Astrochemistry
Encyclopedia
Astrochemistry is the study of the abundance and reactions of chemical element
Chemical element
A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminum, iron, copper, gold, mercury, and lead.As of November 2011, 118 elements...

s and molecule
Molecule
A molecule is an electrically neutral group of at least two atoms held together by covalent chemical bonds. Molecules are distinguished from ions by their electrical charge...

s in the universe, and their interaction with radiation
Radiation
In physics, radiation is a process in which energetic particles or energetic waves travel through a medium or space. There are two distinct types of radiation; ionizing and non-ionizing...

. The discipline is an overlap of astronomy
Astronomy
Astronomy is a natural science that deals with the study of celestial objects and phenomena that originate outside the atmosphere of Earth...

 and chemistry
Chemistry
Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties. Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds....

. The word "astrochemistry" may be applied to both the Solar System
Solar System
The Solar System consists of the Sun and the astronomical objects gravitationally bound in orbit around it, all of which formed from the collapse of a giant molecular cloud approximately 4.6 billion years ago. The vast majority of the system's mass is in the Sun...

 and the interstellar medium
Interstellar medium
In astronomy, the interstellar medium is the matter that exists in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, dust, and cosmic rays. It fills interstellar space and blends smoothly into the surrounding intergalactic space...

. The study of the abundance of elements and isotope ratios in Solar System objects, such as meteorite
Meteorite
A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

s, is also called cosmochemistry
Cosmochemistry
Cosmochemistry or chemical cosmology is the study of the chemical composition of matter in the universe and the processes that led to those compositions. This is done primarily through the study of the chemical composition of meteorites and other physical samples...

, while the study of interstellar atoms and molecules and their interaction with radiation is sometimes also called molecular astrophysics. The formation, atomic and chemical composition, evolution and fate of molecular gas cloud
Molecular cloud
A molecular cloud, sometimes called a stellar nursery if star formation is occurring within, is a type of interstellar cloud whose density and size permits the formation of molecules, most commonly molecular hydrogen ....

s is of special interest, because it is from these clouds that solar systems form.

Spectroscopy

One particularly important experimental tool in astrochemistry is spectroscopy
Spectroscopy
Spectroscopy is the study of the interaction between matter and radiated energy. Historically, spectroscopy originated through the study of visible light dispersed according to its wavelength, e.g., by a prism. Later the concept was expanded greatly to comprise any interaction with radiative...

, the use of telescope
Telescope
A telescope is an instrument that aids in the observation of remote objects by collecting electromagnetic radiation . The first known practical telescopes were invented in the Netherlands at the beginning of the 1600s , using glass lenses...

s to measure the absorption and emission of light
Light
Light or visible light is electromagnetic radiation that is visible to the human eye, and is responsible for the sense of sight. Visible light has wavelength in a range from about 380 nanometres to about 740 nm, with a frequency range of about 405 THz to 790 THz...

 from molecules and atoms in various environments. By comparing astronomical observations with laboratory measurements, astrochemists can infer the elemental abundances, chemical composition, and temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

s of star
Star
A star is a massive, luminous sphere of plasma held together by gravity. At the end of its lifetime, a star can also contain a proportion of degenerate matter. The nearest star to Earth is the Sun, which is the source of most of the energy on Earth...

s and interstellar cloud
Interstellar cloud
Interstellar cloud is the generic name given to an accumulation of gas, plasma and dust in our and other galaxies. Put differently, an interstellar cloud is a denser-than-average region of the interstellar medium. Depending on the density, size and temperature of a given cloud, the hydrogen in it...

s. This is possible because ions, atoms, and molecules have characteristic spectra: that is, the absorption and emission of certain wavelengths (colors) of light, often not visible to the human eye. However, these measurements have limitations, with various types of radiation (radio, infrared, visible, ultraviolet etc.) able to detect only certain types of species, depending on the chemical properties of the molecules. Interstellar formaldehyde
Interstellar formaldehyde
Interstellar formaldehyde was first discovered in 1969 by L. Snyder et al.. using the National Radio Astronomy Observatory. Formaldehyde was detected by means of the 111 - 110 ground state rotational transition at 4830 MHz.-Initial discovery:Formaldehyde was first discovered in interstellar...

 was the first polyatomic organic molecule detected in the interstellar medium.

Perhaps the most powerful technique for detection of individual molecules is radio astronomy
Radio astronomy
Radio astronomy is a subfield of astronomy that studies celestial objects at radio frequencies. The initial detection of radio waves from an astronomical object was made in the 1930s, when Karl Jansky observed radiation coming from the Milky Way. Subsequent observations have identified a number of...

, which has resulted in the detection of over a hundred interstellar species, including radical
Radical (chemistry)
Radicals are atoms, molecules, or ions with unpaired electrons on an open shell configuration. Free radicals may have positive, negative, or zero charge...

s and ions, and organic (i.e. carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...

