QCD matter
Encyclopedia
Quark matter or QCD matter refers to any of a number of theorized phases
Phase (matter)
In the physical sciences, a phase is a region of space , throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, and chemical composition...

 of matter whose degrees of freedom include quark
Quark
A quark is an elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. Due to a phenomenon known as color confinement, quarks are never directly...

s and gluon
Gluon
Gluons are elementary particles which act as the exchange particles for the color force between quarks, analogous to the exchange of photons in the electromagnetic force between two charged particles....

s. These theoretical phases would occur at extremely high temperatures and densities, billions of times higher than can be produced in equilibrium in laboratories. Under such extreme conditions, the familiar structure of matter, where the basic constituents are nuclei
Atomic nucleus
The nucleus is the very dense region consisting of protons and neutrons at the center of an atom. It was discovered in 1911, as a result of Ernest Rutherford's interpretation of the famous 1909 Rutherford experiment performed by Hans Geiger and Ernest Marsden, under the direction of Rutherford. The...

 (consisting of nucleon
Nucleon
In physics, a nucleon is a collective name for two particles: the neutron and the proton. These are the two constituents of the atomic nucleus. Until the 1960s, the nucleons were thought to be elementary particles...

s which are bound states of quarks) and electrons, is disrupted. In quark matter it is more appropriate to treat the quarks themselves as the basic degrees of freedom.

In the standard model
Standard Model
The Standard Model of particle physics is a theory concerning the electromagnetic, weak, and strong nuclear interactions, which mediate the dynamics of the known subatomic particles. Developed throughout the mid to late 20th century, the current formulation was finalized in the mid 1970s upon...

 of particle physics, the strong force
Strong interaction
In particle physics, the strong interaction is one of the four fundamental interactions of nature, the others being electromagnetism, the weak interaction and gravitation. As with the other fundamental interactions, it is a non-contact force...

 is described by the theory of quantum chromodynamics
Quantum chromodynamics
In theoretical physics, quantum chromodynamics is a theory of the strong interaction , a fundamental force describing the interactions of the quarks and gluons making up hadrons . It is the study of the SU Yang–Mills theory of color-charged fermions...

 (QCD). At ordinary temperatures or densities this force just confines the quarks into composite particles (hadrons) of size around 10−15 m = 1 femtometer = 1 fm (corresponding to the QCD energy scale ΛQCD ≈ 200 MeV
MEV
MeV and meV are multiples and submultiples of the electron volt unit referring to 1,000,000 eV and 0.001 eV, respectively.Mev or MEV may refer to:In entertainment:* Musica Elettronica Viva, an Italian musical group...

) and its effects are not noticeable at longer distances. However, when the temperature reaches the QCD energy scale (T
Electronvolt
In physics, the electron volt is a unit of energy equal to approximately joule . By definition, it is equal to the amount of kinetic energy gained by a single unbound electron when it accelerates through an electric potential difference of one volt...

 of order 1012 kelvin
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...

s) or the density rises to the point where the average inter-quark separation is less than 1 fm (quark chemical potential
Chemical potential
Chemical potential, symbolized by μ, is a measure first described by the American engineer, chemist and mathematical physicist Josiah Willard Gibbs. It is the potential that a substance has to produce in order to alter a system...

 μ around 400 MeV), the hadrons are melted into their constituent quarks, and the strong interaction becomes the dominant feature of the physics. Such phases are called quark matter or QCD matter.

The strength of the color force makes the properties of quark matter unlike gas or plasma, instead leading to a state of matter more reminiscent of a liquid. At high densities, quark matter is a Fermi liquid, but is predicted to exhibit color superconductivity
Color superconductivity
Color superconductivity is a phenomenon predicted to occur in quark matter if the baryon density is sufficiently high and the temperature is not too high...

 at high densities and temperatures below 1012 K.

Natural occurrence

  • In early Universe, at high temperature according to the Big Bang
    Big Bang
    The Big Bang theory is the prevailing cosmological model that explains the early development of the Universe. According to the Big Bang theory, the Universe was once in an extremely hot and dense state which expanded rapidly. This rapid expansion caused the young Universe to cool and resulted in...

     theory, when the universe was only a few tens of microseconds old, the phase of matter took the form of a hot phase of quark matter called the quark-gluon plasma
    Quark-gluon plasma
    A quark–gluon plasma or quark soup is a phase of quantum chromodynamics which exists at extremely high temperature and/or density. This phase consists of asymptotically free quarks and gluons, which are several of the basic building blocks of matter...

