Plutonium-244
Encyclopedia
Plutonium-244 is an isotope
of plutonium
that has a halflife of 80 million years. This is longer than any of the other isotopes of plutonium
and longer than any actinide
except for the three naturally abundant ones uranium-235
(700my), uranium-238
, and thorium-232. It is also longer than any other known radioactive isotope
s except samarium
-146 (103my), potassium-40
(1.25by), and a number of nearly stable isotopes with half-lives much longer than the age of the universe
, such as bismuth-209
(19 quintillion years).
More accurate measurements, beginning in the early 1970s, have detected primordial
plutonium-244. As the age of the Earth
is about 50 half-lives, the amount of plutonium-244 left should be very small. However, since plutonium-244 cannot be easily produced by natural neutron capture
in the low neutron activity environment of uranium ores (see below), its presence cannot plausibly be explained by any other means than creation by r-process
nucleosynthesis in supernovae
. Plutonium-244 is thus the shortest-lived and heaviest primordial isotope yet detected or theoretically predicted.
Unlike plutonium-238
, plutonium-239
, plutonium-240
, plutonium-241
, and plutonium-242
, plutonium-244 is not produced in quantity by the nuclear fuel cycle
, because further neutron capture
on plutonium-242 produces plutonium-243 which has a short halflife (5 hours) and quickly beta decay
s to americium-243 before having much opportunity to further capture neutrons in any but very high neutron flux environments. However a nuclear weapon
explosion can produce some plutonium-244 by rapid successive neutron capture
.
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...
of plutonium
Plutonium
Plutonium is a transuranic radioactive chemical element with the chemical symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, forming a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation...
that has a halflife of 80 million years. This is longer than any of the other isotopes of plutonium
Isotopes of plutonium
Plutonium is an artificial element, except for trace quantities of primordial 244Pu, and thus a standard atomic mass cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized long before being found in nature, the first isotope synthesized being 238Pu in 1940....
and longer than any actinide
Actinide
The actinide or actinoid series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium.The actinide series derives its name from the group 3 element actinium...
except for the three naturally abundant ones uranium-235
Uranium-235
- References :* .* DOE Fundamentals handbook: Nuclear Physics and Reactor theory , .* A piece of U-235 the size of a grain of rice can produce energy equal to that contained in three tons of coal or fourteen barrels of oil. -External links:* * * one of the earliest articles on U-235 for the...
(700my), uranium-238
Uranium-238
Uranium-238 is the most common isotope of uranium found in nature. It is not fissile, but is a fertile material: it can capture a slow neutron and after two beta decays become fissile plutonium-239...
, and thorium-232. It is also longer than any other known radioactive isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...
s except samarium
Samarium
Samarium is a chemical element with the symbol Sm, atomic number 62 and atomic weight 150.36. It is a moderately hard silvery metal which readily oxidizes in air. Being a typical member of the lanthanide series, samarium usually assumes the oxidation state +3...
-146 (103my), potassium-40
Potassium-40
Potassium-40 is a radioactive isotope of potassium which has a very long half-life of 1.248 years, or about 39.38 seconds.Potassium-40 is a rare example of an isotope which undergoes all three types of beta decay. About 89.28% of the time, it decays to calcium-40 with emission of a beta particle...
(1.25by), and a number of nearly stable isotopes with half-lives much longer than the age of the universe
Age of the universe
The age of the universe is the time elapsed since the Big Bang posited by the most widely accepted scientific model of cosmology. The best current estimate of the age of the universe is 13.75 ± 0.13 billion years within the Lambda-CDM concordance model...
, such as bismuth-209
Bismuth-209
Bismuth-209 is the isotope of bismuth with the longest half-life. It has 83 protons and 126 neutrons, and an atomic mass of 208.9803987 u. All primordial bismuth is of this isotope...
(19 quintillion years).
