Sanidine is the high temperature form of potassium feldspar

Feldspar

Feldspars are a group of rock-forming tectosilicate minerals which make up as much as 60% of the Earth's crust....

 (K,Na)(Si,Al)₄O₈. Sanidine most typically occurs in felsic

Felsic

The word "felsic" is a term used in geology to refer to silicate minerals, magma, and rocks which are enriched in the lighter elements such as silicon, oxygen, aluminium, sodium, and potassium....

 volcanic rock

Volcanic rock

Volcanic rock is a rock formed from magma erupted from a volcano. In other words, it is an igneous rock of volcanic origin...

s such as obsidian

Obsidian

Obsidian is a naturally occurring volcanic glass formed as an extrusive igneous rock.It is produced when felsic lava extruded from a volcano cools rapidly with minimum crystal growth...

, rhyolite

Rhyolite

This page is about a volcanic rock. For the ghost town see Rhyolite, Nevada, and for the satellite system, see Rhyolite/Aquacade.Rhyolite is an igneous, volcanic rock, of felsic composition . It may have any texture from glassy to aphanitic to porphyritic...

 and trachyte

Trachyte

Trachyte is an igneous volcanic rock with an aphanitic to porphyritic texture. The mineral assemblage consists of essential alkali feldspar; relatively minor plagioclase and quartz or a feldspathoid such as nepheline may also be present....

. Sanidine crystallizes in the monoclinic crystal system. Orthoclase

Orthoclase

Orthoclase is an important tectosilicate mineral which forms igneous rock. The name is from the Greek for "straight fracture," because its two cleavage planes are at right angles to each other. Alternate names are alkali feldspar and potassium feldspar...

 is a monoclinic polymorph

Polymorphism (materials science)

Polymorphism in materials science is the ability of a solid material to exist in more than one form or crystal structure. Polymorphism can potentially be found in any crystalline material including polymers, minerals, and metals, and is related to allotropy, which refers to chemical elements...

 stable at lower temperatures. At yet lower temperatures, microcline

Microcline

Microcline is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures...

, a triclinic polymorph of potassium feldspar, is stable.

Due to the high temperature and rapid quenching, sanidine can contain more sodium in its structure than the two polymorphs that equilibrated at lower temperatures. Sanidine and high albite

Albite

Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. As such it represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula NaAlSi3O8. It is a tectosilicate. Its color is usually pure white, hence...

 constitute a solid solution

Solid solution

A solid solution is a solid-state solution of one or more solutes in a solvent. Such a mixture is considered a solution rather than a compound when the crystal structure of the solvent remains unchanged by addition of the solutes, and when the mixture remains in a single homogeneous phase...

 series with intermediate compositions termed anorthoclase

Anorthoclase

The mineral anorthoclase is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and between 64 and 90 percent of NaAlSi3O8....

. Exsolution of an albite phase does occur; resulting cryptoperthite can best be observed in electron microprobe

Electron microprobe

An electron microprobe , also known as an electron probe microanalyzer or electron micro probe analyzer , is an analytical tool used to non-destructively determine the chemical composition of small volumes of solid materials...

images.