Sodium poly(aspartate)
Encyclopedia
Sodium poly is a condensation polymer
based on the amino acid
aspartic acid
.
reaction is an example of a step-growth polymerization
to a polyamide
and in one practical procedure aspartic acid is simply heated to 180 °C resulting in water
release and the formation of a poly(succinimide) with succinimide
repeating units. In the subsequent step this polymer is reacted with sodium hydroxide in water which results in partial cleavage of the amide
bonds
. Two different bonds (α
and β
) are hydrolyzed
resulting in a sodium poly(aspartate) copolymer with 30% α-linkages and 70% β-linkages.
alternative to several materials such as sodium polyacrylate
used in disposable diaper
s and agriculture.
In addition and due to its water-solubility and ability to chelate
metal ions, polyaspartate is used as a biodegradeable anti-scaling
agent and a corrosion inhibitor
.
Condensation polymer
Condensation polymers are any kind of polymers formed through a condensation reaction, releasing small molecules as by-products such as water or methanol, as opposed to addition polymers which involve the reaction of unsaturated monomers...
based on the amino acid
Amino acid
Amino acids are molecules containing an amine group, a carboxylic acid group and a side-chain that varies between different amino acids. The key elements of an amino acid are carbon, hydrogen, oxygen, and nitrogen...
aspartic acid
Aspartic acid
Aspartic acid is an α-amino acid with the chemical formula HOOCCHCH2COOH. The carboxylate anion, salt, or ester of aspartic acid is known as aspartate. The L-isomer of aspartate is one of the 20 proteinogenic amino acids, i.e., the building blocks of proteins...
.
Polymerization
The polymerizationPolymerization
In polymer chemistry, polymerization is a process of reacting monomer molecules together in a chemical reaction to form three-dimensional networks or polymer chains...
reaction is an example of a step-growth polymerization
Step-growth polymerization
Step-growth polymerization refers to a type of polymerization mechanism in which bi-functional or multifunctional monomers react to form first dimers, then trimers, longer oligomers and eventually long chain polymers. Many naturally occurring and some synthetic polymers are produced by step-growth...
to a polyamide
Polyamide
A polyamide is a polymer containing monomers of amides joined by peptide bonds. They can occur both naturally and artificially, examples being proteins, such as wool and silk, and can be made artificially through step-growth polymerization or solid-phase synthesis, examples being nylons, aramids,...
and in one practical procedure aspartic acid is simply heated to 180 °C resulting in water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
release and the formation of a poly(succinimide) with succinimide
Succinimide
Succinimide is a cyclic imide with the formula C4H5NO2. It is used in a variety of organic syntheses, as well as in some industrial silver plating processes.-Succinimides:...
repeating units. In the subsequent step this polymer is reacted with sodium hydroxide in water which results in partial cleavage of the amide
Amide
In chemistry, an amide is an organic compound that contains the functional group consisting of a carbonyl group linked to a nitrogen atom . The term refers both to a class of compounds and a functional group within those compounds. The term amide also refers to deprotonated form of ammonia or an...
bonds
Covalent bond
A covalent bond is a form of chemical bonding that is characterized by the sharing of pairs of electrons between atoms. The stable balance of attractive and repulsive forces between atoms when they share electrons is known as covalent bonding....
. Two different bonds (α
Alpha (letter)
Alpha is the first letter of the Greek alphabet. In the system of Greek numerals it has a value of 1. It was derived from the Phoenician letter Aleph...
and β
Beta (letter)
Beta is the second letter of the Greek alphabet. In Ancient Greek, beta represented the voiced bilabial plosive . In Modern Greek, it represents the voiced labiodental fricative ....
) are hydrolyzed
Hydrolysis
Hydrolysis is a chemical reaction during which molecules of water are split into hydrogen cations and hydroxide anions in the process of a chemical mechanism. It is the type of reaction that is used to break down certain polymers, especially those made by condensation polymerization...
resulting in a sodium poly(aspartate) copolymer with 30% α-linkages and 70% β-linkages.
Uses
This material can be synthesized in an environmentally friendly way and is biodegradeable, thus it is a greenGreen chemistry
Green chemistry, also called sustainable chemistry, is a philosophy of chemical research and engineering that encourages the design of products and processes that minimize the use and generation of hazardous substances...
alternative to several materials such as sodium polyacrylate
Sodium polyacrylate
Sodium polyacrylate, also known as waterlock, is a polymer with the chemical formula [-CH2-CH-]n widely used in consumer products. It has the ability to absorb as much as 200 to 300 times its mass in water. Acrylate polymers generally are considered to possess an anionic charge...
used in disposable diaper
Diaper
A nappy or a diaper is a kind of pant that allows one to defecate or urinate on oneself discreetly. When diapers become soiled, they require changing; this process is often performed by a second person such as a parent or caregiver...
s and agriculture.
In addition and due to its water-solubility and ability to chelate
Chelation
Chelation is the formation or presence of two or more separate coordinate bonds between apolydentate ligand and a single central atom....
metal ions, polyaspartate is used as a biodegradeable anti-scaling
Fouling
Fouling refers to the accumulation of unwanted material on solid surfaces, most often in an aquatic environment. The fouling material can consist of either living organisms or a non-living substance...
agent and a corrosion inhibitor
Corrosion inhibitor
A corrosion inhibitor is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy. The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and flow regime...
.