Oil shale reserves
Encyclopedia
Oil shale reserves refers to oil shale
Oil shale
Oil shale, an organic-rich fine-grained sedimentary rock, contains significant amounts of kerogen from which liquid hydrocarbons called shale oil can be produced...

 resources that are recoverable under given economic restraints and technological abilities. Oil shale deposits range from small presently non-economic occurrences to large presently commercially exploitable reserves. Defining oil shale reserves is difficult, as the chemical composition of different oil shales, as well as their kerogen
Kerogen
Kerogen is a mixture of organic chemical compounds that make up a portion of the organic matter in sedimentary rocks. It is insoluble in normal organic solvents because of the huge molecular weight of its component compounds. The soluble portion is known as bitumen. When heated to the right...

 content and extraction technologies, vary significantly. The economic feasibility of shale oil extraction is highly dependent on the price of conventional oil; if the price of crude oil per barrel is less than the production price per barrel of shale oil, it is uneconomic.

There are around 600 known oil shale deposits. Many deposits need more exploration to determine their potential as reserves. However, worldwide technically recoverable reserves have recently been estimated at about 2.8 – of shale oil
Shale oil
Shale oil, known also as kerogen oil or oil-shale oil, is an unconventional oil produced from oil shale by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock into synthetic oil and gas...

, with the largest reserves in the United States
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...

, which is thought to have 1.5 –. Well-explored deposits, which could be classified as reserves, include the Green River
Green River Formation
The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes. The sediments are deposited in very fine layers, a dark layer during the growing season and a light-hue inorganic layer in winter. Each pair of layers is called a varve and...

 deposits in the western United States, the Tertiary deposits in Queensland
Queensland
Queensland is a state of Australia, occupying the north-eastern section of the mainland continent. It is bordered by the Northern Territory, South Australia and New South Wales to the west, south-west and south respectively. To the east, Queensland is bordered by the Coral Sea and Pacific Ocean...

, Australia, deposits in Sweden
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....

 and Estonia, the El-Lajjun deposit in Jordan
Jordan
Jordan , officially the Hashemite Kingdom of Jordan , Al-Mamlaka al-Urduniyya al-Hashemiyya) is a kingdom on the East Bank of the River Jordan. The country borders Saudi Arabia to the east and south-east, Iraq to the north-east, Syria to the north and the West Bank and Israel to the west, sharing...

, and deposits in France
France
The French Republic , The French Republic , The French Republic , (commonly known as France , is a unitary semi-presidential republic in Western Europe with several overseas territories and islands located on other continents and in the Indian, Pacific, and Atlantic oceans. Metropolitan France...

, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...

, Brazil, China, and Russia
Russia
Russia or , officially known as both Russia and the Russian Federation , is a country in northern Eurasia. It is a federal semi-presidential republic, comprising 83 federal subjects...

. It is expected that these deposits would yield at least 40 litre (0.251592430703346 bbl) of shale oil per metric ton of shale, using the Fischer Assay
Fischer Assay
The Fischer assay is a standardized laboratory test for determining the oil yield from oil shale to be expected from a conventional shale oil extraction. A 100 gram oil shale sample crushed to...

.

Definition of reserves

Estimating shale oil reserves is complicated by several factors. Firstly, the amount of kerogen contained in oil shale deposits varies considerably. Secondly, some nations report as reserves the total amount of kerogen in place, including all kerogen regardless of technical or economic constraints; these estimates do not consider the amount of kerogen that may be extracted from identified and assayed oil shale rock using available technology and under given economic conditions. By most definitions, "reserves" refers only to the amount of resource which is technically exploitable and economically feasible under current economic conditions. The term "resources", on the other hand, may refer to all deposits containing kerogen. Thirdly, shale oil extraction technologies are still developing, so the amount of recoverable kerogen can only be estimated.

