Zinc borate
Encyclopedia
Zinc borate is an inorganic compound
, a borate
of zinc
. It is a white crystalline or amorphous powder insoluble in water. Its toxicity is low. Its melting point is 980 °C.
Several variants of zinc borate exist, differing by the zinc/boron ratio and the water content:
The hydrated variants lose water between 290–415 °C.
Zinc borate is primarily used as a flame retardant
in plastic
s and cellulose fiber
s, paper
, rubber
s and textile
s. It is also used in paint
s, adhesive
s, and pigment
s. As a flame retardant, it can replace antimony trioxide
as a synergist in both halogen-based and halogen-free systems. It is an anti-dripping and char-promoting agent, and suppresses the afterglow. In electrical insulator plastics it suppresses arcing and tracking
.
In halogen-containing systems, zinc borate is used together with antimony trioxide
and alumina trihydrate. It catalyzes formation of char and creates a protective layer of glass. Zinc catalyzes the release of halogens by forming zinc halides and zinc oxyhalides.
In halogen-free system, zinc borate can be used together with alumina trihydrate, magnesium hydroxide
, red phosphorus, or ammonium polyphosphate
. During burning the plastics, a porous borate ceramics is formed that protects the underlying layers. In presence of silica, borosilicate glass
can be formed at plastic burning temperatures.
Zinc borate is used in polyvinyl chloride
, polyolefin
s, polyamides, epoxy
resins, polyester
s, thermoplastic elastomer
s, rubber
s, etc. It is also used in some intumescent
systems.
Zinc borate has synergistic effect with zinc phosphate
or barium borate
as a corrosion inhibitor
pigment
.
Zinc borate acts as a broad-spectrum fungicide
in plastics and wood products.
Zinc borate can be used as a flux
in some ceramic
s. In electrical insulators it improves the ceramics properties.
Nanopowder zinc borate can be used for the applications above, and also for improving the frictional properties of lubricating oils.
Inorganic compound
Inorganic compounds have traditionally been considered to be of inanimate, non-biological origin. In contrast, organic compounds have an explicit biological origin. However, over the past century, the classification of inorganic vs organic compounds has become less important to scientists,...
, a borate
Borate
Borates are chemical compounds which contain oxoanions of boron in oxidation state +3. The simplest borate ion, BO33−, has a trigonal planar structure. Other borates are made up of trigonal BO3 or tetrahedral BO4 structural units, sharing oxygen atoms...
of zinc
Zinc
Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...
. It is a white crystalline or amorphous powder insoluble in water. Its toxicity is low. Its melting point is 980 °C.
Several variants of zinc borate exist, differing by the zinc/boron ratio and the water content:
- Zinc borate Firebrake ZB (2ZnO·3 B2O3·3.5H2O), CAS number 138265-88-0
- Zinc borate Firebrake 500 (2ZnO·3 B2O3), CAS number 138265-88-0
- Zinc borate Firebrake 415 (4ZnO·B2O3·H2O), CAS number 149749-62-2
- ZB-467 (4ZnO·6B2O3·7H2O), CAS number 1332-07-6
- ZB-223 (2ZnO·2B2O3·3H2O), CAS number 1332-07-6
The hydrated variants lose water between 290–415 °C.
Zinc borate is primarily used as a flame retardant
Flame retardant
Flame retardants are chemicals used in thermoplastics, thermosets, textiles and coatings that inhibit or resist the spread of fire. These can be separated into several different classes of chemicals:...
in plastic
Plastic
A plastic material is any of a wide range of synthetic or semi-synthetic organic solids used in the manufacture of industrial products. Plastics are typically polymers of high molecular mass, and may contain other substances to improve performance and/or reduce production costs...
s and cellulose fiber
Cellulose fiber
Cellulose fibers are fibres of cellulose from any source, either natural or manufactured.-Textile:In the textile industry regenerated cellulose is used as fibers such as rayon, . Cellulose fibers are manufactured from dissolving pulp...
s, paper
Paper
Paper is a thin material mainly used for writing upon, printing upon, drawing or for packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....
, rubber
Rubber
Natural rubber, also called India rubber or caoutchouc, is an elastomer that was originally derived from latex, a milky colloid produced by some plants. The plants would be ‘tapped’, that is, an incision made into the bark of the tree and the sticky, milk colored latex sap collected and refined...
s and textile
Textile
A textile or cloth is a flexible woven material consisting of a network of natural or artificial fibres often referred to as thread or yarn. Yarn is produced by spinning raw fibres of wool, flax, cotton, or other material to produce long strands...
s. It is also used in paint
Paint
Paint is any liquid, liquefiable, or mastic composition which after application to a substrate in a thin layer is converted to an opaque solid film. One may also consider the digital mimicry thereof...
s, adhesive
Adhesive
An adhesive, or glue, is a mixture in a liquid or semi-liquid state that adheres or bonds items together. Adhesives may come from either natural or synthetic sources. The types of materials that can be bonded are vast but they are especially useful for bonding thin materials...
s, and pigment
Pigment
A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, in which a material emits light.Many materials selectively absorb...
s. As a flame retardant, it can replace antimony trioxide
Antimony trioxide
Antimony trioxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as the minerals valentinite and senarmontite...
as a synergist in both halogen-based and halogen-free systems. It is an anti-dripping and char-promoting agent, and suppresses the afterglow. In electrical insulator plastics it suppresses arcing and tracking
Electrical treeing
Within the field of electrical engineering, treeing is an electrical pre-breakdown phenomenon. It is a damaging process due to partial discharges and progresses through the stressed dielectric insulation, whose path resembles the form of a tree....
