Volcanogenic massive sulfide ore deposit
Encyclopedia
Metal
A metal , is an element, compound, or alloy that is a good conductor of both electricity and heat. Metals are usually malleable and shiny, that is they reflect most of incident light...
sulfide
Sulfide
A sulfide is an anion of sulfur in its lowest oxidation state of 2-. Sulfide is also a slightly archaic term for thioethers, a common type of organosulfur compound that are well known for their bad odors.- Properties :...
ore deposit
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
, mainly Cu
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
-Zn
Zinc
Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...
-Pb
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
which are associated with and created by volcanic-associated hydrothermal events in submarine environments.
These deposits are also sometimes called volcanic-hosted massive sulfide
Sulfide
A sulfide is an anion of sulfur in its lowest oxidation state of 2-. Sulfide is also a slightly archaic term for thioethers, a common type of organosulfur compound that are well known for their bad odors.- Properties :...
(VHMS) deposits. They are predominantly layered accumulations of sulfide minerals that precipitate from hydrothermal fluids on or below the seafloor in a wide range of ancient and modern geological settings. In modern oceans they are synonymous with sulfurous plumes called black smokers.
They occur within environments dominated by volcanic or volcanic-derived (e.g., volcano-sedimentary) rocks, and the deposits are contemporary and coincident with the formation of associated volcanic rocks. As a class, they represent a significant source of the world's Cu
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...
, Zn
Zinc
Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...
, Pb
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...
, Au
Gold
Gold is a chemical element with the symbol Au and an atomic number of 79. Gold is a dense, soft, shiny, malleable and ductile metal. Pure gold has a bright yellow color and luster traditionally considered attractive, which it maintains without oxidizing in air or water. Chemically, gold is a...
, and Ag
Silver
Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal...
ores, with Co
Cobalt
Cobalt is a chemical element with symbol Co and atomic number 27. It is found naturally only in chemically combined form. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal....
, Sn
Tin
Tin is a chemical element with the symbol Sn and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows chemical similarity to both neighboring group 14 elements, germanium and lead and has two possible oxidation states, +2 and the slightly more stable +4...
, Ba
Barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...
, S
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...
, Se
Selenium
Selenium is a chemical element with atomic number 34, chemical symbol Se, and an atomic mass of 78.96. It is a nonmetal, whose properties are intermediate between those of adjacent chalcogen elements sulfur and tellurium...
, Mn
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
, Cd
Cadmium
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, bluish-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Similar to zinc, it prefers oxidation state +2 in most of its compounds and similar to mercury it shows a low...
, In
Indium
Indium is a chemical element with the symbol In and atomic number 49. This rare, very soft, malleable and easily fusible post-transition metal is chemically similar to gallium and thallium, and shows the intermediate properties between these two...
, Bi
Bismuth
Bismuth is a chemical element with symbol Bi and atomic number 83. Bismuth, a trivalent poor metal, chemically resembles arsenic and antimony. Elemental bismuth may occur naturally uncombined, although its sulfide and oxide form important commercial ores. The free element is 86% as dense as lead...
, Te, Ga
Gallium
Gallium is a chemical element that has the symbol Ga and atomic number 31. Elemental gallium does not occur in nature, but as the gallium salt in trace amounts in bauxite and zinc ores. A soft silvery metallic poor metal, elemental gallium is a brittle solid at low temperatures. As it liquefies...
and Ge
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....
as mining by-products.
Volcanogenic massive sulfide deposits are forming today on the seafloor around undersea volcanoes along many mid ocean ridges, and within back-arc basins and forearc rifts. Mineral exploration companies are exploring for seafloor massive sulfide deposits
Seafloor massive sulfide deposits
Seafloor massive sulfide deposits or SMS deposits, are modern equivalents of ancient volcanogenic massive sulfide ore deposits or VMS deposits. The term has been coined by mineral explorers to differentiate the modern deposit from the ancient....
; however, most exploration is concentrated in the search for land-based equivalents of these deposits.
The close association with volcanic rocks and eruptive centers sets VMS deposits apart from similar ore deposit types which share similar source, transport and trap processes. Some volcanogenic massive sulfide deposits are distinctive in that ore deposits are formed in close temporal association with submarine volcanism and are formed by hydrothermal circulation and exhalation of sulfides which are independent of sedimentary processes. This can set VMS deposits apart from sedimentary exhalative
Sedimentary exhalative deposits
Sedimentary exhalative deposits are ore deposits which are interpreted to have been formed by release of ore-bearing hydrothermal fluids into a water reservoir , resulting in the precipitation of stratiform ore....