There are a wide variety of extraction methods, which yield significantly different quantities of useful oil. As a result, the estimated amounts of resources and reserves display wide variance. The kerogen content of oil shale formations differs widely, and the economic feasibility of its extraction is highly dependent on international and local costs of oil. Several methods are used to determine the quantity and quality of the products extracted from shale oil. At their best, these methods give an approximate value to its energy potential. One standard method is the Fischer Assay, which yields a heating value, that is, a measure of caloric output. This is generally considered a good overall measure of usefulness. The Fischer Assay has been modified, standardized, and adapted by the American Petroleum Institute
American Petroleum Institute
The American Petroleum Institute, commonly referred to as API, is the largest U.S trade association for the oil and natural gas industry...

. It does not, however, indicate how much oil could be extracted from the sample. Some processing methods yield considerably more useful product than the Fischer Assay would indicate. The Tosco II method
TOSCO II process
The TOSCO II process is an above ground retorting technology for shale oil extraction, which uses fine particles of oil shale that are heated in a rotating kiln. The particularity of this process is that it use hot ceramic balls for the heat transfer between the retort and a heater...

 yields over 100% more oil, and the Hytort process
Hytort process
Hytort process is an above-ground shale oil extraction process developed by the Institute of Gas Technology. It is classified as a reactive fluid process, which produce shale oil by hydrogenation....

 yields between 300% to 400% more oil.
Largest oil shale deposits (over 1 billion metric tons)
DepositCountryPeriodIn-place shale oil resources (million barrels)In-place oil shale resources (million metric tons)
Green River Formation
Green River Formation
The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes. The sediments are deposited in very fine layers, a dark layer during the growing season and a light-hue inorganic layer in winter. Each pair of layers is called a varve and...

USA Tertiary
Tertiary
The Tertiary is a deprecated term for a geologic period 65 million to 2.6 million years ago. The Tertiary covered the time span between the superseded Secondary period and the Quaternary...

1,466,000 213,000
Phosphoria Formation USA Permian
Permian
The PermianThe term "Permian" was introduced into geology in 1841 by Sir Sir R. I. Murchison, president of the Geological Society of London, who identified typical strata in extensive Russian explorations undertaken with Edouard de Verneuil; Murchison asserted in 1841 that he named his "Permian...

250,000 35,775
Eastern Devonian USA Devonian
Devonian
The Devonian is a geologic period and system of the Paleozoic Era spanning from the end of the Silurian Period, about 416.0 ± 2.8 Mya , to the beginning of the Carboniferous Period, about 359.2 ± 2.5 Mya...

189,000 27,000
Heath Formation USA Early Carboniferous
Mississippian (geologic period)
The Mississippian is a subperiod in the geologic timescale or a subsystem of the geologic record. It is the earliest/lowermost of two subperiods of the Carboniferous period lasting from roughly 359 to 318 Ma...

180,000 25,578
Olenyok Basin Russia Cambrian
Cambrian
The Cambrian is the first geological period of the Paleozoic Era, lasting from Mya ; it is succeeded by the Ordovician. Its subdivisions, and indeed its base, are somewhat in flux. The period was established by Adam Sedgwick, who named it after Cambria, the Latin name for Wales, where Britain's...

167,715 24,000
Congo Democratic Republic of Congo ? 100,000 14,310
Irati Formation
Irati Formation
Irati Formation is the name of a geological formation of Brazil.It has previously been dated as Upper Permian using palynomorphs but is now dated as Lower Permian using zircon ages obtained from bentonite layers...

Brazil
Brazil
Brazil , officially the Federative Republic of Brazil , is the largest country in South America. It is the world's fifth largest country, both by geographical area and by population with over 192 million people...

Permian
Permian
The PermianThe term "Permian" was introduced into geology in 1841 by Sir Sir R. I. Murchison, president of the Geological Society of London, who identified typical strata in extensive Russian explorations undertaken with Edouard de Verneuil; Murchison asserted in 1841 that he named his "Permian...

80,000 11,448
Sicily Italy ? 63,000 9,015
Tarfaya Morocco Cretaceous
Cretaceous
The Cretaceous , derived from the Latin "creta" , usually abbreviated K for its German translation Kreide , is a geologic period and system from circa to million years ago. In the geologic timescale, the Cretaceous follows the Jurassic period and is followed by the Paleogene period of the...