-based) compounds, such as alcohol
Alcohol
In chemistry, an alcohol is an organic compound in which the hydroxy functional group is bound to a carbon atom. In particular, this carbon center should be saturated, having single bonds to three other atoms....

s, acid
Acid
An acid is a substance which reacts with a base. Commonly, acids can be identified as tasting sour, reacting with metals such as calcium, and bases like sodium carbonate. Aqueous acids have a pH of less than 7, where an acid of lower pH is typically stronger, and turn blue litmus paper red...

s, aldehyde
Aldehyde
An aldehyde is an organic compound containing a formyl group. This functional group, with the structure R-CHO, consists of a carbonyl center bonded to hydrogen and an R group....

s, and ketone
Ketone
In organic chemistry, a ketone is an organic compound with the structure RCR', where R and R' can be a variety of atoms and groups of atoms. It features a carbonyl group bonded to two other carbon atoms. Many ketones are known and many are of great importance in industry and in biology...

s. One of the most abundant interstellar molecules, and among the easiest to detect with radio waves (due to its strong electric dipole
Dipole
In physics, there are several kinds of dipoles:*An electric dipole is a separation of positive and negative charges. The simplest example of this is a pair of electric charges of equal magnitude but opposite sign, separated by some distance. A permanent electric dipole is called an electret.*A...

 moment), is CO (carbon monoxide
Carbon monoxide
Carbon monoxide , also called carbonous oxide, is a colorless, odorless, and tasteless gas that is slightly lighter than air. It is highly toxic to humans and animals in higher quantities, although it is also produced in normal animal metabolism in low quantities, and is thought to have some normal...

). In fact, CO is such a common interstellar molecule that it is used to map out molecular regions. The radio observation of perhaps greatest human interest is the claim of interstellar glycine
Glycine
Glycine is an organic compound with the formula NH2CH2COOH. Having a hydrogen substituent as its 'side chain', glycine is the smallest of the 20 amino acids commonly found in proteins. Its codons are GGU, GGC, GGA, GGG cf. the genetic code.Glycine is a colourless, sweet-tasting crystalline solid...

, the simplest amino acid
Amino acid
Amino acids are molecules containing an amine group, a carboxylic acid group and a side-chain that varies between different amino acids. The key elements of an amino acid are carbon, hydrogen, oxygen, and nitrogen...

, but with considerable accompanying controversy. One of the reasons why this detection was controversial is that although radio (and some other methods like rotational spectroscopy
Rotational spectroscopy
Rotational spectroscopy or microwave spectroscopy studies the absorption and emission of electromagnetic radiation by molecules associated with a corresponding change in the rotational quantum number of the molecule...

) are good for the identification of simple species with large dipole moments, they are less sensitive to more complex molecules, even something relatively small like amino acids.

Moreover, such methods are completely blind to molecules that have no dipole. For example, by far the most common molecule in the universe is H2 (hydrogen
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

 gas), but it does not have a dipole moment, so it is invisible to radio telescopes. Moreover, such methods cannot detect species that are not in the gas-phase. Since dense molecular clouds are very cold (10-50 K = -263 to -223 C = -440 to -370 F), most molecules in them (other than hydrogen) are frozen, i.e. solid. Instead, hydrogen and these other molecules are detected using other wavelengths of light. Hydrogen is easily detected in the ultraviolet (UV) and visible ranges from its absorption and emission of light (the hydrogen line
Hydrogen line
The hydrogen line, 21 centimeter line or HI line refers to the electromagnetic radiation spectral line that is created by a change in the energy state of neutral hydrogen atoms. This electromagnetic radiation is at the precise frequency of 1420.40575177 MHz, which is equivalent to the vacuum...

). Moreover, most organic compounds absorb and emit light in the infrared (IR) so, for example, the recent detection of methane
Methane
Methane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel...

 in the atmosphere of Mars was achieved using an IR ground-based telescope, NASA's 3-meter Infrared Telescope Facility
Infrared Telescope Facility
The NASA Infrared Telescope Facility is a telescope optimized for use in infrared astronomy and located at the Mauna Kea Observatory in Hawai'i. It was first built to support the Voyager missions and is now the USA national facility for infrared astronomy, providing continued support to...

 atop Mauna Kea, Hawaii. NASA also has an airborne IR telescope called SOFIA
Sofia
Sofia is the capital and largest city of Bulgaria and the 12th largest city in the European Union with a population of 1.27 million people. It is located in western Bulgaria, at the foot of Mount Vitosha and approximately at the centre of the Balkan Peninsula.Prehistoric settlements were excavated...

 and an IR space telescope called Spitzer
Spitzer Space Telescope
The Spitzer Space Telescope , formerly the Space Infrared Telescope Facility is an infrared space observatory launched in 2003...

