Plasticizer
Encyclopedia
Plasticizers or dispersant
Dispersant
A dispersant or a dispersing agent or a plasticizer or a superplasticizer is either a non-surface active polymer or a surface-active substance added to a suspension, usually a colloid, to improve the separation of particles and to prevent settling or clumping...

s
are additives that increase the plasticity
Plasticity (physics)
In physics and materials science, plasticity describes the deformation of a material undergoing non-reversible changes of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the...

 or fluidity
Fluidity
Fluidity may refer toIn science*reciprocal of viscosity*Cognitive fluidity*Membrane fluidity*Sexual fluidityOthers*Fluidity *Dark Fluidity – a literature magazine*Empire Fane ship...

 of the material to which they are added; these include plastics, cement, concrete, wallboard, and clay. Although the same compounds are often used for both plastics and concretes the desired effects and results are different. The worldwide market for plasticizers in 2004 had a total volume of around 5.5 million tons, which led to a turnover of just over 6 billion pounds.

Plasticizers for concrete
Concrete
Concrete is a composite construction material, composed of cement and other cementitious materials such as fly ash and slag cement, aggregate , water and chemical admixtures.The word concrete comes from the Latin word...

 increase the workability of the wet mix, or reduce the water required to achieve the desired workability, and are usually not intended to affect the properties of the final product after it hardens.

Plasticizers for wallboard increase fluidity of the mix, allowing lower use of water and thus reducing energy to dry the board.

Plasticizers for plastics soften the final product increasing its flexibility.

For concrete production

Plasticizers or water reducers, and superplasticizer
Superplasticizer
Superplasticizers, also known as high range water reducers, are chemicals used as admixtures where well-dispersed particle suspension are required. These polymers are used as dispersants to avoid particle aggregation, and to improve the flow characteristics of suspensions such as in concrete...

 or high range water reducers, are chemical admixtures

that can be added to concrete
Concrete
Concrete is a composite construction material, composed of cement and other cementitious materials such as fly ash and slag cement, aggregate , water and chemical admixtures.The word concrete comes from the Latin word...

 mixtures to improve workability. Unless the mix is "starved" of water, the strength of concrete is inversely proportional to the amount of water added or water-cement (w/c) ratio. In order to produce stronger concrete, less water is added (without "starving" the mix), which makes the concrete mixture less workable and difficult to mix, necessitating the use of plasticizers, water reducers, superplasticizers or dispersants.

Plasticizers are also often used when pozzolanic ash is added to concrete to improve strength. This method of mix proportioning is especially popular when producing high-strength concrete and fiber-reinforced concrete.

Adding 1-2% plasticizer per unit weight of cement is usually sufficient. Adding an excessive amount of plasticizer will result in excessive segregation
Particle segregation
In Particle Segregation particulate solids tend to segregate by virtue of differences in the size, density, shape and other properties of particles of which they are composed. The process of segregation occurs during as well as during subsequent handling of completed mix and it is pronounced with...

 of concrete and is not advisable. Depending on the particular chemical used, use of too much plasticizer may result in a retarding effect.

Plasticizers are commonly manufactured from pop lignosulfonates, a by-product from the paper
Paper
Paper is a thin material mainly used for writing upon, printing upon, drawing or for packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....

 industry. Superplasticizers have generally been manufactured from sulfonated
Sulfonic acid
Sulfonic acid usually refers to a member of the class of organosulfur compounds with the general formula RS2–OH, where R is an alkyl or aryl. The formal part of acid, HS2–OH, are formally derivatives of the "parent" inorganic compound with the formula HSO2.-Preparation:Sulfonic acid is...

 naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...

 condensate or sulfonated melamine
Melamine
Melamine is an organic base and a trimer of cyanamide, with a 1,3,5-triazine skeleton. Like cyanamide, it contains 66% nitrogen by mass and, if mixed with resins, has fire retardant properties due to its release of nitrogen gas when burned or charred, and has several other industrial uses....

 formaldehyde, although newer products based on polycarboxylic ethers are now available. Traditional lignosulfonate-based plasticisers, naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...

 and melamine
Melamine
Melamine is an organic base and a trimer of cyanamide, with a 1,3,5-triazine skeleton. Like cyanamide, it contains 66% nitrogen by mass and, if mixed with resins, has fire retardant properties due to its release of nitrogen gas when burned or charred, and has several other industrial uses....

 sulfonate-based superplasticisers disperse the flocculated cement particles through a mechanism of electrostatic repulsion (see colloid
Colloid
A colloid is a substance microscopically dispersed evenly throughout another substance.A colloidal system consists of two separate phases: a dispersed phase and a continuous phase . A colloidal system may be solid, liquid, or gaseous.Many familiar substances are colloids, as shown in the chart below...