More accurate measurements, beginning in the early 1970s, have detected primordial
Primordial nuclide
In geochemistry and geonuclear physics, primordial nuclides or primordial isotopes are nuclides found on the earth that have existed in their current form since before Earth was formed. Only 288 such nuclides are known...
plutonium-244. As the age of the Earth
Age of the Earth
The age of the Earth is 4.54 billion years This age is based on evidence from radiometric age dating of meteorite material and is consistent with the ages of the oldest-known terrestrial and lunar samples...
is about 50 half-lives, the amount of plutonium-244 left should be very small. However, since plutonium-244 cannot be easily produced by natural neutron capture
Neutron capture
Neutron capture is a kind of nuclear reaction in which an atomic nucleus collides with one or more neutrons and they merge to form a heavier nucleus. Since neutrons have no electric charge they can enter a nucleus more easily than positively charged protons, which are repelled...
in the low neutron activity environment of uranium ores (see below), its presence cannot plausibly be explained by any other means than creation by r-process
R-process
The r-process is a nucleosynthesis process, likely occurring in core-collapse supernovae responsible for the creation of approximately half of the neutron-rich atomic nuclei that are heavier than iron. The process entails a succession of rapid neutron captures on seed nuclei, typically Ni-56,...
nucleosynthesis in supernovae
Stellar nucleosynthesis
Stellar nucleosynthesis is the collective term for the nuclear reactions taking place in stars to build the nuclei of the elements heavier than hydrogen. Some small quantity of these reactions also occur on the stellar surface under various circumstances...
. Plutonium-244 is thus the shortest-lived and heaviest primordial isotope yet detected or theoretically predicted.
Unlike plutonium-238
Plutonium-238
-External links:**...
, plutonium-239
Plutonium-239
Plutonium-239 is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 has also been used and is currently the secondary isotope. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in...
, plutonium-240
Plutonium-240
Plutonium-240 is an isotope of the metal plutonium formed when plutonium-239 captures a neutron. About 62% to 73% of the time when Pu-239 captures a neutron it undergoes fission; the rest of the time it forms Pu-240. The longer a nuclear fuel element remains in a nuclear reactor the greater the...
, plutonium-241
Plutonium-241
Plutonium-241 is an isotope of plutonium formed when plutonium-240 captures a neutron. Like Pu-239 but unlike 240Pu, 241Pu is fissile, with a neutron absorption cross section about 1/3 greater than 239Pu, and a similar probability of fissioning on neutron absorption, around 73%. In the non-fission...
, and plutonium-242
Plutonium-242
Pu-242 is one of the isotopes of plutonium, the second longest-lived, with a half-life of 373,300 years.242Pu's halflife is about 15 times as long as Pu-239's halflife; therefore it is 1/15 as radioactive and not one of the larger contributors to nuclear waste radioactivity.242Pu's gamma ray...
, plutonium-244 is not produced in quantity by the nuclear fuel cycle
Nuclear fuel cycle
The nuclear fuel cycle, also called nuclear fuel chain, is the progression of nuclear fuel through a series of differing stages. It consists of steps in the front end, which are the preparation of the fuel, steps in the service period in which the fuel is used during reactor operation, and steps in...
, because further neutron capture
Neutron capture
Neutron capture is a kind of nuclear reaction in which an atomic nucleus collides with one or more neutrons and they merge to form a heavier nucleus. Since neutrons have no electric charge they can enter a nucleus more easily than positively charged protons, which are repelled...
on plutonium-242 produces plutonium-243 which has a short halflife (5 hours) and quickly beta decay
Beta decay
In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a...
s to americium-243 before having much opportunity to further capture neutrons in any but very high neutron flux environments. However a nuclear weapon
Nuclear weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission or a combination of fission and fusion. Both reactions release vast quantities of energy from relatively small amounts of matter. The first fission bomb test released the same amount...
explosion can produce some plutonium-244 by rapid successive neutron capture
R-process
The r-process is a nucleosynthesis process, likely occurring in core-collapse supernovae responsible for the creation of approximately half of the neutron-rich atomic nuclei that are heavier than iron. The process entails a succession of rapid neutron captures on seed nuclei, typically Ni-56,...
.