.
In halogen-containing systems, zinc borate is used together with antimony trioxide
Antimony trioxide
Antimony trioxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as the minerals valentinite and senarmontite...
and alumina trihydrate. It catalyzes formation of char and creates a protective layer of glass. Zinc catalyzes the release of halogens by forming zinc halides and zinc oxyhalides.
In halogen-free system, zinc borate can be used together with alumina trihydrate, magnesium hydroxide
Magnesium hydroxide
Magnesium hydroxide is an inorganic compound with the chemical formula Mg2. As a suspension in water, it is often called milk of magnesia because of its milk-like appearance. The solid mineral form of magnesium hydroxide is known as brucite....
, red phosphorus, or ammonium polyphosphate
Ammonium polyphosphate
Ammonium polyphosphate is an inorganic salt of polyphosphoric acid and ammonia containing both chains and possibly branching. Its chemical formula is [NH4 PO3]n showing that each monomer consists of an orthophosphate radical of a phosphorus atom with three oxygens and one negative charge...
. During burning the plastics, a porous borate ceramics is formed that protects the underlying layers. In presence of silica, borosilicate glass
Borosilicate glass
Borosilicate glass is a type of glass with the main glass-forming constituents silica and boron oxide. Borosilicate glasses are known for having very low coefficients of thermal expansion , making them resistant to thermal shock, more so than any other common glass...
can be formed at plastic burning temperatures.
Zinc borate is used in polyvinyl chloride
Polyvinyl chloride
Polyvinyl chloride, commonly abbreviated PVC, is a thermoplastic polymer. It is a vinyl polymer constructed of repeating vinyl groups having one hydrogen replaced by chloride. Polyvinyl chloride is the third most widely produced plastic, after polyethylene and polypropylene. PVC is widely used in...
, polyolefin
Polyolefin
A polyolefin is a polymer produced from a simple olefin as a monomer. For example, polyethylene is the polyolefin produced by polymerizing the olefin ethylene. An equivalent term is polyalkene; this is a more modern term, although polyolefin is still used in the petrochemical industry...
s, polyamides, epoxy
Epoxy
Epoxy, also known as polyepoxide, is a thermosetting polymer formed from reaction of an epoxide "resin" with polyamine "hardener". Epoxy has a wide range of applications, including fiber-reinforced plastic materials and general purpose adhesives....
resins, polyester
Polyester
Polyester is a category of polymers which contain the ester functional group in their main chain. Although there are many polyesters, the term "polyester" as a specific material most commonly refers to polyethylene terephthalate...
s, thermoplastic elastomer
Elastomer
An elastomer is a polymer with the property of viscoelasticity , generally having notably low Young's modulus and high yield strain compared with other materials. The term, which is derived from elastic polymer, is often used interchangeably with the term rubber, although the latter is preferred...
s, rubber
Rubber
Natural rubber, also called India rubber or caoutchouc, is an elastomer that was originally derived from latex, a milky colloid produced by some plants. The plants would be ‘tapped’, that is, an incision made into the bark of the tree and the sticky, milk colored latex sap collected and refined...
s, etc. It is also used in some intumescent
Intumescent
An intumescent is a substance which swells as a result of heat exposure, thus increasing in volume, and decreasing in density. Intumescents are typically used in passive fire protection and, in America, require listing and approval use and compliance in their installed configurations in order to...
systems.
Zinc borate has synergistic effect with zinc phosphate
Zinc phosphate
Zinc phosphate is an inorganic chemical compound used as a corrosion resistant coating on metal surfaces either as part of an electroplating process or applied as a primer pigment . Zinc phosphate coats better on a crystalline structure than bare metal, so a seeding agent is often used as a...
or barium borate
Barium borate
Barium borate, also called barium diborate, barium boron oxide, barium metaborate, or BBO is an inorganic compound, a borate of barium. It is available as a hydrate or dehydrated....
as a corrosion inhibitor
Corrosion inhibitor
A corrosion inhibitor is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy. The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and flow regime...
pigment
Pigment
A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, in which a material emits light.Many materials selectively absorb...
.
Zinc borate acts as a broad-spectrum fungicide
Fungicide
Fungicides are chemical compounds or biological organisms used to kill or inhibit fungi or fungal spores. Fungi can cause serious damage in agriculture, resulting in critical losses of yield, quality and profit. Fungicides are used both in agriculture and to fight fungal infections in animals...
in plastics and wood products.
Zinc borate can be used as a flux
Flux (metallurgy)
In metallurgy, a flux , is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time...
in some ceramic
Ceramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
s. In electrical insulators it improves the ceramics properties.
Nanopowder zinc borate can be used for the applications above, and also for improving the frictional properties of lubricating oils.