). In normal plasticisers, the active substances are adsorbed
Adsorption
Adsorption is the adhesion of atoms, ions, biomolecules or molecules of gas, liquid, or dissolved solids to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. It differs from absorption, in which a fluid permeates or is dissolved by a liquid or solid...

 on to the cement particles, giving them a negative charge, which leads to repulsion between particles. Lignin
Lignin
Lignin or lignen is a complex chemical compound most commonly derived from wood, and an integral part of the secondary cell walls of plants and some algae. The term was introduced in 1819 by de Candolle and is derived from the Latin word lignum, meaning wood...

, naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...

 and melamine
Melamine
Melamine is an organic base and a trimer of cyanamide, with a 1,3,5-triazine skeleton. Like cyanamide, it contains 66% nitrogen by mass and, if mixed with resins, has fire retardant properties due to its release of nitrogen gas when burned or charred, and has several other industrial uses....

 sulfonate superplasticisers are organic polymers. The long molecules wrap themselves around the cement particles, giving them a highly negative charge so that they repel each other.

Polycarboxylate ether superplasticizer
Superplasticizer
Superplasticizers, also known as high range water reducers, are chemicals used as admixtures where well-dispersed particle suspension are required. These polymers are used as dispersants to avoid particle aggregation, and to improve the flow characteristics of suspensions such as in concrete...

 (PCE) or just polycarboxylate (PC), work differently from sulfonate-based superplasticizers, giving cement dispersion by steric stabilisation, instead of electrostatic repulsion. This form of dispersion is more powerful in its effect and gives improved workability retention to the cementitious mix.

In ancient times, the Romans
Ancient Rome
Ancient Rome was a thriving civilization that grew on the Italian Peninsula as early as the 8th century BC. Located along the Mediterranean Sea and centered on the city of Rome, it expanded to one of the largest empires in the ancient world....

 used animal fat, milk and blood
Blood
Blood is a specialized bodily fluid in animals that delivers necessary substances such as nutrients and oxygen to the cells and transports metabolic waste products away from those same cells....

 to improve workability of concrete mixes.

For gypsum wallboard production

Plasticizers or dispersant
Dispersant
A dispersant or a dispersing agent or a plasticizer or a superplasticizer is either a non-surface active polymer or a surface-active substance added to a suspension, usually a colloid, to improve the separation of particles and to prevent settling or clumping...

s
, are chemical additives that can be added to wallboard stucco mixtures to improve workability. In order to reduce the energy in drying wallboard, less water is added, which makes the gypsum mixture very unworkable and difficult to mix, necessitating the use of plasticizers, water reducers or dispersants.

Adding about two pounds of dispersant per thousand square feet (MSF) in 1/2 inch wallboard (15 g/m² of wallboard) is usually sufficient. Some studies also show that too much of lignosulfonate dispersant could result in a set-retarding effect. Data showed that amorphous crystal formations occurred that detracted from the mechanical needle-like crystal interaction in the core, preventing a stronger core. The sugars, chelating agents in lignosulfonates such as aldonic acids and extractive compounds are mainly responsible for set retardation. These low range water reducing dispersants are commonly manufactured from lignosulfonates, a by-product from the paper
Paper
Paper is a thin material mainly used for writing upon, printing upon, drawing or for packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....

 industry.

High range superplasticizers (dispersants) have generally been manufactured from sulfonated
Sulfonic acid
Sulfonic acid usually refers to a member of the class of organosulfur compounds with the general formula RS2–OH, where R is an alkyl or aryl. The formal part of acid, HS2–OH, are formally derivatives of the "parent" inorganic compound with the formula HSO2.-Preparation:Sulfonic acid is...

 naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...

 condensate, although new generation products based on polycarboxylic ethers are now available. These high range water reducers are used at 1/2 to 1/3 of the lignosulfonate types.

