Bulk modulus
Encyclopedia
The bulk modulus of a substance measures the substance's resistance to uniform compression. It is defined as the pressure
Pressure
Pressure is the force per unit area applied in a direction perpendicular to the surface of an object. Gauge pressure is the pressure relative to the local atmospheric or ambient pressure.- Definition :...

 increase needed to decrease the volume
Volume
Volume is the quantity of three-dimensional space enclosed by some closed boundary, for example, the space that a substance or shape occupies or contains....

 by a factor of 1/e. Its base unit is the pascal
Pascal (unit)
The pascal is the SI derived unit of pressure, internal pressure, stress, Young's modulus and tensile strength, named after the French mathematician, physicist, inventor, writer, and philosopher Blaise Pascal. It is a measure of force per unit area, defined as one newton per square metre...

.

Definition

The bulk modulus K>0 can be formally defined by the equation:


where P is pressure, V is volume, and ∂P/∂V denotes the partial derivative
Partial derivative
In mathematics, a partial derivative of a function of several variables is its derivative with respect to one of those variables, with the others held constant...

 of pressure with respect to volume. The inverse of the bulk modulus gives a substance's compressibility.

Other moduli describe the material's response (strain
Strain (materials science)
In continuum mechanics, the infinitesimal strain theory, sometimes called small deformation theory, small displacement theory, or small displacement-gradient theory, deals with infinitesimal deformations of a continuum body...

) to other kinds of stress
Stress (physics)
In continuum mechanics, stress is a measure of the internal forces acting within a deformable body. Quantitatively, it is a measure of the average force per unit area of a surface within the body on which internal forces act. These internal forces are a reaction to external forces applied on the body...

: the shear modulus describes the response to shear, and Young's modulus
Young's modulus
Young's modulus is a measure of the stiffness of an elastic material and is a quantity used to characterize materials. It is defined as the ratio of the uniaxial stress over the uniaxial strain in the range of stress in which Hooke's Law holds. In solid mechanics, the slope of the stress-strain...

 describes the response to linear stress. For a fluid
Fluid
In physics, a fluid is a substance that continually deforms under an applied shear stress. Fluids are a subset of the phases of matter and include liquids, gases, plasmas and, to some extent, plastic solids....

, only the bulk modulus is meaningful. For an anisotropic solid such as wood
Wood
Wood is a hard, fibrous tissue found in many trees. It has been used for hundreds of thousands of years for both fuel and as a construction material. It is an organic material, a natural composite of cellulose fibers embedded in a matrix of lignin which resists compression...

 or paper
Paper
Paper is a thin material mainly used for writing upon, printing upon, drawing or for packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....

, these three moduli do not contain enough information to describe its behaviour, and one must use the full generalized Hooke's law
Hooke's law
In mechanics, and physics, Hooke's law of elasticity is an approximation that states that the extension of a spring is in direct proportion with the load applied to it. Many materials obey this law as long as the load does not exceed the material's elastic limit. Materials for which Hooke's law...

.

Thermodynamic relation

Strictly speaking, the bulk modulus is a thermodynamic quantity, and it is necessary to specify how the temperature varies in order to specify a bulk modulus: constant-temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

 (isothermal ), constant-entropy
Entropy
Entropy is a thermodynamic property that can be used to determine the energy available for useful work in a thermodynamic process, such as in energy conversion devices, engines, or machines. Such devices can only be driven by convertible energy, and have a theoretical maximum efficiency when...

 (adiabatic
Adiabatic process
In thermodynamics, an adiabatic process or an isocaloric process is a thermodynamic process in which the net heat transfer to or from the working fluid is zero. Such a process can occur if the container of the system has thermally-insulated walls or the process happens in an extremely short time,...

 ), and other variations are possible. In practice, such distinctions are usually only relevant for gas
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...

es.

For a gas, the adiabatic bulk modulus is approximately given by


and the isothermal bulk modulus is approximately given by


where
γ is the adiabatic index, sometimes called κ.
P is the pressure.


In a fluid, the bulk modulus K and the density
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...

 ρ determine the speed of sound
Speed of sound
The speed of sound is the distance travelled during a unit of time by a sound wave propagating through an elastic medium. In dry air at , the speed of sound is . This is , or about one kilometer in three seconds or approximately one mile in five seconds....

 c (pressure waves
P-wave
P-waves are a type of elastic wave, also called seismic waves, that can travel through gases , solids and liquids, including the Earth. P-waves are produced by earthquakes and recorded by seismographs...

), according to the Newton-Laplace formula
Solids can also sustain transverse waves: for these materials one additional elastic modulus
Elastic modulus
An elastic modulus, or modulus of elasticity, is the mathematical description of an object or substance's tendency to be deformed elastically when a force is applied to it...

, for example the shear modulus, is needed to determine wave speeds.

Measurement

It is possible to measure the bulk modulus using powder diffraction under applied pressure.

Selected values

Approximate bulk modulus (K) for common materials
Material Bulk modulus in GPa Bulk modulus in ksi
Glass
Glass
Glass is an amorphous solid material. Glasses are typically brittle and optically transparent.The most familiar type of glass, used for centuries in windows and drinking vessels, is soda-lime glass, composed of about 75% silica plus Na2O, CaO, and several minor additives...

 (see also diagram below table)
to
Steel
Steel
Steel is an alloy that consists mostly of iron and has a carbon content between 0.2% and 2.1% by weight, depending on the grade. Carbon is the most common alloying material for iron, but various other alloying elements are used, such as manganese, chromium, vanadium, and tungsten...

Diamond
Diamond
In mineralogy, diamond is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions...



Material with bulk modulus value of 35GPa needs external pressure of 0.35 GPa (~3500Bar) to reduce the volume by one percent.
Approximate bulk modulus (K) for other substances
Water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

(value increases at higher pressures)
Air (adiabatic bulk modulus)
Air (constant temperature bulk modulus)
Solid helium
Helium
Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas that heads the noble gas group in the periodic table...

(approximate)
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