Baddeleyite is a rare zirconium oxide mineral

Mineral

A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

 (Zr

Zirconium

Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...

O

Oxygen

Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

₂ or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. Baddeleyite is a refractory

Refractory

A refractory material is one that retains its strength at high temperatures. ASTM C71 defines refractories as "non-metallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above...

 mineral, with a melting point

Melting point

The melting point of a solid is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at standard atmospheric pressure...

 of 2700 °C. Hafnium

Hafnium

Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869. Hafnium was the penultimate stable...

 is a substituting impurity and may be present in quantities ranging from 0.1 to several percents.

Discovery and occurrence

Baddeleyite was first described in 1892 from Ratnapura District, Sri Lanka

Sri Lanka

Sri Lanka, officially the Democratic Socialist Republic of Sri Lanka is a country off the southern coast of the Indian subcontinent. Known until 1972 as Ceylon , Sri Lanka is an island surrounded by the Indian Ocean, the Gulf of Mannar and the Palk Strait, and lies in the vicinity of India and the...

. It was named after Joseph Baddeley, who described the occurrences in Sri Lanka. It has also been described from Minas Gerais

Minas Gerais

Minas Gerais is one of the 26 states of Brazil, of which it is the second most populous, the third richest, and the fourth largest in area. Minas Gerais is the Brazilian state with the largest number of Presidents of Brazil, the current one, Dilma Rousseff, being one of them. The capital is the...

 and Jacupiranga

Jacupiranga

Jacupiranga is a municipality in the state of São Paulo in Brazil. The population in 2004 is 18,380 and the area is 709.98 km². The elevation is 33 m. This place name comes from the Tupi language.-External links:**...

, São Paulo

São Paulo

São Paulo is the largest city in Brazil, the largest city in the southern hemisphere and South America, and the world's seventh largest city by population. The metropolis is anchor to the São Paulo metropolitan area, ranked as the second-most populous metropolitan area in the Americas and among...

, Brazil

Brazil

Brazil , officially the Federative Republic of Brazil , is the largest country in South America. It is the world's fifth largest country, both by geographical area and by population with over 192 million people...

, and a wide variety of worldwide locations.

Baddeleyite is often found as detrital

Detrital

Detritus is a geological term used to describe particles of rock derived from pre-existing rock through processes of weathering and erosion. Detrital particles can consist of lithic fragments , or of monomineralic fragments...

 grains in gravel

Gravel

Gravel is composed of unconsolidated rock fragments that have a general particle size range and include size classes from granule- to boulder-sized fragments. Gravel can be sub-categorized into granule and cobble...

s. Its primary occurrence is in high temperature veins and as an accessory mineral in syenite

Syenite

Syenite is a coarse-grained intrusive igneous rock of the same general composition as granite but with the quartz either absent or present in relatively small amounts Syenite is a coarse-grained intrusive igneous rock of the same general composition as granite but with the quartz either absent or...

, diabase

Diabase

Diabase or dolerite is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. In North American usage, the term diabase refers to the fresh rock, whilst elsewhere the term dolerite is used for the fresh rock and diabase refers to altered material...

, gabbro

Gabbro

Gabbro refers to a large group of dark, coarse-grained, intrusive mafic igneous rocks chemically equivalent to basalt. The rocks are plutonic, formed when molten magma is trapped beneath the Earth's surface and cools into a crystalline mass....

, anorthosite

Anorthosite

Anorthosite is a phaneritic, intrusive igneous rock characterized by a predominance of plagioclase feldspar , and a minimal mafic component...

, carbonatite

Carbonatite

Carbonatites are intrusive or extrusive igneous rocks defined by mineralogic composition consisting of greater than 50 percent carbonate minerals. Carbonatites may be confused with marble, and may require geochemical verification....

, kimberlite

Kimberlite

Kimberlite is a type of potassic volcanic rock best known for sometimes containing diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond in 1871 spawned a diamond rush, eventually creating the Big Hole....

 and lamproite

Lamproite

Lamproites are ultrapotassic mantle-derived volcanic and subvolcanic rocks. They have low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements....

 intrusion

Intrusion

An intrusion is liquid rock that forms under Earth's surface. Magma from under the surface is slowly pushed up from deep within the earth into any cracks or spaces it can find, sometimes pushing existing country rock out of the way, a process that can take millions of years. As the rock slowly...

s. It has also been reported from tektite

Tektite

Tektites are natural glass rocks up to a few centimeters in size, which most scientists argue were formed by the impact of large meteorites on Earth's surface. Tektites are typically black or olive-green, and their shape varies from rounded to irregular.Tektites are among the "driest" rocks, with...

s, meteorite

Meteorite

A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

s and lunar basalt

Moon rock

Moon rock describes rock that formed on the Earth's moon. The term is also loosely applied to other lunar materials collected during the course of human exploration of the Moon.The rocks collected from the Moon are measured by radiometric dating techniques...

. Associated minerals include ilmenite

Ilmenite

Ilmenite is a weakly magnetic titanium-iron oxide mineral which is iron-black or steel-gray. It is a crystalline iron titanium oxide . It crystallizes in the trigonal system, and it has the same crystal structure as corundum and hematite....

, zirkelite

Zirkelite

Zirkelite is an oxide mineral with formula: Zr2O7. It occurs as well-formed fine sized isometric crystals. It is a black, brown or yellow mineral with a hardness of 5.5 and a specific gravity of 4.7.-Name and discovery:...

, apatite

Apatite

Apatite is a group of phosphate minerals, usually referring to hydroxylapatite, fluorapatite, chlorapatite and bromapatite, named for high concentrations of OH−, F−, Cl− or Br− ions, respectively, in the crystal...

, magnetite

Magnetite

Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

, perovskite

Perovskite

A perovskite structure is any material with the same type of crystal structure as calcium titanium oxide , known as the perovskite structure, or XIIA2+VIB4+X2−3 with the oxygen in the face centers. Perovskites take their name from this compound, which was first discovered in the Ural mountains of...

 in the Jacupiranga mine, Brazil; and fluorite

Fluorite

Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...

, nepheline

Nepheline

Nepheline, also called nephelite , is a feldspathoid: a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites...

, pyrochlore

Pyrochlore

Pyrochlore 2Nb2O6 is a solid solution between the niobium end member , and the tantalum end member .-Occurrence:...

 and allanite

Allanite

Allanite is a sorosilicate group of minerals within the broader epidote group that contain a significant amount of rare earth elements. The mineral occurs mainly in metamorphosed clay rich sediments and felsic igneous rocks...

 at Monte Somma, Italy

Italy

Italy , officially the Italian Republic languages]] under the European Charter for Regional or Minority Languages. In each of these, Italy's official name is as follows:;;;;;;;;), is a unitary parliamentary republic in South-Central Europe. To the north it borders France, Switzerland, Austria and...

.

Because of their refractory nature and stability under diverse conditions, baddeleyite grains, along with zircon

Zircon

Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is 1–x4x–y...

, are used for uranium-lead radiometric age

Radiometric dating

Radiometric dating is a technique used to date materials such as rocks, usually based on a comparison between the observed abundance of a naturally occurring radioactive isotope and its decay products, using known decay rates...

determinations.