(SEDEX) deposits. Host rock assemblages, textural relationships in sulfide minerals and hydrothermal alteration mineralogy are the best tools for distinguishing SEDEX from VMS deposits (Robb, 2005).
There is a subclass of VMS deposits, the volcanic- and sediment-hosted massive sulfide (VSHMS) deposits, that do share characteristics that are hybrid between the VMS and SEDEX deposits. Notable examples of this class include the deposits of the Bathurst Camp, New Brunswick
New Brunswick
New Brunswick is one of Canada's three Maritime provinces and is the only province in the federation that is constitutionally bilingual . The provincial capital is Fredericton and Saint John is the most populous city. Greater Moncton is the largest Census Metropolitan Area...
, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...
(e.g., Brunswick #12); the deposits of the Iberian Pyrite Belt, Portugal
Portugal
Portugal , officially the Portuguese Republic is a country situated in southwestern Europe on the Iberian Peninsula. Portugal is the westernmost country of Europe, and is bordered by the Atlantic Ocean to the West and South and by Spain to the North and East. The Atlantic archipelagos of the...
and Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...
, and the Wolverine deposit, Yukon
Yukon
Yukon is the westernmost and smallest of Canada's three federal territories. It was named after the Yukon River. The word Yukon means "Great River" in Gwich’in....
, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...
.
Genetic model
- The source of metal and sulfur in VMS deposits is a combination of incompatible elements that are leached from footwall rocks in the sub-seafloor hydrothermal alteration zone by hydrothermal circulation. In some deposits magmatic fluids have been suggested to be an additional source of metals and fluids. Hydrothermal circulation is generally considered to be driven via heat in the crust often related to deep-seated igneous intrusions.
- Transport of metals occurs via convection of hydrothermal fluids, the heat for this supplied by the magmaMagmaMagma is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and is expected to exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and dissolved gas and sometimes also gas bubbles. Magma often collects in...
chamber and subvolcanic intrusions that lie below the volcanic edifice. Cool ocean water is drawn into the hydrothermal zone and is heated by the volcanic rock and is then expelled into the ocean, the process enriching the hydrothermal fluid in sulfur and metal ions. - The ore materials are precipitated within a fumaroleFumaroleA fumarole is an opening in a planet's crust, often in the neighborhood of volcanoes, which emits steam and gases such as carbon dioxide, sulfur dioxide, hydrochloric acid, and hydrogen sulfide. The steam is created when superheated water turns to steam as its pressure drops when it emerges from...
field or a black smoker field when they are expelled into the ocean, cool and mix with seawater resulting in the precipitation of sulfide minerals as stratiform sulfide ore. Some deposits show evidence of formation via deposition of sulfide via replacement of volcanosedimentary or sedimentary rocks, whereas others may also form by invasion of sulfur-rich brines into unconsolidated sediments.
Geology
The typical location for VMS deposits is at the top of the felsic volcanic sequence, within a sequence of volcaniclastic tuffaceous epiclastics, cherts, sediments or perhaps fine tuffs which are usually related to the underlying volcanics. The hangingwall to the deposit is broadly related to a more maficMafic
Mafic is an adjective describing a silicate mineral or rock that is rich in magnesium and iron; the term is a portmanteau of the words "magnesium" and "ferric". Most mafic minerals are dark in color and the relative density is greater than 3. Common rock-forming mafic minerals include olivine,...
sequence of volcanic rocks, either Andesite (examples being Whim Creek & Mons Cupri, Western Australia or Millenbach, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...
), or basalt (Hellyer, Tasmania
Tasmania
Tasmania is an Australian island and state. It is south of the continent, separated by Bass Strait. The state includes the island of Tasmania—the 26th largest island in the world—and the surrounding islands. The state has a population of 507,626 , of whom almost half reside in the greater Hobart...
) or absent or sediments only (Kangaroo Caves, Western Australia).
