A calcium-aluminium-rich inclusion or Ca-Al-rich Inclusion (CAI) is a submillimeter to centimeter-sized light-colored calcium

Calcium

Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

- and aluminium

Aluminium

Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

-rich inclusion

Inclusion (mineral)

In mineralogy, an inclusion is any material that is trapped inside a mineral during its formation.In gemology, an inclusion is a characteristic enclosed within a gemstone, or reaching its surface from the interior....

 found in carbonaceous chondrite

Carbonaceous chondrite

Carbonaceous chondrites or C chondrites are a class of chondritic meteorites comprising at least 7 known groups and many ungrouped meteorites. They include some of the most primitive known meteorites...

 meteorite

Meteorite

A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

s. They are among the oldest substances in the solar system, forming approximately 4567 to 4571 Ma.

Description

CAIs consist of mineral

Mineral

A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

s that are among the first solid

Solid

Solid is one of the three classical states of matter . It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a...

s condensed from the cooling protoplanetary disk

Protoplanetary disk

A protoplanetary disk is a rotating circumstellar disk of dense gas surrounding a young newly formed star, a T Tauri star, or Herbig Ae/Be star...

. The most common and characteristic minerals in CAIs include anorthite

Anorthite

Anorthite is the calcium endmember of plagioclase feldspar. Plagioclase is an abundant mineral in the Earth's crust. The formula of pure anorthite is CaAl2Si2O8.-Mineralogy :...

, melilite

Melilite

Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is 2[SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish brown color...

, perovskite

Perovskite

A perovskite structure is any material with the same type of crystal structure as calcium titanium oxide , known as the perovskite structure, or XIIA2+VIB4+X2−3 with the oxygen in the face centers. Perovskites take their name from this compound, which was first discovered in the Ural mountains of...

, aluminous spinel

Spinel

Spinel is the magnesium aluminium member of the larger spinel group of minerals. It has the formula MgAl2O4. Balas ruby is an old name for a rose-tinted variety.-Spinel group:...

, hibonite

Hibonite

Hibonite is a brownish black mineral with a hardness of 7.5-8.0 and a hexagonal crystal structure. It is rare, but is found in high-grade metamorphic rocks on Madagascar. Some presolar grains in primitive meteorites consist of hibonite. Hibonite also is a common mineral in the Ca-Al-rich...

, calcic pyroxene

Pyroxene

The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. They share a common structure consisting of single chains of silica tetrahedra and they crystallize in the monoclinic and orthorhombic systems...

, and forsterite

Forsterite

Forsterite is the magnesium rich end-member of the olivine solid solution series. Forsterite crystallizes in the orthorhombic system with cell parameters a 4.75 Å , b 10.20 Å and c 5.98 Å .Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites...

-rich olivine

Olivine

The mineral olivine is a magnesium iron silicate with the formula 2SiO4. It is a common mineral in the Earth's subsurface but weathers quickly on the surface....

. CAIs were formed at much higher temperature

Temperature

Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

s than the associated chondrule

Chondrule

Chondrules are round grains found in chondrites. Chondrules form as molten or partially molten droplets in space before being accreted to their parent asteroids...

s, and may have survived many high-temperature events, whereas most chondrules are the product of a single transient melting event.

The isotopic

Isotope

Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...

 anomalies of CAIs give valuable clues about the solar system

Solar System

The Solar System consists of the Sun and the astronomical objects gravitationally bound in orbit around it, all of which formed from the collapse of a giant molecular cloud approximately 4.6 billion years ago. The vast majority of the system's mass is in the Sun...

's formation, suggesting that the solar nebula

Solar nebula

In cosmogony, the nebular hypothesis is the most widely accepted model explaining the formation and evolution of the Solar System. There is evidence that it was first proposed in 1734 by Emanuel Swedenborg. Originally applied only to our own Solar System, this method of planetary system formation...

 collapsed shortly after a nearby supernova

Supernova

A supernova is a stellar explosion that is more energetic than a nova. It is pronounced with the plural supernovae or supernovas. Supernovae are extremely luminous and cause a burst of radiation that often briefly outshines an entire galaxy, before fading from view over several weeks or months...

; radiometric dating

Radiometric dating

Radiometric dating is a technique used to date materials such as rocks, usually based on a comparison between the observed abundance of a naturally occurring radioactive isotope and its decay products, using known decay rates...

 shows that the CAIs formed about 2 million years before the chondrules formed.

Using lead

Lead

Lead is a main-group element in the carbon group with the symbol Pb and atomic number 82. Lead is a soft, malleable poor metal. It is also counted as one of the heavy metals. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed...

 isotopic data determined on CAIs, an age of 4567.2±0.6 million years can be calculated which can be interpreted as the beginning of the formation of the planetary system. However, due to possible disturbances of the lead isotopic system within the CAIs, this age is possibly only a lower limit of the true age. Also an age of 4571 Ma for CAIs has been given, based on Mn

Manganese

Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...

–Cr

Chromium

Chromium is a chemical element which has the symbol Cr and atomic number 24. It is the first element in Group 6. It is a steely-gray, lustrous, hard metal that takes a high polish and has a high melting point. It is also odorless, tasteless, and malleable...

 and Mg

Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

–Al

Aluminium

Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

isotopic data.