.

Infrared astronomy has also revealed that the interstellar medium contains a suite of complex gas-phase carbon compounds called polyaromatic hydrocarbons
Polycyclic aromatic hydrocarbon
Polycyclic aromatic hydrocarbons , also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are potent atmospheric pollutants that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH...

, often abbreviated PAHs or PACs. These molecules, composed primarily of fused rings of carbon (either neutral or in an ionized state), are said to be the most common class of carbon compound in the galaxy. They are also the most common class of carbon molecule in meteorites and in cometary and asteroidal dust (cosmic dust
Cosmic dust
Cosmic dust is a type of dust composed of particles in space which are a few molecules to 0.1 µm in size. Cosmic dust can be further distinguished by its astronomical location; for example: intergalactic dust, interstellar dust, interplanetary dust and circumplanetary dust .In our own Solar...

). These compounds, as well as the amino acids, nucleobase
Nucleobase
Nucleobases are a group of nitrogen-based molecules that are required to form nucleotides, the basic building blocks of DNA and RNA. Nucleobases provide the molecular structure necessary for the hydrogen bonding of complementary DNA and RNA strands, and are key components in the formation of stable...

s, and many other compounds in meteorites, carry deuterium
Deuterium
Deuterium, also called heavy hydrogen, is one of two stable isotopes of hydrogen. It has a natural abundance in Earth's oceans of about one atom in of hydrogen . Deuterium accounts for approximately 0.0156% of all naturally occurring hydrogen in Earth's oceans, while the most common isotope ...

 and isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...

s of carbon, nitrogen, and oxygen that are very rare on earth, attesting to their extraterrestrial origin. The PAHs are thought to form in hot circumstellar environments (around dying, carbon-rich red giant
Red giant
A red giant is a luminous giant star of low or intermediate mass in a late phase of stellar evolution. The outer atmosphere is inflated and tenuous, making the radius immense and the surface temperature low, somewhere from 5,000 K and lower...

 stars).

Infrared astronomy has also been used to assess the composition of solid materials in the interstellar medium, including silicate
Silicate
A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as the other...

s, kerogen
Kerogen
Kerogen is a mixture of organic chemical compounds that make up a portion of the organic matter in sedimentary rocks. It is insoluble in normal organic solvents because of the huge molecular weight of its component compounds. The soluble portion is known as bitumen. When heated to the right...

-like carbon-rich solids, and ice
Ice
Ice is water frozen into the solid state. Usually ice is the phase known as ice Ih, which is the most abundant of the varying solid phases on the Earth's surface. It can appear transparent or opaque bluish-white color, depending on the presence of impurities or air inclusions...

s. This is because unlike visible light, which is scattered or absorbed by solid particles, the IR radiation can pass through the microscopic interstellar particles, but in the process there are absorptions at certain wavelengths that are characteristic of the composition of the grains. As above with radio astronomy, there are certain limitations, e.g. N2 is difficult to detect by either IR or radio astronomy.

Such IR observations have determined that in dense clouds (where there are enough particles to attenuate the destructive UV radiation) thin ice layers coat the microscopic particles, permitting some low-temperature chemistry to occur. Since hydrogen is by far the most abundant molecule in the universe, the initial chemistry of these ices is determined by the chemistry of the hydrogen. If the hydrogen is atomic, then the H atoms react with available O, C and N atoms, producing "reduced" species like H2O, CH4, and NH3. However, if the hydrogen is molecular and thus not reactive, this permits the heavier atoms to react or remain bonded together, producing CO, CO2, CN, etc. These mixed-molecular ices are exposed to ultraviolet radiation and cosmic ray
Cosmic ray
Cosmic rays are energetic charged subatomic particles, originating from outer space. They may produce secondary particles that penetrate the Earth's atmosphere and surface. The term ray is historical as cosmic rays were thought to be electromagnetic radiation...

s, which results in complex radiation-driven chemistry. Lab experiments on the photochemistry of simple interstellar ices have produced amino acids. The similarity between interstellar and cometary ices (as well as comparisons of gas phase compounds) have been invoked as indicators of a connection between interstellar and cometary chemistry. This is somewhat supported by the results of the analysis of the organics from the comet samples returned by the Stardust mission
Stardust (spacecraft)
Stardust is a 300-kilogram robotic space probe launched by NASA on February 7, 1999 to study the asteroid 5535 Annefrank and collect samples from the coma of comet Wild 2. The primary mission was completed January 15, 2006, when the sample return capsule returned to Earth...

 but the minerals also indicated a surprising contribution from high-temperature chemistry in the solar nebula.