42,145 6,448
Volga Basin Russia ? 31,447 4,500
St. Petersburg, Baltic Oil Shale Basin Russia Ordovician
Ordovician
The Ordovician is a geologic period and system, the second of six of the Paleozoic Era, and covers the time between 488.3±1.7 to 443.7±1.5 million years ago . It follows the Cambrian Period and is followed by the Silurian Period...

25,157 3,600
Vychegodsk Basin Russia Jurassic
Jurassic
The Jurassic is a geologic period and system that extends from about Mya to  Mya, that is, from the end of the Triassic to the beginning of the Cretaceous. The Jurassic constitutes the middle period of the Mesozoic era, also known as the age of reptiles. The start of the period is marked by...

19,580 2,800
Wadi Maghar Jordan Cretaceous
Cretaceous
The Cretaceous , derived from the Latin "creta" , usually abbreviated K for its German translation Kreide , is a geologic period and system from circa to million years ago. In the geologic timescale, the Cretaceous follows the Jurassic period and is followed by the Paleogene period of the...

14,009 2,149
Dictyonema shale Estonia Ordovician
Ordovician
The Ordovician is a geologic period and system, the second of six of the Paleozoic Era, and covers the time between 488.3±1.7 to 443.7±1.5 million years ago . It follows the Cambrian Period and is followed by the Silurian Period...

12,386 1,900
Timahdit Morocco Cretaceous
Cretaceous
The Cretaceous , derived from the Latin "creta" , usually abbreviated K for its German translation Kreide , is a geologic period and system from circa to million years ago. In the geologic timescale, the Cretaceous follows the Jurassic period and is followed by the Paleogene period of the...

11,236 1,719
Collingwood Shale Canada Ordovician
Ordovician
The Ordovician is a geologic period and system, the second of six of the Paleozoic Era, and covers the time between 488.3±1.7 to 443.7±1.5 million years ago . It follows the Cambrian Period and is followed by the Silurian Period...

12,300 1,717
Italy Italy Triassic
Triassic
The Triassic is a geologic period and system that extends from about 250 to 200 Mya . As the first period of the Mesozoic Era, the Triassic follows the Permian and is followed by the Jurassic. Both the start and end of the Triassic are marked by major extinction events...

10,000 1,431

Geographical allocation

There is no comprehensive overview of oil shales geographical allocation around the world. Around 600 known oil shale deposits are diversely spread throughout the earth, and are found on every continent with the possible exception of Antarctica, which has not yet been explored for oil shale. Oil shale resources can be concentrated in a large confined deposit such as the Green River formations, which were formed by a large inland lake. These can be many meters thick but limited by the size of the original lake. They may also resemble the deposits found along the eastern American seaboard, which were the product of a shallow sea, in that they may be quite thin but laterally expansive, covering thousands of square kilometers.

The table below reports reserves by estimated amount of shale oil. Shale oil refers to synthetic oil obtained by heating organic material (kerogen) contained in oil shale to a temperature which will separate it into oil, combustible gas, and the residual carbon that remains in the spent shale. All figures are presented in barrels and metric tons.
Shale oil: resources and production at end-2005 by regions and countries with resources over 10 Goilbbl of in-place shale oil
RegionIn-place shale oil resources (million barrels)In-place oil shale resources (million metric tons)Production in 2002 (thousand metric tons (oil))
Africa 159,243 23,317 -
Democratic Republic of the Congo 100,000 14,310 -
Morocco 53,381 8,187 -
Asia 45,894 6,562 180
China 16,000 2,290 180
Europe 368,156 52,845 345
Russia 247,883 35,470 -
Italy 73,000 10,446 -
Estonia 16,286 2,494 345
Middle East 38,172 5,792 -
Jordan 34,172 5,242 -
North America 2,100,469 303,758 -
United States 2,085,228 301,566 -
Canada 15,241 2,192 -
Oceania 31,748 4,534 -
Australia 31,729 4,531 -
South America 82,421 11,794 157
Brazil 82,000 11,734 159
World total 2,826,103 408,602 684

Africa

Major oil shale deposits are located in the Democratic Republic of Congo (equal to 14.31 billion metric tons of shale oil) and Morocco
Morocco
Morocco , officially the Kingdom of Morocco , is a country located in North Africa. It has a population of more than 32 million and an area of 710,850 km², and also primarily administers the disputed region of the Western Sahara...