Traditional lignosulfonate and naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...

 sulfonate based plasticisers disperse the flocculated gypsum particles through a mechanism of electrostatic repulsion (see colloid
Colloid
A colloid is a substance microscopically dispersed evenly throughout another substance.A colloidal system consists of two separate phases: a dispersed phase and a continuous phase . A colloidal system may be solid, liquid, or gaseous.Many familiar substances are colloids, as shown in the chart below...

). In normal plasticisers, the active substances are adsorbed
Adsorption
Adsorption is the adhesion of atoms, ions, biomolecules or molecules of gas, liquid, or dissolved solids to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. It differs from absorption, in which a fluid permeates or is dissolved by a liquid or solid...

 on to the gypsum particles, giving them a negative charge, which leads to repulsion between particles. Lignin and naphthalene sulfonate plasticizers are organic polymers. The long molecules wrap themselves around the gypsum particles, giving them a highly negative charge so that they repel each other.

For plastics

Plasticizers for plastics are additives, most commonly phthalates, that give hard plastic
Plastic
A plastic material is any of a wide range of synthetic or semi-synthetic organic solids used in the manufacture of industrial products. Plastics are typically polymers of high molecular mass, and may contain other substances to improve performance and/or reduce production costs...

s like PVC
Polyvinyl chloride
Polyvinyl chloride, commonly abbreviated PVC, is a thermoplastic polymer. It is a vinyl polymer constructed of repeating vinyl groups having one hydrogen replaced by chloride. Polyvinyl chloride is the third most widely produced plastic, after polyethylene and polypropylene. PVC is widely used in...

 the desired flexibility and durability. They are often based on ester
Ester
Esters are chemical compounds derived by reacting an oxoacid with a hydroxyl compound such as an alcohol or phenol. Esters are usually derived from an inorganic acid or organic acid in which at least one -OH group is replaced by an -O-alkyl group, and most commonly from carboxylic acids and...

s of polycarboxylic acids with linear or branched aliphatic alcohols of moderate chain length. Plasticizers work by embedding themselves between the chains of polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...

s, spacing them apart (increasing the "free volume"), and thus significantly lowering the glass transition
Glass transition
The liquid-glass transition is the reversible transition in amorphous materials from a hard and relatively brittle state into a molten or rubber-like state. An amorphous solid that exhibits a glass transition is called a glass...

 temperature for the plastic and making it softer. For plastics such as PVC, the more plasticizer added, the lower its cold flex temperature will be. This means that it will be more flexible and its durability will increase as a result of it. Some plasticizers evaporate and tend to concentrate in an enclosed space; the "new car smell
New car smell
New-car smell is the common term for the odor that comes from the combination of materials found in new automobiles. Some people regard it as a pleasant and desirable smell. However, there is some question about whether the chemicals in the odour pose a health risk.- Chemical composition :Both the...

" is caused mostly by plasticizers evaporating from the car interior.

Ester plasticizers

Ester
Ester
Esters are chemical compounds derived by reacting an oxoacid with a hydroxyl compound such as an alcohol or phenol. Esters are usually derived from an inorganic acid or organic acid in which at least one -OH group is replaced by an -O-alkyl group, and most commonly from carboxylic acids and...

 plasticizers serve as plasticizers, softeners, extenders, and lubricants, esters play a significant role in rubber
Rubber
Natural rubber, also called India rubber or caoutchouc, is an elastomer that was originally derived from latex, a milky colloid produced by some plants. The plants would be ‘tapped’, that is, an incision made into the bark of the tree and the sticky, milk colored latex sap collected and refined...

 manufacturing. The basic function of an ester plasticizer is to modify a polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...

 or resin enhancing its utility. Ester plasticizers make it possible to achieve improved compound processing characteristics, while also providing flexibility in the end-use product. Ester plasticizers are selected based upon cost-performance evaluation. The rubber compounder must evaluate ester plasticizers for compatibility, processibility, permanence and other performance properties. The wide variety of ester chemistries that are in production include sebacates, adipates, gluterates, phthalates, azelates, and other specialty blends. This broad
product line provides an array of performance benefits required for the many elastomer applications such as tubing and
hose products, seals and gaskets, belts, wire and cable and print rolls. Low to high polarity esters provide utility in a wide range of elastomers including nitrile, polychloroprene, EPDM, chlorinated polyethylene, and epichlorohydrin. Plasticizer-elastomer
interaction is governed by many factors such as solubility parameter, molecular weight and chemical structure. Compatibility and performance attributes are key factors in developing a rubber formulation for a particular application.