VMS deposits are associated spatially and temporally with felsic
Felsic
The word "felsic" is a term used in geology to refer to silicate minerals, magma, and rocks which are enriched in the lighter elements such as silicon, oxygen, aluminium, sodium, and potassium....
volcanic rocks, usually present in the stratigraphy below the deposit, and often as the direct footwall to the deposit. Sediments are usually contiguous with VMS deposits in some form or another and typically are present as (manganiferous) chert
Chert
Chert is a fine-grained silica-rich microcrystalline, cryptocrystalline or microfibrous sedimentary rock that may contain small fossils. It varies greatly in color , but most often manifests as gray, brown, grayish brown and light green to rusty red; its color is an expression of trace elements...
s, volcanogenic tuffaceous sediments and chemical sediments deposited within a submarine environment.
The hanging wall to the deposit can be volcanic units essentially contiguous and contemporary with the footwall rocks, indicating mineralisation was developed in an inter-eruptive pause; it may be volcanic rock dissimilar to the footwall volcanics in bimodal volcanic
Bimodal volcanism
Bimodal volcanism refers to the eruption of both mafic and felsic lavas from a single volcanic centre with little or no lavas of intermediate composition...
subtypes, or it could be sedimentary strata if mineralisation occurred toward the end of an eruptive cycle.
Hybrid VMS-SEDEX deposits of the siliciclastic associations (see below) may be developed within interflow sediments or within units of sedimentary rocks which are present discontinuously throughout a larger and essentially contiguous volcanic package.
Altogether, these geological features have been interpreted to show an association of VMS deposits with hydrothermal systems developed above or around submarine volcanic centres.
Morphology
VMS deposits have a wide variety of morphologies, with mound shaped and bowl shaped deposits most typical. The bowl-shaped formations formed due to venting of hydrothermal solutions into submarine depressions - in many cases, this type of deposit can be confused with sedimentary exhalative depositsSedimentary exhalative deposits
Sedimentary exhalative deposits are ore deposits which are interpreted to have been formed by release of ore-bearing hydrothermal fluids into a water reservoir , resulting in the precipitation of stratiform ore....
. The mound-shaped deposits formed in a way similar to that of modern massive sulfide deposits - via production of a hydrothermal mound formed by successive black smoker chimneys. Deposits that have formed in environments dominated by sedimentary rocks or highly permeable volcanic rocks can show a tabular morphology that mimics the geometry of the surrounding rocks.
VMS deposits have an ideal form of a conical area of highly altered
Metasomatism
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids.Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact...
volcanic or volcanogenic sedimentary rock within the feeder zone, which is called the stringer sulfide or stockwork zone, overlain by a mound of massive exhalites, and flanked by stratiform exhalative sulfides known as the apron.
The stockwork
Stockwork
In geology, a stockwork is a complex system of structurally controlled or randomly oriented veins. Stockworks are common in many ore deposit types and especially notable in greisens. They are also referred to as stringer zones....
zone typically consists of vein
Vein (geology)
In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation...
-hosted sulfides (mostly chalcopyrite
Chalcopyrite
Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite...
, pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...
, and pyrrhotite
Pyrrhotite
Pyrrhotite is an unusual iron sulfide mineral with a variable iron content: FeS . The FeS endmember is known as troilite. Pyrrhotite is also called magnetic pyrite because the color is similar to pyrite and it is weakly magnetic...
) with quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...
, chlorite
Chlorite group
The chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the following four elements in the silicate lattice; Mg, Fe, Ni, and Mn....
and lesser carbonates
Carbonate minerals
Carbonate minerals are those minerals containing the carbonate ion: CO32-.-Anhydrous carbonates:*Calcite group: Trigonal**Calcite CaCO3**Gaspeite CO3**Magnesite MgCO3**Otavite CdCO3**Rhodochrosite MnCO3**Siderite FeCO3**Smithsonite ZnCO3...
and barite
Barite
Baryte, or barite, is a mineral consisting of barium sulfate. The baryte group consists of baryte, celestine, anglesite and anhydrite. Baryte itself is generally white or colorless, and is the main source of barium...
.
The mound zone consists of laminated massive to breccia
Breccia
Breccia is a rock composed of broken fragments of minerals or rock cemented together by a fine-grained matrix, that can be either similar to or different from the composition of the fragments....
ted pyrite, sphalerite
Sphalerite
Sphalerite is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides...
(+/-galena
Galena
Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...
), hematite
Hematite
Hematite, also spelled as haematite, is the mineral form of iron oxide , one of several iron oxides. Hematite crystallizes in the rhombohedral system, and it has the same crystal structure as ilmenite and corundum...
, and barite. The mound can be up to several tens of metres thick and several hundred metres in diameter.
The apron zone is generally more oxidised
Redox
Redox reactions describe all chemical reactions in which atoms have their oxidation state changed....
