha particles consist of two protons and two neutrons bound together into a particle identical to a helium nucleus, which is classically produced in the process of alpha decay, but may be produced also in other ways and given the same name...
s by gold
Gold
Gold is a chemical element with the symbol Au and an atomic number of 79. Gold is a dense, soft, shiny, malleable and ductile metal. Pure gold has a bright yellow color and luster traditionally considered attractive, which it maintains without oxidizing in air or water. Chemically, gold is a...
nuclei
Atomic nucleus
The nucleus is the very dense region consisting of protons and neutrons at the center of an atom. It was discovered in 1911, as a result of Ernest Rutherford's interpretation of the famous 1909 Rutherford experiment performed by Hans Geiger and Ernest Marsden, under the direction of Rutherford. The...
, the Bragg scattering (or diffraction) of electrons and X-rays by a cluster of atoms, and the inelastic scattering of a fission fragment as it traverses a thin foil. More precisely, scattering consists of the study of how solutions of partial differential equations, propagating freely "in the distant past", come together and interact with one another or with a boundary condition, and then propagate away "to the distant future".
Electromagnetic scattering
Electromagnetic radiation
Electromagnetic radiation is a form of energy that exhibits wave-like behavior as it travels through space...
are one of the best known and most commonly encountered forms of radiation that undergo scattering. Scattering of light
Light scattering
Light scattering is a form of scattering in which light is the form of propagating energy which is scattered. Light scattering can be thought of as the deflection of a ray from a straight path, for example by irregularities in the propagation medium, particles, or in the interface between two media...
and radio waves (especially in radar
Radar
Radar is an object-detection system which uses radio waves to determine the range, altitude, direction, or speed of objects. It can be used to detect aircraft, ships, spacecraft, guided missiles, motor vehicles, weather formations, and terrain. The radar dish or antenna transmits pulses of radio...
) is particularly important. Several different aspects of electromagnetic scattering are distinct enough to have conventional names. Major forms of elastic light scattering (involving negligible energy transfer) are Rayleigh scattering
Rayleigh scattering
Rayleigh scattering, named after the British physicist Lord Rayleigh, is the elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the light. The particles may be individual atoms or molecules. It can occur when light travels through...
and Mie scattering
Mie theory
The Mie solution to Maxwell's equations describes the scattering of electromagnetic radiation by a sphere...
. Inelastic scattering includes Brillouin scattering
Brillouin scattering
Brillouin scattering, named after Léon Brillouin, occurs when light in a medium interacts with time dependent optical density variations and changes its energy and path. The density variations may be due to acoustic modes, such as phonons, magnetic modes, such as magnons, or temperature gradients...
, Raman scattering
Raman scattering
Raman scattering or the Raman effect is the inelastic scattering of a photon. It was discovered by Sir Chandrasekhara Venkata Raman and Kariamanickam Srinivasa Krishnan in liquids, and by Grigory Landsberg and Leonid Mandelstam in crystals....
, inelastic X-ray
X-ray
X-radiation is a form of electromagnetic radiation. X-rays have a wavelength in the range of 0.01 to 10 nanometers, corresponding to frequencies in the range 30 petahertz to 30 exahertz and energies in the range 120 eV to 120 keV. They are shorter in wavelength than UV rays and longer than gamma...
scattering and Compton scattering
Compton scattering
In physics, Compton scattering is a type of scattering that X-rays and gamma rays undergo in matter. The inelastic scattering of photons in matter results in a decrease in energy of an X-ray or gamma ray photon, called the Compton effect...
.
Light scattering is one of the two major physical processes that contribute to the visible appearance of most objects, the other being absorption. Surfaces described as white owe their appearance to multiple scattering of light by internal or surface inhomogeneities in the object, for example by the boundaries of transparent microscopic crystals that make up a stone or by the microscopic fibers in a sheet of paper. More generally, the gloss
Gloss (material appearance)
Gloss is an optical property, which is based on the interaction of light with physical characteristics of a surface. It is actually the ability of a surface to reflect light into the specular direction. The factors that affect gloss are the refractive index of the material, the angle of incident...
