Hans Bock (chemist)
Encyclopedia
Hans Bock was a German chemist born in Hamburg
Hamburg
-History:The first historic name for the city was, according to Claudius Ptolemy's reports, Treva.But the city takes its modern name, Hamburg, from the first permanent building on the site, a castle whose construction was ordered by the Emperor Charlemagne in AD 808...

 and died in Königstein im Taunus
Königstein im Taunus
Königstein im Taunus is a climatic spa and lies on the thickly wooded slopes of the Taunus in Hesse, Germany. Owing to its advantageous location for both scenery and transport on the edge of the Frankfurt Rhine Main Region, Königstein is a favourite residential town...

.

Career

Hans Bock studied chemistry at the University of Munich, where he received his PhD in 1958 for his work on water-free hydrazine
Hydrazine
Hydrazine is an inorganic compound with the formula N2H4. It is a colourless flammable liquid with an ammonia-like odor. Hydrazine is highly toxic and dangerously unstable unless handled in solution. Approximately 260,000 tons are manufactured annually...

 in the group of Egon Wiberg. In 1964 he received his post doctoral lecture qualification after work on phosphorus
Phosphorus
Phosphorus is the chemical element that has the symbol P and atomic number 15. A multivalent nonmetal of the nitrogen group, phosphorus as a mineral is almost always present in its maximally oxidized state, as inorganic phosphate rocks...

 containing diacenes
Diazene
Diazene, also called diimine or diimide, is a compound having the formula 2. It exists as two geometric isomers, E and Z. Diazene is also the parent member of the entire class of azo compounds with the formula 2, where R is an organyl group...

 in the same research group. Subsequentely he had a three-years visit in the group of Edgar Heilbronner
Edgar Heilbronner
Edgar Heilbronner was a Swiss German chemist. In 1964 he published the concept of Möbius cyclic annulenes, but the first Möbius aromatic was not synthesized until 2003....

 at ETH Zurich
ETH Zurich
The Swiss Federal Institute of Technology Zurich or ETH Zürich is an engineering, science, technology, mathematics and management university in the City of Zurich, Switzerland....

/Switzerland, where he worked on applications of the HMO-model
Hückel method
The Hückel method or Hückel molecular orbital method proposed by Erich Hückel in 1930, is a very simple linear combination of atomic orbitals molecular orbitals method for the determination of energies of molecular orbitals of pi electrons in conjugated hydrocarbon systems, such as ethene,...

, leading to the textbook: The HMO model and its application.

In 1968 he was announced full professor for inorganic chemistry at the University of Frankfurt.

Research

He is the author and co-author of more than 500 publications in peer-reviewed journals.
He focussed on preparation of element-organic compounds and their characterisation by appropiate physical measurement methodes. Main focus was set on development and application of X-ray photoelectron spectroscopy
X-ray photoelectron spectroscopy
X-ray photoelectron spectroscopy is a quantitative spectroscopic technique that measures the elemental composition, empirical formula, chemical state and electronic state of the elements that exist within a material...

 (XPS) for detection and characterisation of transient molecules.

He proposed the use of the super silyl group in 1993.

Literature

  • The HMO model and its application by Edgar Heilbronner and Hans Bock, translated by W.Martin and A.J.Rackstraw

Recognition

He was external member of Max-Planck-Gesellschaft and became adjunct professor at University of Michigan
University of Michigan
The University of Michigan is a public research university located in Ann Arbor, Michigan in the United States. It is the state's oldest university and the flagship campus of the University of Michigan...

 (Ann Arbor) and TU München. He received two honorary doctorates by universities of Hamburg and Montpellier/France.

In 1987 he received the Wilhelm-Klemm-Award by the Gesellschaft Deutscher Chemiker
Gesellschaft Deutscher Chemiker
The Gesellschaft Deutscher Chemiker is a learned society and professional association founded in 1949 to represent the interests of German chemists in local, national and international contexts...

(GDCh).
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