, with stratiform, laminated sulfidic sediments, similar to SEDEX
Sedimentary exhalative deposits
Sedimentary exhalative deposits are ore deposits which are interpreted to have been formed by release of ore-bearing hydrothermal fluids into a water reservoir , resulting in the precipitation of stratiform ore....
ores, and is generally manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
, barium and hematite enriched, with chert
Chert
Chert is a fine-grained silica-rich microcrystalline, cryptocrystalline or microfibrous sedimentary rock that may contain small fossils. It varies greatly in color , but most often manifests as gray, brown, grayish brown and light green to rusty red; its color is an expression of trace elements...
s, jasper
Jasper
Jasper, a form of chalcedony, is an opaque, impure variety of silica, usually red, yellow, brown or green in color; and rarely blue. This mineral breaks with a smooth surface, and is used for ornamentation or as a gemstone. It can be highly polished and is used for vases, seals, and at one time for...
s and chemical sediments common.
Metal zonation
Most VMS deposits show metal zonation, caused by the changing physical and chemical environments of the circulating hydrothermal fluid within the wall rock. Ideally, this forms a core of massive pyritePyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...
and chalcopyrite
Chalcopyrite
Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite...
around the throat of the vent system, with a halo of chalcopyrite-sphalerite
Sphalerite
Sphalerite is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides...
-pyrite grading into a distal sphalerite-galena
Galena
Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...
and galena-manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
and finally a chert
Chert
Chert is a fine-grained silica-rich microcrystalline, cryptocrystalline or microfibrous sedimentary rock that may contain small fossils. It varies greatly in color , but most often manifests as gray, brown, grayish brown and light green to rusty red; its color is an expression of trace elements...
-manganese-hematite
Hematite
Hematite, also spelled as haematite, is the mineral form of iron oxide , one of several iron oxides. Hematite crystallizes in the rhombohedral system, and it has the same crystal structure as ilmenite and corundum...
facies. Most VMS deposits show a vertical zonation of gold
Gold
Gold is a chemical element with the symbol Au and an atomic number of 79. Gold is a dense, soft, shiny, malleable and ductile metal. Pure gold has a bright yellow color and luster traditionally considered attractive, which it maintains without oxidizing in air or water. Chemically, gold is a...
, with the cooler upper portions generally more enriched in gold and silver.
The mineralogy
Mineralogy
Mineralogy is the study of chemistry, crystal structure, and physical properties of minerals. Specific studies within mineralogy include the processes of mineral origin and formation, classification of minerals, their geographical distribution, as well as their utilization.-History:Early writing...
of VMS massive sulfide consists of over 90% iron sulfide, mainly in the form of pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...
, with chalcopyrite
Chalcopyrite
Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite...
, sphalerite
Sphalerite
Sphalerite is a mineral that is the chief ore of zinc. It consists largely of zinc sulfide in crystalline form but almost always contains variable iron. When iron content is high it is an opaque black variety, marmatite. It is usually found in association with galena, pyrite, and other sulfides...
and galena
Galena
Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...
also being major constituents. Magnetite
Magnetite
Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...
is present in minor amounts; as magnetite content increases, the ores grade into massive oxide deposits. The gangue
Gangue
In mining, gangue is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. The separation of mineral from gangue is known as mineral processing, mineral dressing or ore dressing and it is a necessary and often significant aspect of mining...
(the uneconomic waste material) is mainly quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...
and pyrite
Pyrite
The mineral pyrite, or iron pyrite, is an iron sulfide with the formula FeS2. This mineral's metallic luster and pale-to-normal, brass-yellow hue have earned it the nickname fool's gold because of its resemblance to gold...
or pyrrhotite
Pyrrhotite
Pyrrhotite is an unusual iron sulfide mineral with a variable iron content: FeS . The FeS endmember is known as troilite. Pyrrhotite is also called magnetic pyrite because the color is similar to pyrite and it is weakly magnetic...
. Due to the high density of the deposits some have marked gravity anomalies (Neves-Corvo, Portugal
Portugal
Portugal , officially the Portuguese Republic is a country situated in southwestern Europe on the Iberian Peninsula. Portugal is the westernmost country of Europe, and is bordered by the Atlantic Ocean to the West and South and by Spain to the North and East. The Atlantic archipelagos of the...
) which is of use in exploration.