     (QGP).
  • Compact star
    Compact star
    In astronomy, the term compact star is used to refer collectively to white dwarfs, neutron stars, other exotic dense stars, and black holes. These objects are all small for their mass...

    s (neutron star
    Neutron star
    A neutron star is a type of stellar remnant that can result from the gravitational collapse of a massive star during a Type II, Type Ib or Type Ic supernova event. Such stars are composed almost entirely of neutrons, which are subatomic particles without electrical charge and with a slightly larger...

    s). A neutron star is much cooler than 1012 K, but it is compressed by its own weight to such high densities that it is reasonable to surmise that quark matter may exist in the core. Compact stars composed mostly or entirely of quark matter are called quark star
    Quark star
    A quark star or strange star is a hypothetical type of exotic star composed of quark matter, or strange matter. These are ultra-dense phases of degenerate matter theorized to form inside particularly massive neutron stars....

    s or strange stars, yet at this time no star with properties expected of these objects has been observed.
  • Strangelet
    Strangelet
    A strangelet is a hypothetical particle consisting of a bound state of roughly equal numbers of up, down, and strange quarks. Its size would be a minimum of a few femtometres across . Once the size becomes macroscopic , such an object is usually called a quark star or "strange star" rather than a...

    s. These are theoretically postulated (but as yet unobserved) lumps of strange matter
    Strange matter
    Strange matter is a particular form of quark matter, usually thought of as a "liquid" of up, down, and strange quarks. It is to be contrasted with nuclear matter, which is a liquid of neutrons and protons , and with non-strange quark matter, which is a quark liquid containing only up and down quarks...

     comprising nearly equal amounts of up, down and strange quarks.
  • Cosmic ray
    Cosmic ray
    Cosmic rays are energetic charged subatomic particles, originating from outer space. They may produce secondary particles that penetrate the Earth's atmosphere and surface. The term ray is historical as cosmic rays were thought to be electromagnetic radiation...

     impacts. Cosmic rays comprise also high energy atomic nuclei, particularly that of iron
    Iron
    Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

    . Laboratory experiments suggest that interaction with heavy noble gas in the upper atmosphere would lead to quark-gluon plasma formation.

Laboratory experiments

  • Heavy-ion collisions at very high energies can produce small short-lived regions of space whose energy density is comparable to that of the 20-microsecond-old universe. This has been achieved by colliding heavy nuclei at high speeds, and a first time claims of formation of quark-gluon plasma came from the SPS
    Super Proton Synchrotron
    The Super Proton Synchrotron is a particle accelerator of the synchrotron type at CERN. It is housed in a circular tunnel, in circumference, straddling the border of France and Switzerland near Geneva, Switzerland. The SPS was designed by a team led by John Adams, director-general of what was...

     accelerator at CERN
    CERN
    The European Organization for Nuclear Research , known as CERN , is an international organization whose purpose is to operate the world's largest particle physics laboratory, which is situated in the northwest suburbs of Geneva on the Franco–Swiss border...

     in February 2000. This work has been continued at more powerful accelerators, such as RHIC
    Relativistic Heavy Ion Collider
    The Relativistic Heavy Ion Collider is one of two existing heavy-ion colliders, and the only spin-polarized proton collider in the world. It is located at Brookhaven National Laboratory in Upton, New York and operated by an international team of researchers...

     at Brookhaven National Laboratory
    Brookhaven National Laboratory
    Brookhaven National Laboratory , is a United States national laboratory located in Upton, New York on Long Island, and was formally established in 1947 at the site of Camp Upton, a former U.S. Army base...

     in the USA, and as of 2010 at the LHC
    Large Hadron Collider
    The Large Hadron Collider is the world's largest and highest-energy particle accelerator. It is expected to address some of the most fundamental questions of physics, advancing the understanding of the deepest laws of nature....

     at CERN
    CERN
    The European Organization for Nuclear Research , known as CERN , is an international organization whose purpose is to operate the world's largest particle physics laboratory, which is situated in the northwest suburbs of Geneva on the Franco–Swiss border...

     located in the border area of Switzerland/France. There is good evidence that the quark-gluon plasma has also been produced at RHIC.

