Irving Langmuir
Encyclopedia
Irving Langmuir was an American chemist
Chemistry
Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties. Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds....

 and physicist
Physics
Physics is a natural science that involves the study of matter and its motion through spacetime, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.Physics is one of the oldest academic...

. His most noted publication was the famous 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis
Gilbert N. Lewis
Gilbert Newton Lewis was an American physical chemist known for the discovery of the covalent bond , his purification of heavy water, his reformulation of chemical thermodynamics in a mathematically rigorous manner accessible to ordinary chemists, his theory of Lewis acids and...

's cubical atom
Cubical atom
The cubical atom was an early atomic model in which electrons were positioned at the eight corners of a cube in a non-polar atom or molecule. This theory was developed in 1902 by Gilbert N. Lewis and published in 1916 in the famous article "The Atom and the Molecule" and used to account for the...

 theory and Walther Kossel
Walther Kossel
Walther Ludwig Julius Kossel was a German physicist known for his theory of the chemical bond , Sommerfeld–Kossel displacement law of atomic spectra, the Kossel-Stranski model for crystal growth, and the Kossel effect...

's chemical bonding theory, he outlined his "concentric theory of atomic structure". Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuir's presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at General Electric
General Electric
General Electric Company , or GE, is an American multinational conglomerate corporation incorporated in Schenectady, New York and headquartered in Fairfield, Connecticut, United States...

, from 1909–1950, Langmuir advanced several basic fields of physics
Physics
Physics is a natural science that involves the study of matter and its motion through spacetime, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.Physics is one of the oldest academic...

 and chemistry
Chemistry
Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties. Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds....

, invented the gas-filled incandescent lamp, the hydrogen welding technique
Atomic hydrogen welding
Atomic hydrogen welding is an arc welding process that uses an arc between two metal tungsten electrodes in a shielding atmosphere of hydrogen. The process was invented by Irving Langmuir in the course of his studies of atomic hydrogen...

, and was awarded the 1932 Nobel Prize in Chemistry
Nobel Prize in Chemistry
The Nobel Prize in Chemistry is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outstanding contributions in chemistry, physics, literature,...

 for his work in surface chemistry. He was the first industrial chemist to become a Nobel laureate. The Langmuir Laboratory for Atmospheric Research
Langmuir Laboratory for Atmospheric Research
The Langmuir Laboratory for Atmospheric Research is a scientific laboratory studying the cloud processes that produce lightning, hail, and rain, located in the Magdalena Mountains of central New Mexico in the United States...

 near Socorro, New Mexico
Socorro, New Mexico
Socorro is a city in Socorro County in the U.S. state of New Mexico. It stands in the Rio Grande Valley at an elevation of . The population was 9,051 at the 2010 census...

 was named in his honor as was the American Chemical Society
American Chemical Society
The American Chemical Society is a scientific society based in the United States that supports scientific inquiry in the field of chemistry. Founded in 1876 at New York University, the ACS currently has more than 161,000 members at all degree-levels and in all fields of chemistry, chemical...

 journal for Surface Science, called Langmuir
Langmuir (journal)
Langmuir is a peer-reviewed scientific journal, published since 1985 by the American Chemical Society. It publishes research in the areas of surface chemistry and colloid chemistry...

.

Early years

Irving Langmuir was born in Brooklyn
Brooklyn
Brooklyn is the most populous of New York City's five boroughs, with nearly 2.6 million residents, and the second-largest in area. Since 1896, Brooklyn has had the same boundaries as Kings County, which is now the most populous county in New York State and the second-most densely populated...

, New York on 31 January 1881. He was the third child of four of Charles Langmuir and Sadie, née Comings. During his childhood, Langmuir's parents encouraged him to carefully observe nature and to keep a detailed record of his various observations. When Irving was eleven, it was discovered that he had poor eyesight. When this problem was corrected, details that had previously eluded him were revealed, and his interest in the complications of nature was heightened.