Alteration morphology
Alteration haloes developed by VMS deposits are typically conical in shape, occur mostly stratigraphically below the original fluid flow location (not necessarily the ore itself), and are typically zoned.The most intense alteration (containing the stringer sulfide zone) is generally located directly underneath the greatest concentration of massive sulfides, within the footwall volcanic sequence. If the stringer zone is displaced from the sulfides, it is often the product of tectonic deformation, or the formation of a hybrid SEDEX-like distal pool of sulfides.
The alteration assemblages of the footwall alteration zone is, from core outwards;
- Silica alteration zone, found in the most intensely altered examples, resulting in complete silica replacement of the host rocks, and associated with chalcopyrite-pyrite stringer zones.
- Chlorite zone, found in nearly all examples, consisting of chlorite +/- sericite +/- silica. Often the host rock is entirely replaced by chlorite, which may appear as a chlorite schist in deformed examples.
- Sericite zone, found in nearly all examples, consisting of sericite +/- chlorite +/- silica,
- Silicification zone, often gradational with background silica-albite metasomatism.
In all cases these alteration zones are metasomatism
Metasomatism
Metasomatism is the chemical alteration of a rock by hydrothermal and other fluids.Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact...
effects in the strictest sense, resulting in addition of potassium, silica, magnesium, and depletion of sodium. Chlorite minerals are usually more magnesian in composition within the footwall alteration zone of a VMS deposit than equivalent rocks within the same formation distally. The hangingwall to a VMS deposit is often weakly sodium depleted.
Alteration not associated with the ore forming process may also be omnipresent both above and below the massive sulfide deposit. Typical alteration textures
Rock microstructure
Rock microstructure includes the texture of a rock and the small scale rock structures. The words "texture" and "microstructure" are interchangeable, with the latter preferred in modern geological literature...
associated with devitrification of submarine volcanic rocks such as rhyolitic glasses
Obsidian
Obsidian is a naturally occurring volcanic glass formed as an extrusive igneous rock.It is produced when felsic lava extruded from a volcano cools rapidly with minimum crystal growth...
, notably formation of spherulites, of perlite
Perlite
Perlite is an amorphous volcanic glass that has a relatively high water content, typically formed by the hydration of obsidian. It occurs naturally and has the unusual property of greatly expanding when heated sufficiently...
, lithophysae, and low-temperature prehnite-pumpellyite facies sub-seafloor alteration is ubiquitous though often overprinted by later metamorphic events.
Metamorphic mineralogical, textural and structural changes within the host volcanic sequence may also further serve to disguise original metasomatic mineral assemblages.
Classification
Deposits of this class have been classified by numerous workers in different ways (e.g., metal sources, type examples, geodynamic setting - see Franklin et al. (1981) and Lydon (1984)). Recently, VMS deposits have been classified according to their setting and rock associations into five subclasses, including (after Barrie and Hannington (1999) and Franklin et al. (2005)):Mafic Associated
VMS deposits associated with geological environments dominated by mafic rocks, commonly ophiolite sequences. The CyprusCyprus
Cyprus , officially the Republic of Cyprus , is a Eurasian island country, member of the European Union, in the Eastern Mediterranean, east of Greece, south of Turkey, west of Syria and north of Egypt. It is the third largest island in the Mediterranean Sea.The earliest known human activity on the...
, Oman
Oman
Oman , officially called the Sultanate of Oman , is an Arab state in southwest Asia on the southeast coast of the Arabian Peninsula. It is bordered by the United Arab Emirates to the northwest, Saudi Arabia to the west, and Yemen to the southwest. The coast is formed by the Arabian Sea on the...
ophiolites host examples and ophiolite-hosted deposits are found in the Newfoundland Appalachians
Appalachian Mountains
The Appalachian Mountains #Whether the stressed vowel is or ,#Whether the "ch" is pronounced as a fricative or an affricate , and#Whether the final vowel is the monophthong or the diphthong .), often called the Appalachians, are a system of mountains in eastern North America. The Appalachians...