Thermodynamics

The context for understanding the thermodynamics of quark matter is the standard model
Standard Model
The Standard Model of particle physics is a theory concerning the electromagnetic, weak, and strong nuclear interactions, which mediate the dynamics of the known subatomic particles. Developed throughout the mid to late 20th century, the current formulation was finalized in the mid 1970s upon...

 of particle physics, which contains six different flavors of quarks, as well as lepton
Lepton
A lepton is an elementary particle and a fundamental constituent of matter. The best known of all leptons is the electron which governs nearly all of chemistry as it is found in atoms and is directly tied to all chemical properties. Two main classes of leptons exist: charged leptons , and neutral...

s like electron
Electron
The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...

s and neutrino
Neutrino
A neutrino is an electrically neutral, weakly interacting elementary subatomic particle with a half-integer spin, chirality and a disputed but small non-zero mass. It is able to pass through ordinary matter almost unaffected...

s. These interact via the strong interaction
Strong interaction
In particle physics, the strong interaction is one of the four fundamental interactions of nature, the others being electromagnetism, the weak interaction and gravitation. As with the other fundamental interactions, it is a non-contact force...

, electromagnetism
Electromagnetism
Electromagnetism is one of the four fundamental interactions in nature. The other three are the strong interaction, the weak interaction and gravitation...

, and also the weak interaction
Weak interaction
Weak interaction , is one of the four fundamental forces of nature, alongside the strong nuclear force, electromagnetism, and gravity. It is responsible for the radioactive decay of subatomic particles and initiates the process known as hydrogen fusion in stars...

 which allows one flavor of quark to turn into another. Electromagnetic interactions occur between particles that carry electrical charge; strong interactions occur between particles that carry color charge
Color charge
In particle physics, color charge is a property of quarks and gluons that is related to the particles' strong interactions in the theory of quantum chromodynamics . Color charge has analogies with the notion of electric charge of particles, but because of the mathematical complications of QCD,...

.

The correct thermodynamic treatment of quark matter depends on the physical context. For large quantities that exist for long periods of time (the "thermodynamic limit"), we must take into account the fact that the only conserved charges in the standard model are quark number (equivalent to baryon
Baryon
A baryon is a composite particle made up of three quarks . Baryons and mesons belong to the hadron family, which are the quark-based particles...

 number), electric charge, the eight color charges, and lepton number. Each of these can have an associated chemical potential. However, large volumes of matter must be electrically and color-neutral, which determines the electric and color charge chemical potentials. This leaves a three-dimensional phase space
Phase space
In mathematics and physics, a phase space, introduced by Willard Gibbs in 1901, is a space in which all possible states of a system are represented, with each possible state of the system corresponding to one unique point in the phase space...

, parameterized by quark chemical potential, lepton chemical potential, and temperature.

In compact stars quark matter would occupy cubic kilometers and exist for millions of years, so the thermodynamic limit is appropriate. However, the neutrinos escape, violating lepton number, so the phase space for quark matter in compact stars only has two dimensions, temperature (T) and quark number chemical potential μ. A strangelet
Strangelet
A strangelet is a hypothetical particle consisting of a bound state of roughly equal numbers of up, down, and strange quarks. Its size would be a minimum of a few femtometres across . Once the size becomes macroscopic , such an object is usually called a quark star or "strange star" rather than a...

 is not in the thermodynamic limit of large volume, so it is like an exotic nucleus: it may carry electric charge.

A heavy-ion collision is in neither the thermodynamic limit of large volumes nor long times. Putting aside questions of whether it is sufficiently equilibrated for thermodynamics to be applicable, there is certainly not enough time for weak interactions to occur, so flavor is conserved, and there are independent chemical potentials for all six quark flavors. The initial conditions (the impact parameter
Impact parameter
The impact parameter b is defined as the perpendicular distance between the path of a projectile and the center of the field U created by an object that the projectile is approaching...

 of the collision, the number of up and down quarks in the colliding nuclei, and the fact that they contain no quarks of other flavors) determine the chemical potentials. (Reference for this section:,).

Phase diagram

The phase diagram of quark matter is not well known, either experimentally or theoretically. A commonly conjectured form of the
phase diagram is shown in the figure. It is applicable to matter in a compact star, where the only relevant thermodynamic potentials are quark chemical potential μ and temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

 T. For guidance it also shows the typical values of μ and T in heavy-ion collisions and in the early universe. For readers who are not familiar with the concept of a chemical potential, it is helpful to think of μ as a measure of the imbalance between quarks and antiquarks in the system. Higher μ means a stronger bias favoring quarks over antiquarks. At low temperatures there are no antiquarks, and then higher μ generally means a higher density of quarks.

