Linarite
Encyclopedia
Linarite is a somewhat rare, crystalline mineral that is known among mineral collectors for its unusually intense, pure blue color. It is formed by the oxidation of galena
Galena
Galena is the natural mineral form of lead sulfide. It is the most important lead ore mineral.Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms...

 and chalcopyrite
Chalcopyrite
Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite...

 and other copper sulfides. It is a combined copper
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...

 lead
Lead
Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...

 sulfate
Sulfate
In inorganic chemistry, a sulfate is a salt of sulfuric acid.-Chemical properties:...

 hydroxide
Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and a hydrogen atom held together by a covalent bond, and carrying a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, as a ligand, a nucleophile, and a...

 with formula PbCuSO4(OH)2.
Linarite occurs as monoclinic prismatic to tabular crystals and irregular masses. It is easily confused with azurite
Azurite
Azurite is a soft, deep blue copper mineral produced by weathering of copper ore deposits. It is also known as Chessylite after the type locality at Chessy-les-Mines near Lyon, France...

, but does not react with dilute hydrochloric acid
Hydrochloric acid
Hydrochloric acid is a solution of hydrogen chloride in water, that is a highly corrosive, strong mineral acid with many industrial uses. It is found naturally in gastric acid....

 as azurite does. It has a Mohs hardness of 2.5 and a specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 of 5.3 - 5.5.

Linarite was first identified in 1822. It is named after the Linares Plateau, Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...

. It occurs in association with brochantite
Brochantite
Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is CuSO4·3Cu2. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it is named for its discoverer, the French geologist and mineralogist, A. J. M...

, anglesite
Anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and...

, caledonite
Caledonite
Caledonite, whose name derives from Caledonia, the historical name of its place of discovery , is a richly colored blue-green sulfate-carbonate mineral of lead and copper with an orthorhombic crystal structure. It is an uncommon mineral found in the oxidized zones of copper-lead...

, leadhillite
Leadhillite
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO422.Leadhillite crystallizes in the monoclinic system, but forms pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably colored adamantine crystals...

, cerussite
Cerussite
Cerussite is a mineral consisting of lead carbonate , and an important ore of lead. The name is from the Latin cerussa, white lead. Cerussa nativa was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name cruse to the mineral, whilst the present form, cerussite, is due to...

, malachite
Malachite
Malachite is a copper carbonate mineral, with the formula Cu2CO32. This green-colored mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses. Individual crystals are rare but do occur as slender to acicular prisms...

 and hemimorphite
Hemimorphite
Hemimorphite, is a sorosilicate mineral which has been mined from days of old from the upper parts of zinc and lead ores, chiefly associated with smithsonite. It was often assumed to be the same mineral and both were classed under the same name of calamine...

.
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