(or lustre
Lustre (mineralogy)
Lustre is a description of the way light interacts with the surface of a crystal, rock, or mineral. The word lustre traces its origins back to the Latin word lux, meaning "light", and generally implies radiance, gloss, or brilliance....
or sheen
Gloss (paint)
Paint and other finishes come in a variety of finish gloss levels, which correspond to different levels of specular reflection.Some common names for levels of gloss include: flat, matte, eggshell, satin, silk, semi-gloss, high gloss. These terms are not standardized, and not all manufacturers use...
) of the surface is determined by scattering. Highly scattering surfaces are described as being dull or having a matte finish, while the absence of surface scattering leads to a glossy appearance, as with polished metal or stone. Spectral absorption, the selective absorption of certain colors, determines the color of most objects with some modification by elastic scattering. The apparent blue color of veins in skin is a common example where both spectral absorption and scattering play important and complex roles in the coloration. Light scattering can also create color without absorption, often shades of blue, as with the sky (Rayleigh scattering
Rayleigh scattering
Rayleigh scattering, named after the British physicist Lord Rayleigh, is the elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the light. The particles may be individual atoms or molecules. It can occur when light travels through...
), the human blue iris
Iris (anatomy)
The iris is a thin, circular structure in the eye, responsible for controlling the diameter and size of the pupils and thus the amount of light reaching the retina. "Eye color" is the color of the iris, which can be green, blue, or brown. In some cases it can be hazel , grey, violet, or even pink...
, and the feathers of some birds (Prum et al. 1998). However, resonant light scattering in nanoparticles can produce many different highly saturated and vibrant hues, especially when surface plasmon resonance
Surface plasmon resonance
The excitation of surface plasmons by light is denoted as a surface plasmon resonance for planar surfaces or localized surface plasmon resonance for nanometer-sized metallic structures....
is involved (Roqué et al. 2006).
Models of light scattering can be divided into three domains based on a dimensionless size parameter, α which is defined as
where πDp is the circumference of a particle and λ is the wavelength of incident radiation. Based on the value of α, these domains are:
: Rayleigh scatteringRayleigh scattering
Rayleigh scattering, named after the British physicist Lord Rayleigh, is the elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the light. The particles may be individual atoms or molecules. It can occur when light travels through...
(small particle compared to wavelength of light)
: Mie scattering (particle about the same size as wavelength of light): Geometric scattering (particle much larger than wavelength of light)Rayleigh scattering
Rayleigh scattering
Rayleigh scattering, named after the British physicist Lord Rayleigh, is the elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the light. The particles may be individual atoms or molecules. It can occur when light travels through...
is a process in which electromagnetic radiation (including light) is scattered by a small spherical volume of variant refractive index, such as a particle, bubble, droplet, or even a density fluctuation. This effect was first modeled successfully by Lord Rayleigh, from whom it gets its name. In order for Rayleigh's model to apply, the sphere must be much smaller in diameter than the wavelength
Wavelength
In physics, the wavelength of a sinusoidal wave is the spatial period of the wave—the distance over which the wave's shape repeats.It is usually determined by considering the distance between consecutive corresponding points of the same phase, such as crests, troughs, or zero crossings, and is a...
(λ) of the scattered wave; typically the upper limit is taken to be about 1/10 the wavelength. In this size regime, the exact shape of the scattering center is usually not very significant and can often be treated as a sphere of equivalent volume. The inherent scattering that radiation undergoes passing through a pure gas is due to microscopic density fluctuations as the gas molecules move around, which are normally small enough in scale for Rayleigh's model to apply. This scattering mechanism is the primary cause of the blue color of the Earth's sky on a clear day, as the shorter blue wavelengths of sunlight passing overhead are more strongly scattered than the longer red wavelengths according to Rayleigh's famous 1/λ4 relation. Along with absorption, such scattering is a major cause of the attenuation of radiation by the atmosphere
Earth's atmosphere
The atmosphere of Earth is a layer of gases surrounding the planet Earth that is retained by Earth's gravity. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention , and reducing temperature extremes between day and night...