 (12.3 billion metric tons or 8.16 billion metric tons of shale oil). Deposits in Congo are not properly explored yet. In Morocco, oil shale deposits have been identified at ten localities with the largest deposits in Tarfaya
Tarfaya
- References :CitationsBibliography* Didier Daurat, , France: Édition Dynamo, 1954....

 and Timahdite
Timahdite
Timahdite is a town in Ifrane Province, Meknès-Tafilalet, Morocco. According to the 2004 census it has a population of 2507. Located at an altitude of 1800 metres, it lies in the heart of Middle Atlas Mountains, in an area with a harsh climate....

. Although reserves in Tarfaya and Timahdit are well explored, the commercial exploitation has not started yet and only a limited program of laboratory and pilot-plant research has been undertaken. There are also oil shale reserves in Egypt
Egypt
Egypt , officially the Arab Republic of Egypt, Arabic: , is a country mainly in North Africa, with the Sinai Peninsula forming a land bridge in Southwest Asia. Egypt is thus a transcontinental country, and a major power in Africa, the Mediterranean Basin, the Middle East and the Muslim world...

, South Africa, Madagascar
Madagascar
The Republic of Madagascar is an island country located in the Indian Ocean off the southeastern coast of Africa...

, and Nigeria
Nigeria
Nigeria , officially the Federal Republic of Nigeria, is a federal constitutional republic comprising 36 states and its Federal Capital Territory, Abuja. The country is located in West Africa and shares land borders with the Republic of Benin in the west, Chad and Cameroon in the east, and Niger in...

. The main deposits of Egypt are located in Safaga-Al-Qusair
Al-Qusair
Al-Qusair is a city in Egypt. Approximately 5000 year old, it lies along the Red Sea...

 and Abu Tartour areas.

Asia

Major oil shale deposits are located in China
China
Chinese civilization may refer to:* China for more general discussion of the country.* Chinese culture* Greater China, the transnational community of ethnic Chinese.* History of China* Sinosphere, the area historically affected by Chinese culture...

, which has an estimated total of 32 billion metric tons, of which 4.4 billion metric tons are technically exploitable and economically feasible; Thailand
Thailand
Thailand , officially the Kingdom of Thailand , formerly known as Siam , is a country located at the centre of the Indochina peninsula and Southeast Asia. It is bordered to the north by Burma and Laos, to the east by Laos and Cambodia, to the south by the Gulf of Thailand and Malaysia, and to the...

 (18.7 billion metric tons), Kazakhstan
Kazakhstan
Kazakhstan , officially the Republic of Kazakhstan, is a transcontinental country in Central Asia and Eastern Europe. Ranked as the ninth largest country in the world, it is also the world's largest landlocked country; its territory of is greater than Western Europe...

 (several deposits; major deposit at Kenderlyk Field with 4 billion metric tons), and Turkey
Turkey
Turkey , known officially as the Republic of Turkey , is a Eurasian country located in Western Asia and in East Thrace in Southeastern Europe...

 (2.2 billion metric tons). Smaller oil shale reserves have also been found in Assam
Assam
Assam , also, rarely, Assam Valley and formerly the Assam Province , is a northeastern state of India and is one of the most culturally and geographically distinct regions of the country...

  ( India
India
India , officially the Republic of India , is a country in South Asia. It is the seventh-largest country by geographical area, the second-most populous country with over 1.2 billion people, and the most populous democracy in the world...

 ), Pakistan
Pakistan
Pakistan , officially the Islamic Republic of Pakistan is a sovereign state in South Asia. It has a coastline along the Arabian Sea and the Gulf of Oman in the south and is bordered by Afghanistan and Iran in the west, India in the east and China in the far northeast. In the north, Tajikistan...

, Uzbekistan
Uzbekistan
Uzbekistan , officially the Republic of Uzbekistan is a doubly landlocked country in Central Asia and one of the six independent Turkic states. It shares borders with Kazakhstan to the west and to the north, Kyrgyzstan and Tajikistan to the east, and Afghanistan and Turkmenistan to the south....