Dicarboxylic/tricarboxylic ester-based plasticizers

  • Phthalate-based plasticizers are used in situations where good resistance to water and oils is required. Some common phthalate plasticizers are:
    • Bis(2-ethylhexyl) phthalate
      Bis(2-ethylhexyl) phthalate
      Bisphthalate, commonly abbreviated DEHP, is an organic compound with the formula C6H42. It is sometimes called dioctyl phthalate and abbreviated DOP. It is the most important "phthalate," being the diester of phthalic acid and the branched-chain 2-ethylhexanol. This colourless viscous liquid is...

       (DEHP), used in construction materials and medical devices
    • Diisononyl phthalate (DINP), found in garden hoses, shoes, toys, and building materials
    • Bis(n-butyl)phthalate (DnBP, DBP), used for cellulose plastics, food wraps, adhesives, perfumes, and cosmetics - about a third of nail polish
      Nail polish
      Nail polish, or nail varnish, is a lacquer applied to human fingernails or toenails to decorate and/or protect the nail plate.-History:...

      es, glosses, enamels, and hardeners contain it, together with some shampoo
      Shampoo
      Shampoo is a hair care product used for the removal of oils, dirt, skin particles, dandruff, environmental pollutants and other contaminant particles that gradually build up in hair...

      s, sunscreen
      Sunscreen
      Sunblock is a lotion, spray, gel or other topical product that absorbs or reflects some of the sun's ultraviolet radiation on the skin exposed to sunlight and thus helps protect against sunburn...

      s, skin emollients, and insect repellent
      Insect repellent
      An insect repellent is a substance applied to skin, clothing, or other surfaces which discourages insects from landing or climbing on that surface. There are also insect repellent products available based on sound production, particularly ultrasound...

      s
    • Butyl benzyl phthalate (BBzP) is found in vinyl tiles, traffic cones, food conveyor belt
      Conveyor belt
      A conveyor belt consists of two or more pulleys, with a continuous loop of material - the conveyor belt - that rotates about them. One or both of the pulleys are powered, moving the belt and the material on the belt forward. The powered pulley is called the drive pulley while the unpowered pulley...

      s, artificial leather
      Artificial leather
      Artificial leather is a fabric or finish intended to substitute for leather in fields such as upholstery, clothing and fabrics, and other uses where a leather-like finish is required but the actual material is cost-prohibitive or unsuitable....

      , and plastic foams
    • Diisodecyl phthalate
      Diisodecyl phthalate
      Diisodecyl phthalate is a commonly used plasticizer used in the production of plastic and plastic coating to increase flexibility...

       (DIDP), used for insulation of wires and cables, car undercoating, shoes, carpets, pool liners
    • Di-n-octyl phthalate (DOP or DnOP), used in flooring materials, carpets, notebook covers, and high explosives, such as Semtex
      Semtex
      Semtex is a general-purpose plastic explosive containing RDX and PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex became notoriously popular with terrorists because it was, until recently, extremely difficult to detect, as in the case of Pan Am...

      . Together with DEHP it was the most common plasticizers, but now is suspected of causing cancer
    • Diisooctyl phthalate (DIOP), all-purpose plasticizer for polyvinyl chloride, polyvinyl acetate, rubbers, cellulose plastics, and polyurethane.
    • Diethyl phthalate
      Diethyl phthalate
      Diethyl phthalate is a phthalate ester, namely the diethyl ester of phthalic acid. It is a clear substance that is liquid at room temperature and which does not occur in nature. It has a faint, disagreeable odor and can be transferred from the plastics that contain it...

       (DEP)
    • Diisobutyl phthalate
      Diisobutyl phthalate
      Diisobutyl Phthalate is prepared by esterification process of isobutanol and phthalic anhydride. Its structural formula is C6H42. Refractive index is 1.488 - 1.492 ....

       (DIBP)
    • Di-n-hexyl phthalate, used in flooring materials, tool handles, and automobile parts

  • Trimellitates are used in automobile interiors and other applications where resistance to high temperature is required. They have extremely low volatility.
    • Trimethyl trimellitate (TMTM)
    • Tri-(2-ethylhexyl) trimellitate (TEHTM-MG)
    • Tri-(n-octyl,n-decyl) trimellitate (ATM)
    • Tri-(heptyl,nonyl) trimellitate (LTM)
    • n-octyl trimellitate (OTM)

  • Adipate
    Adipate
    Adipate is the ionized form of adipic acid.As food additives, adipates are used as acidity regulators. Examples are sodium adipate and potassium adipate .-See also:* Acidity regulator...

