In solid state physics, a band gap, also called an energy gap or bandgap, is an energy range in a solid

Solid

Solid is one of the three classical states of matter . It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a...

 where no electron

Electron

The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...

 states can exist. In graphs of the electronic band structure

Electronic band structure

In solid-state physics, the electronic band structure of a solid describes those ranges of energy an electron is "forbidden" or "allowed" to have. Band structure derives from the diffraction of the quantum mechanical electron waves in a periodic crystal lattice with a specific crystal system and...

 of solids, the band gap generally refers to the energy difference (in electron volts) between the top of the valence band

Valence band

In solids, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature....

 and the bottom of the conduction band

Conduction band

In the solid-state physics field of semiconductors and insulators, the conduction band is the range of electron energies, higher than that of the valence band, sufficient to free an electron from binding with its individual atom and allow it to move freely within the atomic lattice of the material...

 in insulator

Electrical insulation

thumb|250px|[[Coaxial Cable]] with dielectric insulator supporting a central coreThis article refers to electrical insulation. For insulation of heat, see Thermal insulation...

s and semiconductor

Semiconductor

A semiconductor is a material with electrical conductivity due to electron flow intermediate in magnitude between that of a conductor and an insulator. This means a conductivity roughly in the range of 103 to 10−8 siemens per centimeter...

s. This is equivalent to the energy required to free an outer shell electron

Valence electron

In chemistry, valence electrons are the electrons of an atom that can participate in the formation of chemical bonds with other atoms. Valence electrons are the "own" electrons, present in the free neutral atom, that combine with valence electrons of other atoms to form chemical bonds. In a single...

 from its orbit about the nucleus

Atomic nucleus

The nucleus is the very dense region consisting of protons and neutrons at the center of an atom. It was discovered in 1911, as a result of Ernest Rutherford's interpretation of the famous 1909 Rutherford experiment performed by Hans Geiger and Ernest Marsden, under the direction of Rutherford. The...

 to become a mobile charge carrier

Charge carrier

In physics, a charge carrier is a free particle carrying an electric charge, especially the particles that carry electric currents in electrical conductors. Examples are electrons and ions...

, able to move freely within the solid material.