During his childhood, Langmuir was influenced by his older brother, Arthur Langmuir. Arthur was a research chemist who encouraged Irving to be curious about nature and how things work. Arthur helped Irving set up his first chemistry lab in the corner of his bedroom, and he was content to answer the myriad of questions that Irving would pose. Langmuir's hobbies included mountaineering, skiing, piloting his own plane, and classical music. In addition to his professional interest in the politics of atomic energy, he was concerned about wilderness conservation.

Education

Langmuir attended his early education at various schools and institutes in America and Paris (1892–1895). Langmuir graduated high school from Chestnut Hill Academy
Chestnut Hill Academy
Chestnut Hill Academy, commonly referred to as CHA, is a Pre-K to 12 all-male independent college preparatory school located in northwest Philadelphia, Pennsylvania....

 (1898), an elite private school located in the affluent Chestnut Hill area in Philadelphia. He graduated with a Bachelor of Science degree in metallurgical engineering from the Columbia University
Columbia University
Columbia University in the City of New York is a private, Ivy League university in Manhattan, New York City. Columbia is the oldest institution of higher learning in the state of New York, the fifth oldest in the United States, and one of the country's nine Colonial Colleges founded before the...

 School of Mines (the first mining and metallurgy school in the U.S., established,1864 and presently known as Fu Foundation School of Engineering and Applied Science
Fu Foundation School of Engineering and Applied Science
The Fu Foundation School of Engineering and Applied Science is a school of Columbia University which awards Bachelor of Science, Master of Science, Master of Financial Engineering, Doctor of Philosophy, Doctor of Science, Doctor of Engineering degrees in engineering, applied physics and applied...

) in 1903. He earned his Ph.D. degree in 1906 under Nobel laureate Walther Nernst
Walther Nernst
Walther Hermann Nernst FRS was a German physical chemist and physicist who is known for his theories behind the calculation of chemical affinity as embodied in the third law of thermodynamics, for which he won the 1920 Nobel Prize in chemistry...

 in Göttingen
Göttingen
Göttingen is a university town in Lower Saxony, Germany. It is the capital of the district of Göttingen. The Leine river runs through the town. In 2006 the population was 129,686.-General information:...

, for research done using the "Nernst glower
Nernst glower
The Nernst glower is an obsolete device for providing a continuous source of infrared radiation for use in spectroscopy. Typically it was in the form of a cylindrical rod or tube composed of a mixture of certain oxides such as zirconium oxide , yttrium oxide and erbium oxide at a ratio of...

", an electric lamp invented by Nernst. His doctoral thesis was entitled “On the Partial Recombination of Dissolved Gases During Cooling.” He later did postgraduate work in chemistry. Langmuir then taught at Stevens Institute of Technology
Stevens Institute of Technology
Stevens Institute of Technology is a technological university located on a campus in Hoboken, New Jersey, USA – founded in 1870 with an 1868 bequest from Edwin A. Stevens. It is known for its engineering, science, and technological management curricula.The institute has produced leading...

 in Hoboken, New Jersey
Hoboken, New Jersey
Hoboken is a city in Hudson County, New Jersey, United States. As of the 2010 United States Census, the city's population was 50,005. The city is part of the New York metropolitan area and contains Hoboken Terminal, a major transportation hub for the region...

, until 1909, when he began working at the General Electric
General Electric
General Electric Company , or GE, is an American multinational conglomerate corporation incorporated in Schenectady, New York and headquartered in Fairfield, Connecticut, United States...

 research laboratory (Schenectady, New York
Schenectady, New York
Schenectady is a city in Schenectady County, New York, United States, of which it is the county seat. As of the 2010 census, the city had a population of 66,135...

).