    -based plasticizers are used for low-temperature or resistance to ultraviolet
    Ultraviolet
    Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...

     light. Some examples are:
    • Bis(2-ethylhexyl)adipate (DEHA)
    • Dimethyl adipate (DMAD)
    • Monomethyl adipate (MMAD)
    • Dioctyl adipate
      Dioctyl adipate
      Dioctyl adipate or DOA is a plasticizer. DOA is a diester of adipic acid and two equivalents of n-octanol. Its chemical formula is 22424.DEHA is sometimes incorrectly called dioctyl adipate....

       (DOA)

  • Sebacate-based plasticiser
    • Dibutyl sebacate
      Dibutyl sebacate
      Dibutyl sebacate is an organic chemical, a dibutyl ester of sebacic acid. Its main use is as a plasticizer in production of plastics, namely cellulose acetate butyrate, cellulose acetate propionate, ethyl cellulose, polyvinyl butyral, polyvinyl chloride, polystyrene, and many synthetic rubbers ...

       (DBS)

  • Maleates
    • Dibutyl maleate (DBM)
    • Diisobutyl maleate (DIBM)

Other plasticizers

  • Benzoates

  • Epoxidized
    Epoxide
    An epoxide is a cyclic ether with three ring atoms. This ring approximately defines an equilateral triangle, which makes it highly strained. The strained ring makes epoxides more reactive than other ethers. Simple epoxides are named from the parent compound ethylene oxide or oxirane, such as in...

     vegetable oils

  • Sulfonamide
    Sulfonamide (chemistry)
    In chemistry, the sulfonamide functional group is -S2-NH2, a sulfonyl group connected to an amine group.A sulfonamide is a compound that contains this group. The general formula is RSO2NH2, where R is some organic group. For example, "methanesulfonamide" is CH3SO2NH2...

    s
    • N-ethyl toluene sulfonamide (o/p ETSA), ortho and para isomers
    • N-(2-hydroxypropyl) benzene sulfonamide (HP BSA)
    • N-(n-butyl) benzene sulfonamide (BBSA-NBBS)

  • Organophosphate
    Organophosphate
    An organophosphate is the general name for esters of phosphoric acid. Phosphates are probably the most pervasive organophosphorus compounds. Many of the most important biochemicals are organophosphates, including DNA and RNA as well as many cofactors that are essential for life...

    s
    • Tricresyl phosphate
      Tricresyl phosphate
      Tricresyl phosphate, abbreviated TCP, is an organophosphate compound that is used as a plasticizer and diverse other applications. It is a colourless, viscous liquid, although commercial samples are typically yellow...

       (TCP)
    • Tributyl phosphate
      Tributyl phosphate
      Tributyl phosphate, known commonly as TBP, is an organophosphorus compound with the formula 3PO. This colourless, odorless liquid finds some applications as an extractant and a plasticizer. It is an ester of orthophosphoric acid with n-butanol.- Production :Tributyl phosphate is manufactured by...

       (TBP)

  • Glycols/polyethers
    • Triethylene glycol dihexanoate (3G6, 3GH)
    • Tetraethylene glycol diheptanoate (4G7)

  • Polymeric plasticizers
  • Polybutene
    Polybutene
    Polybutene and polyisobutylene are liquid oligomers widely used as plasticizers for high-molecular weight polymers, such as polyethylene. They are not to be confused with the high molecular weight polymer polybutene-1.-Properties:...



Some other chemicals working as plasticizers are nitrobenzene
Nitrobenzene
Nitrobenzene is an organic compound with the chemical formula C6H5NO2. It is a water-insoluble pale yellow oil with an almond-like odor. It freezes to give greenish-yellow crystals. It is produced on a large scale as a precursor to aniline. Although occasionally used as a flavoring or perfume...

