Pinitol
Encyclopedia
Pinitol is a cyclitol
Cyclitol
Cyclitols are cycloalkanes containing one hydroxyl group on three or more ring atoms. They are cyclic polyols. Cyclitols are one of the compatible solutes which are formed in a plant as a response to salt or water stress...

, a cyclic polyol
Polyol
A polyol is an alcohol containing multiple hydroxyl groups. In two technological disciplines the term "polyol" has a special meaning: food science and polymer chemistry.- Polyols in food science :...

. It is a known anti-diabetic agent isolated from Sutherlandia frutescens
Sutherlandia frutescens
Sutherlandia frutescens is a southern African legume shrub with bitter, aromatic leaves. Red-orange flowers appear in spring.-External links:*...

leaves. Gall
Gall
Galls or cecidia are outgrowths on the surface of lifeforms caused by invasion by other lifeforms, such as parasites or bacterial infection. Plant galls are abnormal outgrowths of plant tissues and can be caused by various parasites, from fungi and bacteria, to insects and mites...

 plant tannins can be differentiated by their content of pinitol.

Certain variants of the bacteria Pseudomonas putida
Pseudomonas putida
Pseudomonas putida is a gram-negative rod-shaped saprotrophic soil bacterium. Based on 16S rRNA analysis, P. putida has been placed in the P. putida group, to which it lends its name....

have been used in organic synthesis
Organic synthesis
Organic synthesis is a special branch of chemical synthesis and is concerned with the construction of organic compounds via organic reactions. Organic molecules can often contain a higher level of complexity compared to purely inorganic compounds, so the synthesis of organic compounds has...

, the first example being the oxidation of benzene
Benzene
Benzene is an organic chemical compound. It is composed of 6 carbon atoms in a ring, with 1 hydrogen atom attached to each carbon atom, with the molecular formula C6H6....

, employed by Prof. S. V. Ley in the synthesis of (+/-)pinitol.

Glycosides

Ciceritol
Ciceritol
Ciceritol is a cyclitol. It is a pinitol digalactoside that can be isolated from seeds of chickpea, lentil and white lupin....

 is a pinitol digalactoside that can be isolated form seeds of chickpea
Chickpea
The chickpea is a legume of the family Fabaceae, subfamily Faboideae...

, lentil
Lentil
The lentil is an edible pulse. It is a bushy annual plant of the legume family, grown for its lens-shaped seeds...

 and white lupin.

A cyclitol derivative can be found in the marine sponge Petrosia sp.
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