Research

His initial contributions to science came from his study of light bulbs (a continuation of his Ph.D. work). His first major development was the improvement of the diffusion pump
Diffusion pump
Diffusion pumps use a high speed jet of vapor to direct gas molecules in the pump throat down into the bottom of the pump and out the exhaust. Presented in 1915 by Wolfgang Gaede and using mercury vapor, they were the first type of high vacuum pumps operating in the regime of free molecular flow,...

, which ultimately led to the invention of the high-vacuum tube
Vacuum tube
In electronics, a vacuum tube, electron tube , or thermionic valve , reduced to simply "tube" or "valve" in everyday parlance, is a device that relies on the flow of electric current through a vacuum...

. A year later, he and colleague Lewi Tonks
Lewi Tonks
Lewi Tonks was an American quantum physicist noted for his discovery of the Tonks-Girardeau gas.Tonks was employed by the General Electric for most of his working life, researching microwaves and ferromagnetism...

 discovered that the lifetime of a tungsten
Tungsten
Tungsten , also known as wolfram , is a chemical element with the chemical symbol W and atomic number 74.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as...

 filament was greatly lengthened by filling the bulb with an inert gas
Inert gas
An inert gas is a non-reactive gas used during chemical synthesis, chemical analysis, or preservation of reactive materials. Inert gases are selected for specific settings for which they are functionally inert since the cost of the gas and the cost of purifying the gas are usually a consideration...

, such as argon
Argon
Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide...

. He also discovered that twisting the filament into a tight coil improved its efficiency. These were important developments in the history of the incandescent light bulb
Incandescent light bulb
The incandescent light bulb, incandescent lamp or incandescent light globe makes light by heating a metal filament wire to a high temperature until it glows. The hot filament is protected from air by a glass bulb that is filled with inert gas or evacuated. In a halogen lamp, a chemical process...

. His work in surface chemistry began at this point, when he discovered that molecular hydrogen introduced into a tungsten-filament bulb dissociated into atomic hydrogen and formed a layer one atom thick on the surface of the bulb.

His assistant in vacuum tube research was his cousin William Comings White
William Comings White
William Comings White was an electrical engineer. He was research assistant to, and cousin of, the Nobel Prize winning chemist Irving Langmuir at the General Electric research laboratory....

.

In 1917, he published a paper on the chemistry of oil films that later became the basis for the award of the 1932 Nobel Prize in chemistry. Langmuir theorized that oils consisting of an aliphatic chain with a hydrophilic end group (perhaps an alcohol or acid) were oriented as a film one molecule thick upon the surface of water, with the hydrophilic group down in the water and the hydrophobic chains clumped together on the surface. The thickness of the film could be easily determined from the known volume and area of the oil, which allowed investigation of the molecular configuration before spectroscopic techniques were available.

As he continued to study filaments in vacuum and different gas environments, he began to study the emission of charged particles from hot filaments (thermionic emission
Thermionic emission
Thermionic emission is the heat-induced flow of charge carriers from a surface or over a potential-energy barrier. This occurs because the thermal energy given to the carrier overcomes the binding potential, also known as work function of the metal. The charge carriers can be electrons or ions, and...

). He was one of the first scientists to work with plasma
Plasma (physics)
In physics and chemistry, plasma is a state of matter similar to gas in which a certain portion of the particles are ionized. Heating a gas may ionize its molecules or atoms , thus turning it into a plasma, which contains charged particles: positive ions and negative electrons or ions...

s and was the first to call these ionized gases by that name, because they reminded him of blood plasma
Blood plasma
Blood plasma is the straw-colored liquid component of blood in which the blood cells in whole blood are normally suspended. It makes up about 55% of the total blood volume. It is the intravascular fluid part of extracellular fluid...

. Langmuir and Tonks discovered electron density waves in plasmas that are now known as Langmuir waves.