, carbon disulfide
Carbon disulfide
Carbon disulfide is a colorless volatile liquid with the formula CS2. The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent...

 and β-naphthyl salicylate. Plasticizers, such as DEHP and DOA, were found to be carcinogen
Carcinogen
A carcinogen is any substance, radionuclide, or radiation that is an agent directly involved in causing cancer. This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes...

s and endocrine disruptor
Endocrine disruptor
Endocrine disruptors are chemicals that interfere with endocrine in animals, including humans. These disruptions can cause cancerous tumors, birth defects, and other developmental disorders...

s.

Safer plasticizers

Safer plasticizers with better biodegradability and fewer biochemical effects are being developed. Some such plasticizers are:
  • Acetylated monoglycerides; these can be used as food additive
    Food additive
    Food additives are substances added to food to preserve flavor or enhance its taste and appearance.Some additives have been used for centuries; for example, preserving food by pickling , salting, as with bacon, preserving sweets or using sulfur dioxide as in some wines...

    s

  • Alkyl citrate
    Citrate
    A citrate can refer either to the conjugate base of citric acid, , or to the esters of citric acid. An example of the former, a salt is trisodium citrate; an ester is triethyl citrate.-Other citric acid ions:...

    s, used in food packagings, medical products, cosmetics and children toys
    • Triethyl citrate
      Triethyl citrate
      Triethyl citrate is an ester of citric acid. It is a colorless, odorless liquid used as a food additive to stabilize foams, especially as whipping aid for egg white. It is also used in pharmaceutical coatings and plastics....

       (TEC)
    • Acetyl triethyl citrate (ATEC), higher boiling point and lower volatility than TEC
    • Tributyl citrate (TBC)
    • Acetyl tributyl citrate (ATBC), compatible with PVC and vinyl chloride copolymers
    • Trioctyl citrate (TOC), also used for gums and controlled release medicines
    • Acetyl trioctyl citrate (ATOC), also used for printing ink
      Ink
      Ink is a liquid or paste that contains pigments and/or dyes and is used to color a surface to produce an image, text, or design. Ink is used for drawing and/or writing with a pen, brush, or quill...

    • Trihexyl citrate (THC), compatible with PVC, also used for controlled release medicines
    • Acetyl trihexyl citrate (ATHC), compatible with PVC
    • Butyryl trihexyl citrate (BTHC, trihexyl o-butyryl citrate), compatible with PVC
    • Trimethyl citrate (TMC), compatible with PVC

  • alkyl sulphonic acid phenyl ester (ASE), compatible with PVC , vinyl chloride copolymers, TPU, NBR etc.

  • 1,2-Cyclohexane dicarboxylic acid diisononyl ester (BASF trademark: DINCH) is used in food packaging, medical devices, toy and childcare articles. It is compatible with a wide range of polymers including PVC.

Plasticizers for energetic materials

Energetic material
Energetic material
Energetic materials are a class of material with high amount of stored chemical energy that can be released.Typical classes of energetic materials are e.g. explosives, pyrotechnic compositions, propellants , and fuels ....

 pyrotechnic composition
Pyrotechnic composition
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions...

s, especially solid rocket propellant
Rocket propellant
Rocket propellant is mass that is stored in some form of propellant tank, prior to being used as the propulsive mass that is ejected from a rocket engine in the form of a fluid jet to produce thrust. A fuel propellant is often burned with an oxidizer propellant to produce large volumes of very hot...

s and smokeless powder
Smokeless powder
Smokeless powder is the name given to a number of propellants used in firearms and artillery which produce negligible smoke when fired, unlike the older gunpowder which they replaced...

s for guns, often employ plasticizers to improve physical properties of the propellant binder or of the overall propellant, to provide a secondary fuel, and ideally, to improve specific energy yield (e.g. specific impulse
Specific impulse
Specific impulse is a way to describe the efficiency of rocket and jet engines. It represents the derivative of the impulse with respect to amount of propellant used, i.e., the thrust divided by the amount of propellant used per unit time. If the "amount" of propellant is given in terms of mass ,...