. The degree of scattering varies as a function of the ratio of the particle diameter to the wavelength of the radiation, along with many other factors including polarization, angle, and coherence
Coherence (physics)
In physics, coherence is a property of waves that enables stationary interference. More generally, coherence describes all properties of the correlation between physical quantities of a wave....
.
For larger diameters, the problem of electromagnetic scattering by spheres was first solved by Gustav Mie
Gustav Mie
Gustav Adolf Feodor Wilhelm Ludwig Mie was a German physicist.-Biography:Mie was born in Rostock. From 1886 he studied mathematics and physics at the University of Rostock. In addition to his major subjects, he also attended lectures in chemistry, zoology, geology, mineralogy, astronomy as well as...
, and scattering by spheres larger than the Rayleigh range is therefore usually known as Mie scattering
Mie theory
The Mie solution to Maxwell's equations describes the scattering of electromagnetic radiation by a sphere...
. In the Mie regime, the shape of the scattering center becomes much more significant and the theory only applies well to spheres and, with some modification, spheroids and ellipsoids. Closed-form solutions for scattering by certain other simple shapes exist, but no general closed-form solution is known for arbitrary shapes.
Both Mie and Rayleigh scattering are considered elastic scattering processes, in which the energy (and thus wavelength and frequency) of the light is not substantially changed. However, electromagnetic radiation scattered by moving scattering centers does undergo a Doppler shift, which can be detected and used to measure the velocity of the scattering center/s in forms of techniques such as LIDAR
LIDAR
LIDAR is an optical remote sensing technology that can measure the distance to, or other properties of a target by illuminating the target with light, often using pulses from a laser...
and radar
Radar
Radar is an object-detection system which uses radio waves to determine the range, altitude, direction, or speed of objects. It can be used to detect aircraft, ships, spacecraft, guided missiles, motor vehicles, weather formations, and terrain. The radar dish or antenna transmits pulses of radio...
. This shift involves a slight change in energy.
At values of the ratio of particle diameter to wavelength more than about 10, the laws of geometric optics are mostly sufficient to describe the interaction of light with the particle, and at this point the interaction is not usually described as scattering.
For modeling of scattering in cases where the Rayleigh and Mie models do not apply such as irregularly shaped particles, there are many numerical methods that can be used. The most common are finite-element methods
Finite element method
The finite element method is a numerical technique for finding approximate solutions of partial differential equations as well as integral equations...
which solve Maxwell's equations
Maxwell's equations
Maxwell's equations are a set of partial differential equations that, together with the Lorentz force law, form the foundation of classical electrodynamics, classical optics, and electric circuits. These fields in turn underlie modern electrical and communications technologies.Maxwell's equations...
to find the distribution of the scattered electromagnetic field. Sophisticated software packages exist which allow the user to specify the refractive index or indices of the scattering feature in space, creating a 2- or sometimes 3-dimensional model of the structure. For relatively large and complex structures, these models usually require substantial execution times on a computer.
See also
- Bragg diffraction
- Brillouin scatteringBrillouin scatteringBrillouin scattering, named after Léon Brillouin, occurs when light in a medium interacts with time dependent optical density variations and changes its energy and path. The density variations may be due to acoustic modes, such as phonons, magnetic modes, such as magnons, or temperature gradients...
- Compton scatteringCompton scatteringIn physics, Compton scattering is a type of scattering that X-rays and gamma rays undergo in matter. The inelastic scattering of photons in matter results in a decrease in energy of an X-ray or gamma ray photon, called the Compton effect...
- Dynamic Light ScatteringDynamic light scatteringthumb|right|350px|Hypothetical Dynamic light scattering of two samples: Larger particles on the top and smaller particle on the bottomDynamic light scattering is a technique in physics that can be used to determine the size distribution profile of small particles in suspension or polymers...