He introduced the concept of electron temperature and in 1924 invented the diagnostic method for measuring both temperature and density with an electrostatic probe, now called a Langmuir probe
Langmuir probe
A Langmuir probe is a device named after Nobel Prize winning physicist Irving Langmuir, used to determine the electron temperature, electron density, and electric potential of a plasma. It works by inserting one or more electrodes into a plasma, with a constant or time-varying electric potential...

 and commonly used in plasma physics. The current of a biased probe tip is measured as a function of bias voltage to determine the local plasma temperature and density. He also discovered atomic hydrogen
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

, which he put to use by inventing the atomic hydrogen welding
Atomic hydrogen welding
Atomic hydrogen welding is an arc welding process that uses an arc between two metal tungsten electrodes in a shielding atmosphere of hydrogen. The process was invented by Irving Langmuir in the course of his studies of atomic hydrogen...

 process; the first plasma weld ever made. Plasma welding has since been developed into gas tungsten arc welding
Gas tungsten arc welding
Gas tungsten arc welding , also known as tungsten inert gas welding, is an arc welding process that uses a nonconsumable tungsten electrode to produce the weld...

.

Later years

Following World War I
World War I
World War I , which was predominantly called the World War or the Great War from its occurrence until 1939, and the First World War or World War I thereafter, was a major war centred in Europe that began on 28 July 1914 and lasted until 11 November 1918...

 Langmuir contributed to atomic theory and the understanding of atomic structure by defining the modern concept of valence shells and isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...

s.

Langmuir was president of the Institute of Radio Engineers
Institute of Radio Engineers
The Institute of Radio Engineers was a professional organization which existed from 1912 until January 1, 1963, when it merged with the American Institute of Electrical Engineers to form the Institute of Electrical and Electronics Engineers .-Founding:Following several attempts to form a...

 in 1923.

He joined Katharine B. Blodgett to study thin films and surface adsorption. They introduced the concept of a monolayer
Monolayer
- Chemistry :A Langmuir monolayer or insoluble monolayer is a one-molecule thick layer of an insoluble organic material spread onto an aqueous subphase. Traditional compounds used to prepare Langmuir monolayers are amphiphilic materials that possess a hydrophilic headgroup and a hydrophobic tail...

 (a layer of material one molecule thick) and the two-dimensional physics which describe such a surface. In 1932 he received the Nobel Prize in Chemistry
Nobel Prize in Chemistry
The Nobel Prize in Chemistry is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outstanding contributions in chemistry, physics, literature,...

 "for his discoveries and investigations in surface chemistry."

In 1938, Langmuir's scientific interests began to turn to atmospheric science and meteorology
Meteorology
Meteorology is the interdisciplinary scientific study of the atmosphere. Studies in the field stretch back millennia, though significant progress in meteorology did not occur until the 18th century. The 19th century saw breakthroughs occur after observing networks developed across several countries...

. One of his first ventures, although tangentially related, was a refutation of the claim of entomologist Charles H. T. Townsend that the deer botfly
Deer botfly
The name deer botfly refers to any species in the genus Cephenemyia, within the family Oestridae. They are large, gray-brown flies, often very accurate mimics of bumblebees. They attack chiefly the nostrils and pharyngeal cavity of members of the deer family. The larva of Cephenemyia auribarbis,...

 flew at speeds in excess of 800 miles per hour. Langmuir estimated the fly's true speed at 25 miles per hour.

After observing windrow
Windrow
A windrow is a row of cut hay or small grain crop. It is allowed to dry before being baled, combined, or rolled. For hay, the windrow is often formed by a hay rake, which rakes hay that has been cut by a mower machine or by scythe into a row, or it may naturally form as the hay is mowed...

s of drifting seaweed in the Sargasso Sea
Sargasso Sea
The Sargasso Sea is a region in the middle of the North Atlantic Ocean, surrounded by ocean currents. It is bounded on the west by the Gulf Stream; on the north, by the North Atlantic Current; on the east, by the Canary Current; and on the south, by the North Atlantic Equatorial Current. This...

 he discovered a wind-driven surface circulation in the sea. It is now called the Langmuir circulation
Langmuir circulation
Langmuir circulation is a wind driven helix circulation in the ocean with the axis almost parallel to the wind. Irving Langmuir discovered this phenomenon after noticing windrows of seaweed in the Sargasso Sea in 1938....