, energy yield per gram of propellant, or similar indices) of the propellant. An energetic plasticizer improves the physical properties of an energetic material
Energetic material
Energetic materials are a class of material with high amount of stored chemical energy that can be released.Typical classes of energetic materials are e.g. explosives, pyrotechnic compositions, propellants , and fuels ....

 while also increasing its specific energy yield. Energetic plasticizers are usually preferred to non-energetic plasticizers, especially for solid rocket propellant
Rocket propellant
Rocket propellant is mass that is stored in some form of propellant tank, prior to being used as the propulsive mass that is ejected from a rocket engine in the form of a fluid jet to produce thrust. A fuel propellant is often burned with an oxidizer propellant to produce large volumes of very hot...

s. Energetic plasticizers reduce the required mass of propellant, enabling a rocket vehicle to carry more payload or reach higher velocities than would otherwise be the case. However, safety or cost considerations may demand that non-energetic plasticizers be used, even in rocket propellants. The solid rocket propellant
Rocket propellant
Rocket propellant is mass that is stored in some form of propellant tank, prior to being used as the propulsive mass that is ejected from a rocket engine in the form of a fluid jet to produce thrust. A fuel propellant is often burned with an oxidizer propellant to produce large volumes of very hot...

 used to fuel the Space Shuttle
Space Shuttle
The Space Shuttle was a manned orbital rocket and spacecraft system operated by NASA on 135 missions from 1981 to 2011. The system combined rocket launch, orbital spacecraft, and re-entry spaceplane with modular add-ons...

 solid rocket booster
Solid rocket booster
Solid rocket boosters or Solid Rocket Motors, SRM, are used to provide thrust in spacecraft launches from the launchpad up to burnout of the SRBs. Many launch vehicles include SRBs, including the Ariane 5, Atlas V , and the NASA Space Shuttle...

 employs a non-energetic plasticizer/binder/secondary fuel: HTPB. HTPB is a synthetic rubber
Synthetic rubber
Synthetic rubber is is any type of artificial elastomer, invariably a polymer. An elastomer is a material with the mechanical property that it can undergo much more elastic deformation under stress than most materials and still return to its previous size without permanent deformation...

.
Here are some energetic plasticizers used in rocket propellant
Rocket propellant
Rocket propellant is mass that is stored in some form of propellant tank, prior to being used as the propulsive mass that is ejected from a rocket engine in the form of a fluid jet to produce thrust. A fuel propellant is often burned with an oxidizer propellant to produce large volumes of very hot...

s and smokeless powder
Smokeless powder
Smokeless powder is the name given to a number of propellants used in firearms and artillery which produce negligible smoke when fired, unlike the older gunpowder which they replaced...

s:
  • Nitroglycerine (NG, aka "nitro", glyceryl trinitrate)
  • Butanetriol trinitrate (BTTN)
  • Dinitrotoluene
    Dinitrotoluene
    2,4-Dinitrotoluene or Dinitro is an organic compound with the formula C6H32. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene but is mainly used in the polymer industry....

     (DNT)
  • Trimethylolethane trinitrate
    Trimethylolethane trinitrate
    Trimethylolethane trinitrate , also known as metriol trinitrate or nitropentaglycerin, is a nitro ester. It is a high explosive similar to nitroglycerin. It is a transparent oily liquid, colorless to light brown. It is odorless. It is used in some solid propellants and smokeless powders as a...

     (TMETN, aka Metriol trinitrate, METN)
  • Diethylene glycol dinitrate
    Diethylene glycol dinitrate
    Diethylene glycol dinitrate is a nitrated alcohol ester produced by the action of concentrated nitric acid, normally admixed with an excess of strong sulfuric acid as a dehydrating agent, upon diethylene glycol....

     (DEGDN, less commonly DEGN)
  • Triethylene glycol dinitrate
    Triethylene glycol dinitrate
    Triethylene glycol dinitrate is a nitrated alcohol ester of triethylene glycol. It is used as an energetic plasticizer in explosives and propellants. Its chemical formula is O2N-O-CH2CH2-O-CH2CH2-O-CH2CH2-O-NO2. It is a pale yellow oily liquid...

     (TEGDN, less commonly TEGN)
  • Bis(2,2-dinitropropyl)formal (BDNPF)
  • Bis(2,2-dinitropropyl)acetal (BDNPA)
  • 2,2,2-Trinitroethyl 2-nitroxyethyl ether (TNEN)

Due to the secondary alcohol groups, NG and BTTN have relatively low thermal stability. TMETN, DEGDN, BDNPF and BDNPA have relatively low energies. NG and DEGN have relatively high vapor pressure
Vapor pressure
Vapor pressure or equilibrium vapor pressure is the pressure of a vapor in thermodynamic equilibrium with its condensed phases in a closed system. All liquids have a tendency to evaporate, and some solids can sublimate into a gaseous form...

. http://www.freepatentsonline.com/4745208.html

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