Clathrate compound
Encyclopedia
Chemical substance
In chemistry, a chemical substance is a form of matter that has constant chemical composition and characteristic properties. It cannot be separated into components by physical separation methods, i.e. without breaking chemical bonds. They can be solids, liquids or gases.Chemical substances are...
consisting of a lattice
Lattice (group)
In mathematics, especially in geometry and group theory, a lattice in Rn is a discrete subgroup of Rn which spans the real vector space Rn. Every lattice in Rn can be generated from a basis for the vector space by forming all linear combinations with integer coefficients...
of one type of molecule trapping and containing a second type of molecule. The name clathrate complex used to refer only to the inclusion complex of hydroquinone
Hydroquinone
Hydroquinone, also benzene-1,4-diol or quinol, is an aromatic organic compound that is a type of phenol, having the chemical formula C6H42. Its chemical structure, shown in the table at right, has two hydroxyl groups bonded to a benzene ring in a para position. It is a white granular solid...
, but recently it has been adopted for many other weak composites which consist of a host molecule (forming the basic frame) and a guest molecule (held in the host molecule by inter-molecular interaction). Clathrates are also called host-guest complexes, inclusion compounds, adducts (chiefly in the case of urea
Urea
Urea or carbamide is an organic compound with the chemical formula CO2. The molecule has two —NH2 groups joined by a carbonyl functional group....
and thiourea
Thiourea
Thiourea is an organosulfur compound of with the formula SC2 . It is structurally similar to urea, except that the oxygen atom is replaced by a sulfur atom, but the properties of urea and thiourea differ significantly. Thiourea is a reagent in organic synthesis. "Thioureas" refers to a broad...
) and, in the oil industry, hydrates. They used to be called molecular compounds.
A clathrate hydrate
Clathrate hydrate
Clathrate hydrates are crystalline water-based solids physically resembling ice, in which small non-polar molecules or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded water molecules...
, in particular, is a special type of gas hydrate
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....
in which a lattice of water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
molecules encloses molecules of a trapped gas
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...
. Large amounts of methane
Methane
Methane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel...
naturally frozen in this form have been discovered both in permafrost formations and under the ocean sea-bed. Researchers have begun to investigate silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...
and germanium
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....
clathrates for possible semiconducting
Semiconductor
A semiconductor is a material with electrical conductivity due to electron flow intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 103 to 10−8 siemens per centimeter...
, superconducting
Superconductivity
Superconductivity is a phenomenon of exactly zero electrical resistance occurring in certain materials below a characteristic temperature. It was discovered by Heike Kamerlingh Onnes on April 8, 1911 in Leiden. Like ferromagnetism and atomic spectral lines, superconductivity is a quantum...
, and thermoelectric properties.
The word clathrate is derived from the Latin clatratus meaning with bars or a lattice
Crystal structure
In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry...
.
History
The history of clathrate compounds is relatively recent. Clathrate hydrates were discovered in 1810 by Humphry Davy. Clathrates were studied by P. Pfeiffer in 1927 and in 1930, E. Hertel defined "molecular compounds" as substances decomposed into individual components following the mass action law in solution or gas state. In 1945, H. M. Powell analyzed the crystal structure of these compounds and named them clathrates.Urea- and thiourea-hosted clathrates were applied to the separation of paraffin
Paraffin
In chemistry, paraffin is a term that can be used synonymously with "alkane", indicating hydrocarbons with the general formula CnH2n+2. Paraffin wax refers to a mixture of alkanes that falls within the 20 ≤ n ≤ 40 range; they are found in the solid state at room temperature and begin to enter the...
. Thereafter, cyclodextrin
Cyclodextrin
Cyclodextrins are a family of compounds made up of sugar molecules bound together in a ring ....
, crown ether
Crown ether
Crown ethers are cyclic chemical compounds that consist of a ring containing several ether groups. The most common crown ethers are oligomers of ethylene oxide, the repeating unit being ethyleneoxy, i.e., -CH2CH2O-. Important members of this series are the tetramer , the pentamer , and the hexamer...
