Ultrasonic cleaning
Encyclopedia
An ultrasonic cleaner is a cleaning device that uses ultrasound
Ultrasound
Ultrasound is cyclic sound pressure with a frequency greater than the upper limit of human hearing. Ultrasound is thus not separated from "normal" sound based on differences in physical properties, only the fact that humans cannot hear it. Although this limit varies from person to person, it is...

 (usually from 20–400 kHz) and an appropriate cleaning solvent (sometimes ordinary tap water) to clean delicate items. The ultrasound can be used with only water but use of a solvent appropriate for the item to be cleaned and the soiling enhances the effect.

Ultrasonic cleaners are often used to clean jewellery
Jewellery
Jewellery or jewelry is a form of personal adornment, such as brooches, rings, necklaces, earrings, and bracelets.With some exceptions, such as medical alert bracelets or military dog tags, jewellery normally differs from other items of personal adornment in that it has no other purpose than to...

, lenses
Lens (optics)
A lens is an optical device with perfect or approximate axial symmetry which transmits and refracts light, converging or diverging the beam. A simple lens consists of a single optical element...

 and other optical parts, watch
Watch
A watch is a small timepiece, typically worn either on the wrist or attached on a chain and carried in a pocket, with wristwatches being the most common type of watch used today. They evolved in the 17th century from spring powered clocks, which appeared in the 15th century. The first watches were...

es, dental
Dentistry
Dentistry is the branch of medicine that is involved in the study, diagnosis, prevention, and treatment of diseases, disorders and conditions of the oral cavity, maxillofacial area and the adjacent and associated structures and their impact on the human body. Dentistry is widely considered...

 and surgical instruments, fountain pens, industrial parts and electronic equipment. They are used in many jewellery workshops, watchmaker
Watchmaker
A watchmaker is an artisan who makes and repairs watches. Since virtually all watches are now factory made, most modern watchmakers solely repair watches. However, originally they were master craftsmen who built watches, including all their parts, by hand...

s' establishments, and electronic repair workshops.

Process characteristics

Ultrasonic cleaning uses high frequency sound waves to agitate in a liquid. Cavitation
Cavitation
Cavitation is the formation and then immediate implosion of cavities in a liquidi.e. small liquid-free zones that are the consequence of forces acting upon the liquid...

 bubbles induced by the agitation act on contaminants adhering to substrates like metals, plastics, glass, rubber, and ceramics. This action also penetrates blind holes, cracks, and recesses. The intention is to thoroughly remove all traces of contamination tightly adhering or embedded onto solid surfaces. Water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 or other solvent
Solvent
A solvent is a liquid, solid, or gas that dissolves another solid, liquid, or gaseous solute, resulting in a solution that is soluble in a certain volume of solvent at a specified temperature...

s can be used, depending on the type of contamination and the workpiece. Contaminants can include dust, dirt, oil, pigments, grease, polishing compounds, flux agents, fingerprints, soot wax and mold release agents, biological soil like blood, and so on. Ultrasonic cleaning can be used for a wide range of workpiece shapes, sizes and materials, and may not require the part to be disassembled prior to cleaning.

Design and operating principle

In an ultrasonic cleaner, the object to be cleaned is placed in a chamber containing a suitable solution (in an aqueous or organic solution, depending on the application). In aqueous cleaners, the chemical added is a surfactant
Surfactant
Surfactants are compounds that lower the surface tension of a liquid, the interfacial tension between two liquids, or that between a liquid and a solid...

 which breaks down the surface tension of the water base. An ultrasound generating transducer
Transducer
A transducer is a device that converts one type of energy to another. Energy types include electrical, mechanical, electromagnetic , chemical, acoustic or thermal energy. While the term transducer commonly implies the use of a sensor/detector, any device which converts energy can be considered a...

 built into the chamber, or lowered into the fluid, produces ultrasonic waves in the fluid by changing size in concert with an electrical signal oscillating at ultrasonic frequency. This creates compression waves in the liquid of the tank which ‘tear’ the liquid apart, leaving behind many millions of microscopic ‘voids’ or ‘partial vacuum bubbles’ (cavitation
Cavitation
Cavitation is the formation and then immediate implosion of cavities in a liquidi.e. small liquid-free zones that are the consequence of forces acting upon the liquid...