, Turkmenistan
Turkmenistan
Turkmenistan , formerly also known as Turkmenia is one of the Turkic states in Central Asia. Until 1991, it was a constituent republic of the Soviet Union, the Turkmen Soviet Socialist Republic . Turkmenistan is one of the six independent Turkic states...

, Myanmar
Myanmar
Burma , officially the Republic of the Union of Myanmar , is a country in Southeast Asia. Burma is bordered by China on the northeast, Laos on the east, Thailand on the southeast, Bangladesh on the west, India on the northwest, the Bay of Bengal to the southwest, and the Andaman Sea on the south....

, Armenia
Armenia
Armenia , officially the Republic of Armenia , is a landlocked mountainous country in the Caucasus region of Eurasia...

, and Mongolia
Mongolia
Mongolia is a landlocked country in East and Central Asia. It is bordered by Russia to the north and China to the south, east and west. Although Mongolia does not share a border with Kazakhstan, its western-most point is only from Kazakhstan's eastern tip. Ulan Bator, the capital and largest...

.

The principal Chinese oil shale deposits and production lie in Fushun
Fushun
Fushun is a city in Liaoning, China, about 45 km east from Shenyang, with a population about 2,138 090 inhabitants at the 2010 census and an area of 11,271 km2, including 713 km2 of the city proper. Fushun is situated on the Hun He . It was formerly called Fouchouen in French...

 and Liaoning
Liaoning
' is a province of the People's Republic of China, located in the northeast of the country. Its one-character abbreviation is "辽" , a name taken from the Liao River that flows through the province. "Níng" means "peace"...

; others are located in Maoming
Maoming
Maoming is located in southwestern Guangdong province, People's Republic of China. Facing the South China Sea to the city's south, Maoming city neighbors Zhanjiang in the west and is from Guangzhou and from Zhanjiang. The Maoming Port is a Grade I port that handled 16.8 million tons of cargo in...

 in Guangdong
Guangdong
Guangdong is a province on the South China Sea coast of the People's Republic of China. The province was previously often written with the alternative English name Kwangtung Province...

, Huadian
Huadian
Huadian is a city in southeastern Jilin province, People's Republic of China. It is under the administration of Jilin City.-Administrative divisions:Subdistricts:...

 in Jilin
Jilin
Jilin , is a province of the People's Republic of China located in the northeastern part of the country. Jilin borders North Korea and Russia to the east, Heilongjiang to the north, Liaoning to the south, and Inner Mongolia to the west...

, Heilongjiang
Heilongjiang
For the river known in Mandarin as Heilong Jiang, see Amur River' is a province of the People's Republic of China located in the northeastern part of the country. "Heilongjiang" literally means Black Dragon River, which is the Chinese name for the Amur. The one-character abbreviation is 黑...

, and Shandong
Shandong
' is a Province located on the eastern coast of the People's Republic of China. Shandong has played a major role in Chinese history from the beginning of Chinese civilization along the lower reaches of the Yellow River and served as a pivotal cultural and religious site for Taoism, Chinese...

. In 2002, China produced more than 90,000 metric tons of shale oil. Thailand's oil shale deposits are near Mae Sot
Mae Sot
- External links :* * : an audio documentary.* *...

, Tak Province
Tak Province
Tak is one of the northern provinces of Thailand. Neighboring provinces are Mae Hong Son, Chiang Mai, Lamphun, Lampang, Sukhothai, Kamphaeng Phet, Nakhon Sawan, Uthai Thani and Kanchanaburi...

, and at Li
Amphoe Li
Li is the southernmost district of Lamphun Province, northern Thailand.-History:Li district was established in 1911. Originally named Mueang Li, it was shortened to Li in 1917.-Geography:...

, Lamphun Province
Lamphun Province
Lamphun is one of the northern provinces of Thailand. Neighboring provinces are Chiang Mai, Lampang and Tak.-Geography:Lamphun is located in the river valley of the Ping River, surrounded by mountain chains....

. Deposits in Turkey are found mainly in middle and western Anatolia
Anatolia
Anatolia is a geographic and historical term denoting the westernmost protrusion of Asia, comprising the majority of the Republic of Turkey...

.