represent classic districts of this subclass
Bimodal-mafic
VMS deposits associated with environments dominated by mafic volcanic rocks, but with up to 25% felsic volcanic rocks, the latter often hosting the deposits. The Noranda, Flin Flon-Snow Lake and Kidd Creek camps would be classic districts of this groupMafic-siliciclastic
VMS deposits associated with sub-equal proportions of mafic volcanic and siliciclastic rocks; felsic rocks can be a minor component; and mafic (and ultramafic) intrusive rocks are common. In metamorphic terranes may be known as or pelitic-mafic associated VMS deposits. The Besshi deposits in Japan and Windy Craggy, BC represent classic districts of this group.Felsic-siliciclastic
VMS deposits associated with siliciclastic sedimentary rock dominated settings with abundant felsic rocks and less than 10% mafic material. These settings are often shale-rich siliciclastic-felsic or bimodal siliciclastic. The Bathurst camp, New Brunswick, Canada; Iberian Pyrite Belt, Spain and Portugal; and Finlayson Lake areas, Yukon, Canada are classic districts of this groupBimodal-felsic
VMS deposits associated with bimodal sequences where felsic rocks are in greater abundance than mafic rocks with only minor sedimentary rocks. The Kuroko deposits, Japan; Buchans deposits, Canada; and Skellefte deposits, SwedenSweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....
are classic districts of this group.
Distribution
The majority of VMS deposits were formed in riftRift
In geology, a rift or chasm is a place where the Earth's crust and lithosphere are being pulled apart and is an example of extensional tectonics....
environments associated with volcanic rocks, often associated with mid-ocean ridge spreading centres, back-arc spreading centres, and forearc spreading centres. A theme common to VMS deposits through time is the association with spreading (i.e., an extensional geodynamic regime). The deposits are typically associated with bimodal sequences (sequences with subequal percentages of mafic and felsic rocks - e.g., Noranda or Kuroko), felsic and sediment-rich environments (e.g., Bathurst), mafic and sediment-rich environments (e.g., Besshi or Windy Craggy), or mafic-dominated settings (e.g., Cyprus
Cyprus
Cyprus , officially the Republic of Cyprus , is a Eurasian island country, member of the European Union, in the Eastern Mediterranean, east of Greece, south of Turkey, west of Syria and north of Egypt. It is the third largest island in the Mediterranean Sea.The earliest known human activity on the...
and other ophiolite hosted deposits).
The majority of world deposits are small, with about 80% of known deposits in the range 0.1-10 Mt. Examples of VMS deposits are Kidd Creek
Kidd creek
Kidd Mine an underground base metal mine in the city of Timmins, Ontario, Canada. It is owned and operated by Xstrata Copper, following the August 2006 takeover of Falconbridge Ltd. Ore from the Kidd mine is processed at the Kidd Metallurgical Site, located southeast of the mine...
in the Abitibi greenstone belt
Abitibi greenstone belt
The Abitibi greenstone belt is a 2,800-2,600 million year old greenstone belt that spans across the Ontario-Quebec border in Canada. It is mostly made of volcanic rocks, but also includes ultramafic rocks, mafic intrusions, granitoid rocks, and early and middle Precambrian sediments.-Geographical...
, Ontario
Ontario
Ontario is a province of Canada, located in east-central Canada. It is Canada's most populous province and second largest in total area. It is home to the nation's most populous city, Toronto, and the nation's capital, Ottawa....
, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...
; Flin Flon
Flin Flon
Flin Flon is a Canadian mining city located on the border of Manitoba and Saskatchewan, with the majority of the city located within Manitoba.- Founding :...
in the Flin Flon greenstone belt
Flin Flon greenstone belt
The Flin Flon greenstone belt, also referred to as the Flin Flon-Snow Lake greenstone belt, is a Precambrian greenstone belt located in the central area of Manitoba and east-central Saskatchewan, Canada . It lies in the central portion of the Trans-Hudson orogeny and was formed by arc volcanism...
, Manitoba
Manitoba
Manitoba is a Canadian prairie province with an area of . The province has over 110,000 lakes and has a largely continental climate because of its flat topography. Agriculture, mostly concentrated in the fertile southern and western parts of the province, is vital to the province's economy; other...
, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...
(777 and Trout Lake Mine); Brunswick #12, New Brunswick
New Brunswick
New Brunswick is one of Canada's three Maritime provinces and is the only province in the federation that is constitutionally bilingual . The provincial capital is Fredericton and Saint John is the most populous city. Greater Moncton is the largest Census Metropolitan Area...
, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...
; Rio Tinto, Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...
; Greens Creek mine, Alaska
Alaska
Alaska is the largest state in the United States by area. It is situated in the northwest extremity of the North American continent, with Canada to the east, the Arctic Ocean to the north, and the Pacific Ocean to the west and south, with Russia further west across the Bering Strait...
, U.S..