Research

Research is progressing on the way in which interstellar and circumstellar molecules form and interact, and this research could have a profound impact on our understanding of the suite of molecules that were present in the molecular cloud when our solar system formed, which contributed to the rich carbon chemistry of comets and asteroids and hence the meteorites and interstellar dust particles which fall to the Earth by the ton every day.

The sparseness of interstellar and interplanetary space results in some unusual chemistry, since symmetry-forbidden reactions cannot occur except on the longest of timescales. For this reason, molecules and molecular ions which are unstable on Earth can be highly abundant in space, for example the H3+
Protonated molecular hydrogen
Protonated molecular hydrogen, trihydrogen cation, or H3+, is one of the most abundant ions in the universe. It is stable in the interstellar medium due to the low temperature and low density of interstellar space. The role that H3+ plays in the gas-phase chemistry of the ISM is unparalleled by...

 ion. Astrochemistry overlaps with astrophysics
Astrophysics
Astrophysics is the branch of astronomy that deals with the physics of the universe, including the physical properties of celestial objects, as well as their interactions and behavior...

 and nuclear physics
Nuclear physics
Nuclear physics is the field of physics that studies the building blocks and interactions of atomic nuclei. The most commonly known applications of nuclear physics are nuclear power generation and nuclear weapons technology, but the research has provided application in many fields, including those...

 in characterizing the nuclear reactions which occur in stars, the consequences for stellar evolution
Stellar evolution
Stellar evolution is the process by which a star undergoes a sequence of radical changes during its lifetime. Depending on the mass of the star, this lifetime ranges from only a few million years to trillions of years .Stellar evolution is not studied by observing the life of a single...

, as well as stellar 'generations'. Indeed, the nuclear reactions in stars produce every naturally occurring chemical element. As the stellar 'generations' advance, the mass of the newly formed elements increases. A first-generation star uses elemental hydrogen (H) as a fuel source and produces helium
Helium
Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas that heads the noble gas group in the periodic table...

 (He). Hydrogen is the most abundant element, and it is the basic building block for all other elements as its nucleus has only one proton
Proton
The proton is a subatomic particle with the symbol or and a positive electric charge of 1 elementary charge. One or more protons are present in the nucleus of each atom, along with neutrons. The number of protons in each atom is its atomic number....

. Gravitational pull toward the center of a star creates massive amounts of heat and pressure, which cause nuclear fusion
Nuclear fusion
Nuclear fusion is the process by which two or more atomic nuclei join together, or "fuse", to form a single heavier nucleus. This is usually accompanied by the release or absorption of large quantities of energy...

. Through this process of merging nuclear mass, heavier elements are formed. Carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...

, oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

 and silicon
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...

 are examples of elements that form in stellar fusion. After many stellar generations, very heavy elements are formed (e.g. iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 and lead
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...

).

In October 2011, scientists reported that cosmic dust
Cosmic dust
Cosmic dust is a type of dust composed of particles in space which are a few molecules to 0.1 µm in size. Cosmic dust can be further distinguished by its astronomical location; for example: intergalactic dust, interstellar dust, interplanetary dust and circumplanetary dust .In our own Solar...

 contains complex organic
Organic compound
An organic compound is any member of a large class of gaseous, liquid, or solid chemical compounds whose molecules contain carbon. For historical reasons discussed below, a few types of carbon-containing compounds such as carbides, carbonates, simple oxides of carbon, and cyanides, as well as the...

 matter ("amorphous organic solids with a mixed aromatic-aliphatic structure") that could be created naturally, and rapidly, by stars.

See also

  • Interstellar medium
    Interstellar medium
    In astronomy, the interstellar medium is the matter that exists in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, dust, and cosmic rays. It fills interstellar space and blends smoothly into the surrounding intergalactic space...

  • List of molecules in interstellar space
  • Molecular astrophysics
  • Nucleocosmochronology
    Nucleocosmochronology
    Nucleocosmochronology, also known as cosmochronology, is a relatively new technique used to determine timescales for astrophysical objects and events...

  • Wikiversity:Topic:Astrochemistry

External links

  • Astrochemistry division of the International Astronomical Union
    International Astronomical Union
    The International Astronomical Union IAU is a collection of professional astronomers, at the Ph.D. level and beyond, active in professional research and education in astronomy...

  • The University of Arizona Astrochemistry Group http://www.chem.arizona.edu/faculty/ziur/ziur-group.html
  • Astrophysics & Astrochemistry at http://www.Astrochemistry.eu/
  • The Astrochemistry Lab at NASA Ames Research Center http://www.astrochemistry.org/
  • The Astrochemistry Lab at NASA Goddard Space Flight Center http://www-691.gsfc.nasa.gov/
  • The University of Leiden Laboratory for Astrophysics http://www.strw.leidenuniv.nl/~lab/
The source of this article is wikipedia, the free encyclopedia.  The text of this article is licensed under the GFDL.
 
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