Professor Alan R. Carroll of University of Wisconsin–Madison
University of Wisconsin–Madison
The University of Wisconsin–Madison is a public research university located in Madison, Wisconsin, United States. Founded in 1848, UW–Madison is the flagship campus of the University of Wisconsin System. It became a land-grant institution in 1866...

 estimates that Upper Permian lacustrine oil shale deposits of northwest China, absent from previous global oil shale assessments, are comparable to the Green River Formation.

Europe

The biggest oil shale reserves in Europe are located in Russia
Russia
Russia or , officially known as both Russia and the Russian Federation , is a country in northern Eurasia. It is a federal semi-presidential republic, comprising 83 federal subjects...

 (equal to 35.47 billion metric tons of shale oil). Major deposits are located in the Volga-Petchyorsk province and in the Baltic Oil Shale Basin. Other major oil shale deposits in Europe
Europe
Europe is, by convention, one of the world's seven continents. Comprising the westernmost peninsula of Eurasia, Europe is generally 'divided' from Asia to its east by the watershed divides of the Ural and Caucasus Mountains, the Ural River, the Caspian and Black Seas, and the waterways connecting...

 are located in Italy
Italy
Italy , officially the Italian Republic languages]] under the European Charter for Regional or Minority Languages. In each of these, Italy's official name is as follows:;;;;;;;;), is a unitary parliamentary republic in South-Central Europe. To the north it borders France, Switzerland, Austria and...

 (10.45 billion metric tons of shale oil
Oil
An oil is any substance that is liquid at ambient temperatures and does not mix with water but may mix with other oils and organic solvents. This general definition includes vegetable oils, volatile essential oils, petrochemical oils, and synthetic oils....

), Estonia
Estonia
Estonia , officially the Republic of Estonia , is a state in the Baltic region of Northern Europe. It is bordered to the north by the Gulf of Finland, to the west by the Baltic Sea, to the south by Latvia , and to the east by Lake Peipsi and the Russian Federation . Across the Baltic Sea lies...

 (2.49 billion metric tons of shale oil), France
France
The French Republic , The French Republic , The French Republic , (commonly known as France , is a unitary semi-presidential republic in Western Europe with several overseas territories and islands located on other continents and in the Indian, Pacific, and Atlantic oceans. Metropolitan France...

 (1 billion metric tons of shale oil), Belarus
Belarus
Belarus , officially the Republic of Belarus, is a landlocked country in Eastern Europe, bordered clockwise by Russia to the northeast, Ukraine to the south, Poland to the west, and Lithuania and Latvia to the northwest. Its capital is Minsk; other major cities include Brest, Grodno , Gomel ,...

 (1 billion metric tons of shale oil), Sweden
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....

 (875 million metric tons of shale oil), Ukraine
Ukraine
Ukraine is a country in Eastern Europe. It has an area of 603,628 km², making it the second largest contiguous country on the European continent, after Russia...

 (600 million metric tons of shale oil) and the United Kingdom
United Kingdom
The United Kingdom of Great Britain and Northern IrelandIn the United Kingdom and Dependencies, other languages have been officially recognised as legitimate autochthonous languages under the European Charter for Regional or Minority Languages...

 (500 million metric tons of shale oil). There are oil shale reserves also in Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...

, Luxembourg
Luxembourg
Luxembourg , officially the Grand Duchy of Luxembourg , is a landlocked country in western Europe, bordered by Belgium, France, and Germany. It has two principal regions: the Oesling in the North as part of the Ardennes massif, and the Gutland in the south...

, Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...

, Bulgaria
Bulgaria
Bulgaria , officially the Republic of Bulgaria , is a parliamentary democracy within a unitary constitutional republic in Southeast Europe. The country borders Romania to the north, Serbia and Macedonia to the west, Greece and Turkey to the south, as well as the Black Sea to the east...

, Hungary
Hungary
Hungary , officially the Republic of Hungary , is a landlocked country in Central Europe. It is situated in the Carpathian Basin and is bordered by Slovakia to the north, Ukraine and Romania to the east, Serbia and Croatia to the south, Slovenia to the southwest and Austria to the west. The...