Ordinary atomic matter as we know it is really a mixed phase, droplets of nuclear matter (nuclei) surrounded by vacuum, which exists at the low-temperature phase boundary between vacuum and nuclear matter, at μ = 310 MeV and T close to zero. If we increase the quark density (i.e. increase μ) keeping the temperature low, we move into a phase of more and more compressed nuclear matter. Following this path corresponds to burrowing more and more deeply into a neutron star
Neutron star
A neutron star is a type of stellar remnant that can result from the gravitational collapse of a massive star during a Type II, Type Ib or Type Ic supernova event. Such stars are composed almost entirely of neutrons, which are subatomic particles without electrical charge and with a slightly larger...

. Eventually, at an unknown critical value of μ, there is a transition to quark matter. At ultra-high densities we expect to find the color-flavor-locked
Color-flavor locking
Color–flavor locking is a phenomenon that is expected to occur in ultra-high-density quark matter. The quarks form Cooper pairs, whose color properties are correlated with their flavor properties in a symmetric pattern...

 (CFL) phase of color-superconducting
Color superconductivity
Color superconductivity is a phenomenon predicted to occur in quark matter if the baryon density is sufficiently high and the temperature is not too high...

 quark matter. At intermediate densities we expect some other phases (labelled "non-CFL quark liquid" in the figure) whose nature is presently unknown,. They might be other forms of color-superconducting quark matter, or something different.

Now, imagine starting at the bottom left corner of the phase diagram, in the vacuum where μ = T = 0. If we heat up the system without introducing any preference for quarks over antiquarks, this corresponds to moving vertically upwards along the T axis. At first, quarks are still confined and we create a gas of hadrons (pion
Pion
In particle physics, a pion is any of three subatomic particles: , , and . Pions are the lightest mesons and they play an important role in explaining the low-energy properties of the strong nuclear force....

s, mostly). Then around T = 170 MeV there is a crossover to the quark gluon plasma: thermal fluctuations break up the pions, and we find a gas of quarks, antiquarks, and gluons, as well as lighter particles such as photons, electrons, positrons, etc. Following this path corresponds to travelling far back in time (so to say), to the state of the universe shortly after the big bang (where there was a very tiny preference for quarks over antiquarks).

The line that rises up from the nuclear/quark matter transition and then bends back towards the T axis, with its end marked by a star, is the conjectured boundary between confined and unconfined phases. Until recently it was also believed to be a boundary between phases where chiral symmetry is broken (low temperature and density) and phases where it is unbroken (high temperature and density). It is now known that the CFL phase exhibits chiral symmetry breaking, and other quark matter phases may also break chiral symmetry, so it is not clear whether this is really a chiral transition line. The line ends at the "chiral critical point
Critical point (thermodynamics)
In physical chemistry, thermodynamics, chemistry and condensed matter physics, a critical point, also called a critical state, specifies the conditions at which a phase boundary ceases to exist...

", marked by a star in this figure, which is a special temperature and density at which striking physical phenomena, analogous to critical opalescence
Critical opalescence
Critical opalescence is a phenomenon which arises in the region of a continuous, or second-order, phase transition. Originally reported by Thomas Andrews in 1869 for the liquid-gas transition in carbon dioxide, many other examples have been discovered since. The phenomenon is most commonly...

, are expected. (Reference for this section:,,).

For a complete description of phase diagram it is required that one must have complete understanding of dense, strongly interacting hadronic matter and strongly interacting quark matter from some underlying theory e.g quantum chromodynamics (QCD). However because such a description requires the proper understanding of QCD in its non-perturbative regime, which is still far from being completely understood,any theoretical advance remains very challenging.

Theoretical challenges: calculation techniques

The phase structure of quark matter remains mostly conjectural because it is difficult to perform calculations predicting the properties of quark matter. The reason is that QCD, the theory describing the dominant interaction between quarks, is strongly coupled at the densities and temperatures of greatest physical interest, and hence it is very hard to obtain any predictions from it. Here are brief descriptions of some of the standard approaches.

Lattice gauge theory

The only first-principles calculational tool currently available is lattice QCD
Lattice QCD
Lattice QCD is a well-established non-perturbative approach to solving the quantum chromodynamics theory of quarks and gluons. It is a lattice gauge theory formulated on a grid or lattice of points in space and time....

, i.e. brute-force computer calculations. Because of a technical obstacle known as the fermion sign problem, this method can only be used at low density and high temperature (μ < T), and it predicts that the crossover to the quark-gluon plasma will occur around T = 170 MeV However, it cannot be used to investigate the interesting color-superconducting phase structure at high density and low temperature.