- Espresso crema effectEspresso crema effectIn materials science, the espresso crema effect is an analogue model for superficial material alteration. Alteration processes such as weathering can influence the physical character and chemical composition of matter near the surface, without affecting the bulk medium beneath...
- Kikuchi lineKikuchi lineKikuchi lines pair up to form bands in electron diffraction from single crystal specimens, there to serve as "roads in orientation-space" for microscopists not sure what they are looking at. In transmission electron microscopes, they are easily seen in diffraction from regions of the specimen thick...
- Light scattering by particlesLight scattering by particlesLight scattering by particles is the process by which small particles such as ice crystals, dust, planetary dust, and blood cells cause observable phenomena such as rainbows, the color of the sky, and halos....
- Mie theoryMie theoryThe Mie solution to Maxwell's equations describes the scattering of electromagnetic radiation by a sphere...
- Mott scatteringMott scatteringMott scattering, also referred to as spin-coupling inelastic Coulomb scattering, is the separation of the two spin states of an electron beam by scattering the beam off the Coulomb field of heavy atoms...
- Neutron scatteringNeutron scatteringNeutron scattering,the scattering of free neutrons by matter,is a physical processand an experimental technique using this processfor the investigation of materials.Neutron scattering as a physical process is of primordial importance...
- Photon diffusionPhoton diffusionPhoton diffusion is a situation where photons travel through a material without being absorbed, but rather undergoing repeated scattering events which change the direction of their path. The path of any given photon is then effectively a random walk...
- Powder diffractionPowder diffractionPowder diffraction is a scientific technique using X-ray, neutron, or electron diffraction on powder or microcrystalline samples for structural characterization of materials.-Explanation:...
- Raman scatteringRaman scatteringRaman scattering or the Raman effect is the inelastic scattering of a photon. It was discovered by Sir Chandrasekhara Venkata Raman and Kariamanickam Srinivasa Krishnan in liquids, and by Grigory Landsberg and Leonid Mandelstam in crystals....
- Rayleigh scatteringRayleigh scatteringRayleigh scattering, named after the British physicist Lord Rayleigh, is the elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the light. The particles may be individual atoms or molecules. It can occur when light travels through...
- Rutherford scatteringRutherford scatteringIn physics, Rutherford scattering is a phenomenon that was explained by Ernest Rutherford in 1911, and led to the development of the Rutherford model of the atom, and eventually to the Bohr model. It is now exploited by the materials analytical technique Rutherford backscattering...
- Small-angle scatteringSmall-angle scatteringSmall-angle scattering is a scattering technique based on the deflection of a beam of particles, or an electromagnetic or acoustic wave, away from the straight trajectory after it interacts with structures that are much larger than the wavelength of the radiation. The deflection is small hence...
- Tyndall effectTyndall effectThe Tyndall effect, also known as Tyndall scattering, is light scattering by particles in a colloid or particles in a fine suspension. It is named after the 19th century physicist John Tyndall. It is similar to Rayleigh scattering, in that the intensity of the scattered light depends on the fourth...
- Thomson scatteringThomson scatteringThomson scattering is the elastic scattering of electromagnetic radiation by a free charged particle, as described by classical electromagnetism. It is just the low-energy limit of Compton scattering: the particle kinetic energy and photon frequency are the same before and after the scattering...
- Wolf effectWolf effectThe Wolf Effect is a frequency shift in the electromagnetic spectrum.The phenomenon occurs in several closely related phenomena in radiation physics, with analogous effects occurring in the scattering of light. It was first predicted by Emil Wolf in 1987 and subsequently confirmed in the...
- X-ray crystallographyX-ray crystallographyX-ray crystallography is a method of determining the arrangement of atoms within a crystal, in which a beam of X-rays strikes a crystal and causes the beam of light to spread into many specific directions. From the angles and intensities of these diffracted beams, a crystallographer can produce a...