, Poland
Poland
Poland , officially the Republic of Poland , is a country in Central Europe bordered by Germany to the west; the Czech Republic and Slovakia to the south; Ukraine, Belarus and Lithuania to the east; and the Baltic Sea and Kaliningrad Oblast, a Russian exclave, to the north...

, Serbia
Serbia
Serbia , officially the Republic of Serbia , is a landlocked country located at the crossroads of Central and Southeast Europe, covering the southern part of the Carpathian basin and the central part of the Balkans...

, Austria
Austria
Austria , officially the Republic of Austria , is a landlocked country of roughly 8.4 million people in Central Europe. It is bordered by the Czech Republic and Germany to the north, Slovakia and Hungary to the east, Slovenia and Italy to the south, and Switzerland and Liechtenstein to the...

, Albania
Albania
Albania , officially known as the Republic of Albania , is a country in Southeastern Europe, in the Balkans region. It is bordered by Montenegro to the northwest, Kosovo to the northeast, the Republic of Macedonia to the east and Greece to the south and southeast. It has a coast on the Adriatic Sea...

, and Romania
Romania
Romania is a country located at the crossroads of Central and Southeastern Europe, on the Lower Danube, within and outside the Carpathian arch, bordering on the Black Sea...

.

Middle East

Significant oil shale deposits are located in Jordan (5.242 billion metric tons of shale oil or 65 billion metric tons of oil shale) and Israel
Israel
The State of Israel is a parliamentary republic located in the Middle East, along the eastern shore of the Mediterranean Sea...

 (550 million metric tons of shale oil or 6.5 billion metric tons of oil shale). Jordanian oil shales are high quality, comparable to western US oil shale, although their sulfur
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...

 content is high. The best-explored deposits are El Lajjun, Sultani, and the Juref ed Darawishare located in west-central Jordan, while the Yarmouk
Yarmouk River
The Yarmouk River is the largest tributary of the Jordan River. It drains much of the Hauran Plateau. It is one of three main tributaries which enter the Jordan between the Sea of Galilee and the Dead Sea. To the south, are the Jabbok/Zarqa and the Arnon/Wadi Mujib) rivers...

 deposit, close to its northern border, extends into Syria
Syria
Syria , officially the Syrian Arab Republic , is a country in Western Asia, bordering Lebanon and the Mediterranean Sea to the West, Turkey to the north, Iraq to the east, Jordan to the south, and Israel to the southwest....

. Most of Israel's deposits are located in the Rotem Basin region of the northern Negev desert
Negev
The Negev is a desert and semidesert region of southern Israel. The Arabs, including the native Bedouin population of the region, refer to the desert as al-Naqab. The origin of the word Neghebh is from the Hebrew root denoting 'dry'...

 near the Dead Sea
Dead Sea
The Dead Sea , also called the Salt Sea, is a salt lake bordering Jordan to the east and Israel and the West Bank to the west. Its surface and shores are below sea level, the lowest elevation on the Earth's surface. The Dead Sea is deep, the deepest hypersaline lake in the world...

. Israeli oil shale is relatively low in heating value and oil yield.

North America

At 301 billion metric tons, the oil shale deposits in the United States are easily the largest in the world. There are two major deposits: the eastern US deposits, in Devonian-Mississippian shales, cover 250000 square miles (647,497 km²); the western US deposits of the Green River Formation
Green River Formation
The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes. The sediments are deposited in very fine layers, a dark layer during the growing season and a light-hue inorganic layer in winter. Each pair of layers is called a varve and...

 in Colorado
Colorado
Colorado is a U.S. state that encompasses much of the Rocky Mountains as well as the northeastern portion of the Colorado Plateau and the western edge of the Great Plains...

, Wyoming
Wyoming
Wyoming is a state in the mountain region of the Western United States. The western two thirds of the state is covered mostly with the mountain ranges and rangelands in the foothills of the Eastern Rocky Mountains, while the eastern third of the state is high elevation prairie known as the High...

, and Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...

, are among the richest oil shale deposits in the world. In Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...