.

During World War II
World War II
World War II, or the Second World War , was a global conflict lasting from 1939 to 1945, involving most of the world's nations—including all of the great powers—eventually forming two opposing military alliances: the Allies and the Axis...

, Langmuir worked on improving naval sonar
Sonar
Sonar is a technique that uses sound propagation to navigate, communicate with or detect other vessels...

 for submarine detection, and later to develop protective smoke screens and methods for deicing
Deicing
For snow and ice control on roadways and similar facilities, see Snow removalDe-icing is defined as removal of snow, ice or frost from a surface...

 aircraft wings. This research led him to theorize that the introduction of dry ice
Dry ice
Dry ice, sometimes referred to as "Cardice" or as "card ice" , is the solid form of carbon dioxide. It is used primarily as a cooling agent. Its advantages include lower temperature than that of water ice and not leaving any residue...

 and iodide
Iodide
An iodide ion is the ion I−. Compounds with iodine in formal oxidation state −1 are called iodides. This page is for the iodide ion and its salts. For information on organoiodides, see organohalides. In everyday life, iodide is most commonly encountered as a component of iodized salt,...

 into a sufficiently moist cloud of low temperature could induce precipitation (cloud seeding
Cloud seeding
Cloud seeding, a form of intentional weather modification, is the attempt to change the amount or type of precipitation that falls from clouds, by dispersing substances into the air that serve as cloud condensation or ice nuclei, which alter the microphysical processes within the cloud...

); though in frequent practice, particularly in Australia and the People's Republic of China, the efficiency of this technique remains controversial today.

In 1953 Langmuir coined the term "pathological science
Pathological science
Pathological science is the process in science in which "people are tricked into false results ... by subjective effects, wishful thinking or threshold interactions". The term was first used by Irving Langmuir, Nobel Prize-winning chemist, during a 1953 colloquium at the Knolls Research Laboratory...

", describing research conducted with accordance to the scientific method
Scientific method
Scientific method refers to a body of techniques for investigating phenomena, acquiring new knowledge, or correcting and integrating previous knowledge. To be termed scientific, a method of inquiry must be based on gathering empirical and measurable evidence subject to specific principles of...

, but tainted by unconscious bias or subjective effects. This is in contrast to pseudoscience
Pseudoscience
Pseudoscience is a claim, belief, or practice which is presented as scientific, but which does not adhere to a valid scientific method, lacks supporting evidence or plausibility, cannot be reliably tested, or otherwise lacks scientific status...

, which has no pretense of following the scientific method. In his original speech, he presented ESP
Extra-sensory perception
Extrasensory perception involves reception of information not gained through the recognized physical senses but sensed with the mind. The term was coined by Frederic Myers, and adopted by Duke University psychologist J. B. Rhine to denote psychic abilities such as telepathy, clairaudience, and...

 and flying saucers as examples of pathological science; since then, the label has been applied to polywater
Polywater
Polywater was a hypothetical polymerized form of water that was the subject of much scientific controversy during the late 1960s. By 1969 the popular press had taken notice, and by 1970 doubts about its authenticity were being circulated. By 1973 it was found to be illusory...

 and cold fusion
Cold fusion
Cold fusion, also called low-energy nuclear reaction , refers to the hypothesis that nuclear fusion might explain the results of a group of experiments conducted at ordinary temperatures . Both the experimental results and the hypothesis are disputed...

.

His house
Irving Langmuir House
The Irving Langmuir House was the home of physicist-chemist Irving Langmuir, winner of the 1932 Nobel Prize during his research career with General Electric...

 in Schenectady, was designated a National Historic Landmark
National Historic Landmark
A National Historic Landmark is a building, site, structure, object, or district, that is officially recognized by the United States government for its historical significance...

 in 1976.