). These bubbles collapse with enormous energy; temperatures and pressures on the order of 5,000 K and 20,000 lbs per square inch are achieved ; however, they are so small that they do no more than clean and remove surface dirt and contaminants. The higher the frequency, the smaller the nodes between the cavitation points, which allows for cleaning of more intricate detail.
Transducers are usually made of piezoelectric
Piezoelectricity
Piezoelectricity is the charge which accumulates in certain solid materials in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure...

 material (e.g. lead zirconate titanate
Lead zirconate titanate
Lead zirconate titanate , also called PZT, is a ceramic perovskite material that shows a marked piezoelectric effect. PZT-based compounds are composed of the chemical elements lead and zirconium and the chemical compound titanate which are combined under extremely high temperatures. A filter is...

 or barium titanate
Barium titanate
Barium titanate is the inorganic compound with the chemical formula BaTiO3. Barium titanate is a white powder and transparent as larger crystals...

), and sometimes magnetostrictive
Magnetostriction
Magnetostriction is a property of ferromagnetic materials that causes them to change their shape or dimensions during the process of magnetization. The variation of material's magnetization due to the applied magnetic field changes the magnetostrictive strain until reaching its saturation value, λ...

 (made of a material such as nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

 or ferrite
Ferrite (magnet)
Ferrites are chemical compounds consisting of ceramic materials with iron oxide as their principal component. Many of them are magnetic materials and they are used to make permanent magnets, ferrite cores for transformers, and in various other applications.Many ferrites are spinels with the...

). The often harsh chemicals used as cleaners in many industries are not needed, or used in much lower concentrations, with ultrasonic agitation. Ultrasonics are used for industrial cleaning, and also used in many medical and dental techniques and industrial processes.

Cleaning solution

Ultrasonic activity (cavitation) helps the solution to do its job; plain water would not normally be effective. The cleaning solution contains ingredients designed to make ultrasonic cleaning more effective. For example, reduction of surface tension
Surface tension
Surface tension is a property of the surface of a liquid that allows it to resist an external force. It is revealed, for example, in floating of some objects on the surface of water, even though they are denser than water, and in the ability of some insects to run on the water surface...

 increases cavitation levels, so the solution contains a good wetting agent (surfactant
Surfactant
Surfactants are compounds that lower the surface tension of a liquid, the interfacial tension between two liquids, or that between a liquid and a solid...

). Aqueous cleaning solutions contain detergents, wetting agents and other components, and have a large influence on the cleaning process. Correct composition of the solution is very dependent upon the item cleaned. Solutions are mostly used warm, at about 50–65 °C (122–149 F), however, in medical applications it is generally accepted that cleaning should be at temperatures below 38 °C (100.4 °F) to prevent protein coagulation.

Water-based solutions are more limited in their ability to remove contaminants by chemical action alone than solvent solutions; e.g. for delicate parts covered with thick grease. The effort required to design an effective aqueous-cleaning system for a particular purpose is much greater than for a solvent system.

Some better machines (which are not unduly large) recycle the hydrocarbon cleaning fluids. Three tanks are used in a cascade. The lower tank containing dirty fluid is heated causing the fluid to evaporate. At the top of the machine there is a refrigeration coil. Fluid condenses on the coil and falls into the upper tank. The upper tank eventually overflows and clean fluid runs into the work tank where the cleaning takes place. Purchase price is higher than simpler machines, but such machines are economical in the long run. The same fluid can be reused many times, minimising wastage and pollution.

Carbon tetrachloride
Carbon tetrachloride
Carbon tetrachloride, also known by many other names is the organic compound with the formula CCl4. It was formerly widely used in fire extinguishers, as a precursor to refrigerants, and as a cleaning agent...

 was used in the past, but is now prohibited as a health hazard.

Uses

Most hard, non-absorbent materials (metals, plastics, etc.) not chemically attacked by the cleaning fluid are suitable for ultrasonic cleaning.

Industrial ultrasonic cleaners are used in the automotive, sporting, printing, marine, medical, pharmaceutical, electroplating, disk drive components, engineering and weapons industries.

Ultrasonic baths are also used to experimentally determine the elastic constants of many anisotropic
Anisotropy
Anisotropy is the property of being directionally dependent, as opposed to isotropy, which implies identical properties in all directions. It can be defined as a difference, when measured along different axes, in a material's physical or mechanical properties An example of anisotropy is the light...

 materials. Ultrasonic waves can usually only be sent through a material at right angles to the material's surface (normal
Surface normal
A surface normal, or simply normal, to a flat surface is a vector that is perpendicular to that surface. A normal to a non-flat surface at a point P on the surface is a vector perpendicular to the tangent plane to that surface at P. The word "normal" is also used as an adjective: a line normal to a...

incidence). In water the angle of incidence for a longitudinal wave can be set, inducing both longitudinal and transverse waves in the material. Then, by measuring the time of flight for both waves, the elastic constants can be determined.

External links

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