 19 deposits have been identified. The best-examined deposits are in Nova Scotia
Nova Scotia
Nova Scotia is one of Canada's three Maritime provinces and is the most populous province in Atlantic Canada. The name of the province is Latin for "New Scotland," but "Nova Scotia" is the recognized, English-language name of the province. The provincial capital is Halifax. Nova Scotia is the...

 and New Brunswick
New Brunswick
New Brunswick is one of Canada's three Maritime provinces and is the only province in the federation that is constitutionally bilingual . The provincial capital is Fredericton and Saint John is the most populous city. Greater Moncton is the largest Census Metropolitan Area...

.

Oceania

Australia
Australia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...

's oil shale resource is estimated at about 58 billion metric tons or 4.531 billion metric tons of shale oil, of which about 24 Goilbbl is recoverable. The deposits are located in the eastern and southern states with the biggest potential in the eastern Queensland
Queensland
Queensland is a state of Australia, occupying the north-eastern section of the mainland continent. It is bordered by the Northern Territory, South Australia and New South Wales to the west, south-west and south respectively. To the east, Queensland is bordered by the Coral Sea and Pacific Ocean...

 deposits. Oil shale has also been found in New Zealand
New Zealand
New Zealand is an island country in the south-western Pacific Ocean comprising two main landmasses and numerous smaller islands. The country is situated some east of Australia across the Tasman Sea, and roughly south of the Pacific island nations of New Caledonia, Fiji, and Tonga...

.

South America

Brazil has the world's second-largest known oil shale resources (the Irati shale and lacustrine
Lake
A lake is a body of relatively still fresh or salt water of considerable size, localized in a basin, that is surrounded by land. Lakes are inland and not part of the ocean and therefore are distinct from lagoons, and are larger and deeper than ponds. Lakes can be contrasted with rivers or streams,...

 deposits) and is currently the world's second largest shale oil producer, after Estonia. Oil shale resources occur in São Mateus do Sul
São Mateus do Sul
São Mateus do Sul is a town and municipality in the state of Paraná in the Southern Region of Brazil.-References:...

, Paraná
Paraná (state)
Paraná is one of the states of Brazil, located in the South of the country, bordered on the north by São Paulo state, on the east by the Atlantic Ocean, on the south by Santa Catarina state and the Misiones Province of Argentina, and on the west by Mato Grosso do Sul and the republic of Paraguay,...

, and in Vale do Paraíba. Brazil has developed the world’s largest surface oil shale pyrolysis retort at Petrosix
Petrosix
Petrosix is currently the world’s largest surface oil shale pyrolysis retort with an diameter vertical shaft kiln, operational since 1992. It is located in São Mateus do Sul, Brazil, and it is owned and operated by the Brazil energy company Petrobras. Petrosix means also the Petrosix process, an...

, with a 11 metres (36 ft)-diameter vertical shaft. Brazilian production in 1999 was about 200,000 metric tons.
Small resources are also found in Argentina
Argentina
Argentina , officially the Argentine Republic , is the second largest country in South America by land area, after Brazil. It is constituted as a federation of 23 provinces and an autonomous city, Buenos Aires...

, Chile
Chile
Chile ,officially the Republic of Chile , is a country in South America occupying a long, narrow coastal strip between the Andes mountains to the east and the Pacific Ocean to the west. It borders Peru to the north, Bolivia to the northeast, Argentina to the east, and the Drake Passage in the far...

, Paraguay
Paraguay
Paraguay , officially the Republic of Paraguay , is a landlocked country in South America. It is bordered by Argentina to the south and southwest, Brazil to the east and northeast, and Bolivia to the northwest. Paraguay lies on both banks of the Paraguay River, which runs through the center of the...

, Peru
Peru
Peru , officially the Republic of Peru , is a country in western South America. It is bordered on the north by Ecuador and Colombia, on the east by Brazil, on the southeast by Bolivia, on the south by Chile, and on the west by the Pacific Ocean....

, Uruguay
Uruguay
Uruguay ,officially the Oriental Republic of Uruguay,sometimes the Eastern Republic of Uruguay; ) is a country in the southeastern part of South America. It is home to some 3.5 million people, of whom 1.8 million live in the capital Montevideo and its metropolitan area...

, and Venezuela
Venezuela
Venezuela , officially called the Bolivarian Republic of Venezuela , is a tropical country on the northern coast of South America. It borders Colombia to the west, Guyana to the east, and Brazil to the south...

.
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