, and cryptand
Cryptand
Cryptands are a family of synthetic bi- and polycyclic multidentate ligands for a variety of cations. The Nobel Prize for Chemistry in 1987 was given to Donald J. Cram, Jean-Marie Lehn, and Charles J. Pedersen for their efforts in discovering and determining uses of cryptands and crown ethers,...
were found as host molecules (see figure). A much studied host molecule is Dianin's compound
Dianin's compound
Dianin's compound was invented by Aleksandr Dianin in 1914. This compound is a condensation isomer of bisphenol A and acetone and of special importance in host-guest chemistry because it can form a large variety of clathrates with suitable guest molecules. One example is the clathrate of Dianin's...
.
Properties
Clathrate complexes are various and include, for example, strong interaction via chemical bondChemical bond
A chemical bond is an attraction between atoms that allows the formation of chemical substances that contain two or more atoms. The bond is caused by the electromagnetic force attraction between opposite charges, either between electrons and nuclei, or as the result of a dipole attraction...
s between host molecules and guest molecules, or guest molecules set in the geometrical space of host molecules by weak intermolecular force
Intermolecular force
Intermolecular forces are forces of attraction or repulsion which act between neighboring particles: atoms, molecules or ions. They are weak compared to the intramolecular forces, the forces which keep a molecule together...
. Typical examples of host-guest complexes are inclusion compound
Inclusion compound
In host-guest chemistry an inclusion compound is a complex in which one chemical compound forms a cavity in which molecules of a second "guest" compound are located. The definition of inclusion compounds is very broad, extending to channels formed between molecules in a crystal lattice in which...
s and intercalation
Intercalation (chemistry)
In chemistry, intercalation is the reversible inclusion of a molecule between two other molecules . Examples include DNA intercalation and graphite intercalation compounds.- DNA intercalation :...
compounds.
Clathrates can be isolated as chemically different species, and may have structural and positional isomers (enantiomers and diastereomers).
Media references
- In John BarnesJohn Barnes (author)-Writing:Two of his novels, The Sky So Big and Black and The Duke of Uranium have been reviewed as having content appropriate for a young adult readership, comparing favorably to Robert A. Heinlein's "juvenile" novels...
' science-fiction novel Mother of StormsMother of StormsMother of Storms is a 1994 science fiction novel by John Barnes. It was nominated for three major science fiction awards.-Plot summary:In the early 21st century, the earth suffers from a giant hurricane spawned by the release of clathrate compounds, as the result of a nuclear explosion...
, the destruction of Arctic sea bed clathrates and the subsequent release of trapped and methaneMethaneMethane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel...
is central to the plot development involving a vast supersonic hurricane. - During the Deepwater Horizon oil spillDeepwater Horizon oil spillThe Deepwater Horizon oil spill is an oil spill in the Gulf of Mexico which flowed unabated for three months in 2010, and continues to leak fresh oil. It is the largest accidental marine oil spill in the history of the petroleum industry...
clathrate formation inside a large device intended to cap the main leak prevented its successful deployment. - In the massively multiplayer online gameMassively multiplayer online gameA massively multiplayer online game is a multiplayer video game which is capable of supporting hundreds or thousands of players simultaneously. By necessity, they are played on the Internet, and usually feature at least one persistent world. They are, however, not necessarily games played on...
Eve OnlineEVE OnlineEve Online is a video game by CCP Games. It is a player-driven, persistent-world MMORPG set in a science fiction space setting. Characters pilot customizable ships through a galaxy of over 7,500 star systems. Most star systems are connected to one or more other star systems by means of stargates...
, strontiumStrontiumStrontium is a chemical element with the symbol Sr and the atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when exposed to air. It occurs naturally in the minerals celestine and...
clathrates, mined from ice asteroids, have various strategic applications.
See also
- Clathrate gun hypothesisClathrate gun hypothesisThe clathrate gun hypothesis is the popular name given to the hypothesis that rises in sea temperatures can trigger the sudden release of methane from methane clathrate compounds buried in seabeds and permafrost which, because the methane itself is a powerful greenhouse gas, leads to further...
, a hypothesis regarding the sudden release of methane clathrateMethane clathrateMethane clathrate, also called methane hydrate, hydromethane, methane ice, "fire ice", natural gas hydrate or just gas hydrate, is a solid clathrate compound in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice...
from ocean sediments. - Weaire-Phelan structureWeaire-Phelan structureIn geometry, the Weaire–Phelan structure is a complex 3-dimensional structure representing an idealised foam of equal-sized bubbles. In 1993, Trinity College Dublin physicist Denis Weaire and his student Robert Phelan found that in computer simulations of foam, this structure was a better...
, related to clathrate structure. - Chelate