Personal life

Langmuir was married to Marion Mersereau in 1912 with whom he adopted two children: Kenneth and Barbara. After a short illness, he died in Woods Hole, Massachusetts
Woods Hole, Massachusetts
Woods Hole is a census-designated place in the town of Falmouth in Barnstable County, Massachusetts, United States. It lies at the extreme southwest corner of Cape Cod, near Martha's Vineyard and the Elizabeth Islands...

 from a heart attack in 1957. His obituary ran on the front page of The New York Times
The New York Times
The New York Times is an American daily newspaper founded and continuously published in New York City since 1851. The New York Times has won 106 Pulitzer Prizes, the most of any news organization...

.

In Fiction

According to author Kurt Vonnegut
Kurt Vonnegut
Kurt Vonnegut, Jr. was a 20th century American writer. His works such as Cat's Cradle , Slaughterhouse-Five and Breakfast of Champions blend satire, gallows humor and science fiction. He was known for his humanist beliefs and was honorary president of the American Humanist Association.-Early...

, Langmuir was the inspiration for his fictional scientist Dr. Felix Hoenikker in the novel Cat's Cradle
Cat's Cradle
Cat's Cradle is the fourth novel by American writer Kurt Vonnegut, first published in 1963. It explores issues of science, technology, and religion, satirizing the arms race and many other targets along the way...

. The character's invention of ice-nine
Ice-nine
Ice-nine is a fictional material appearing in Kurt Vonnegut's novel Cat's Cradle. It is supposed to be a more stable polymorph of water than common ice which instead of melting at 0 degrees Celsius , melts at 45.8 °C...

 eventually destroyed the world. Langmuir had worked with Vonnegut's brother, Bernard Vonnegut
Bernard Vonnegut
Bernard Vonnegut was an American atmospheric scientist credited with discovering that silver iodide could be used effectively in cloud seeding to produce snow and rain...

.

Honors


Patents

  • Langmuir, , "Incandescent Electric Lamp"
  • Langmuir, , "Electron-discharge apparatus and method of operating the same"
  • Langmuir, , "Method of and apparatus for controlling x-ray tubes"

See also

  • Irving Langmuir House
    Irving Langmuir House
    The Irving Langmuir House was the home of physicist-chemist Irving Langmuir, winner of the 1932 Nobel Prize during his research career with General Electric...

  • Langmuir isotherm
  • Langmuir probe
    Langmuir probe
    A Langmuir probe is a device named after Nobel Prize winning physicist Irving Langmuir, used to determine the electron temperature, electron density, and electric potential of a plasma. It works by inserting one or more electrodes into a plasma, with a constant or time-varying electric potential...

  • Child-Langmuir Law
  • Langmuir Trough
  • Langmuir circulation
    Langmuir circulation
    Langmuir circulation is a wind driven helix circulation in the ocean with the axis almost parallel to the wind. Irving Langmuir discovered this phenomenon after noticing windrows of seaweed in the Sargasso Sea in 1938....

    , a wind-driven ocean circulation
  • Langmuir equation
    Langmuir equation
    The Langmuir equation relates the coverage or adsorption of molecules on a solid surface to gas pressure or concentration of a medium above the solid surface at a fixed temperature. The equation was developed by Irving Langmuir in 1916...

    , an equation that relates the coverage or adsorption of molecules on a solid surface to gas pressure or concentration of a medium above the solid surface at a fixed temperature
  • Langmuir wave, a rapid oscillation of the electron density in conducting media such as plasmas or metals

Further reading

  • Patrick Coffey, Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry, Oxford University Press, 2008. ISBN 978-0-19-532134-0

External links

The source of this article is wikipedia, the free encyclopedia.  The text of this article is licensed under the GFDL.
 
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