Weak coupling theory

Because QCD is asymptotically free
Asymptotic freedom
In physics, asymptotic freedom is a property of some gauge theories that causes interactions between particles to become arbitrarily weak at energy scales that become arbitrarily large, or, equivalently, at length scales that become arbitrarily small .Asymptotic freedom is a feature of quantum...

 it becomes weakly coupled at unrealistically high densities, and diagrammatic
methods can be used. Such methods show that the CFL phase occurs at very high density. At high temperatures, however, diagrammatic methods are still not under full control.

Models

To obtain a rough idea of what phases might occur, one can use a model that has some of the same properties as QCD, but is easier to manipulate. Many physicists use Nambu-Jona-Lasinio model
Nambu-Jona-Lasinio model
In quantum field theory, the Nambu–Jona-Lasinio model is a theory of nucleons and mesons constructed from interacting Dirac fermions with chiral symmetry which parallels the construction of Cooper pairs from electrons in the BCS theory of superconductivity...

s, which contain no gluons, and replace the strong interaction with a four-fermion interaction. Mean-field methods are commonly used to analyse the phases. Another approach is the bag model, in which the effects of confinement are simulated by an additive energy density that penalizes unconfined quark matter.

Effective theories

Many physicists simply give up on a microscopic approach, and make informed guesses of the expected phases (perhaps based on NJL model results). For each phase, they then write down an effective theory for the low-energy excitations, in terms of a small number of parameters, and use it to make predictions that could allow those parameters to be fixed by experimental observations.

Other approaches

There are other methods that are sometimes used to shed light on QCD, but for various reasons have not yet yielded useful results in studying quark matter.

1/N expansion

Treat the number of colors N, which is actually 3, as a large number, and expand in powers of 1/N. It turns out that at high density the higher-order corrections are large, and the expansion gives misleading results.

Supersymmetry

Adding scalar quarks (squarks) and fermionic gluons (gluinos) to the theory makes it more tractable, but the thermodynamics of quark matter depends crucially on the fact that only fermions can carry quark number, and on the number of degrees of freedom in general.

Experimental challenges

Experimentally, it is hard to map the phase diagram of quark matter because it has been rather difficult to learn how to tune to high enough temperatures and density in the laboratory experiment using collisions of relativistic heavy ions as experimental tools. However, these collisions ultimately will provide information about the crossover from hadronic matter to QGP. It has been suggested that the observations of compact stars may also constrain the information about the high-density low-temperature region. Models of the cooling, spin-down, and precession of these stars offer information about the relevant properties of their interior. As observations become more precise, physicists hope to learn more.

One of the natural subjects for future research is the search for the exact location of the chiral critical point. Some ambitious lattice QCD calculations may have found evidence for it, and future calculations will clarify the situation. Heavy-ion collisions might be able to measure its position experimentally, but this will require scanning across a range of values of μ and T.

See also

  • Color–flavor locking
  • Lattice QCD
    Lattice QCD
    Lattice QCD is a well-established non-perturbative approach to solving the quantum chromodynamics theory of quarks and gluons. It is a lattice gauge theory formulated on a grid or lattice of points in space and time....

  • Quantum chromodynamics
    Quantum chromodynamics
    In theoretical physics, quantum chromodynamics is a theory of the strong interaction , a fundamental force describing the interactions of the quarks and gluons making up hadrons . It is the study of the SU Yang–Mills theory of color-charged fermions...

  • Quark-gluon plasma
    Quark-gluon plasma
    A quark–gluon plasma or quark soup is a phase of quantum chromodynamics which exists at extremely high temperature and/or density. This phase consists of asymptotically free quarks and gluons, which are several of the basic building blocks of matter...

  • Quark star
    Quark star
    A quark star or strange star is a hypothetical type of exotic star composed of quark matter, or strange matter. These are ultra-dense phases of degenerate matter theorized to form inside particularly massive neutron stars....

  • Strange matter
    Strange matter
    Strange matter is a particular form of quark matter, usually thought of as a "liquid" of up, down, and strange quarks. It is to be contrasted with nuclear matter, which is a liquid of neutrons and protons , and with non-strange quark matter, which is a quark liquid containing only up and down quarks...

  • Strangeness production
    Strangeness production
    Strangeness production is a signature and a diagnostic tool of quark-gluon plasma formation and properties. Unlike up and down quarks, from which everyday matter is made, strange quarks are formed in pair production processes in collisions between constituents of the plasma...

  • 1/N expansion
    1/N expansion
    In quantum field theory and statistical mechanics, the 1/N expansion is a particular perturbative analysis of quantum field theories with an internal symmetry group such as SO or SU...


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