Alexander Naumovich Frumkin
Encyclopedia
Alexander Naumovich Frumkin (Алекса́ндр Нау́мович Фру́мкин) (October 24, 1895 – May 27, 1976), Russia
Russia
Russia or , officially known as both Russia and the Russian Federation , is a country in northern Eurasia. It is a federal semi-presidential republic, comprising 83 federal subjects...

n/Soviet
Soviet Union
The Soviet Union , officially the Union of Soviet Socialist Republics , was a constitutionally socialist state that existed in Eurasia between 1922 and 1991....

 electrochemist
Electrochemistry
Electrochemistry is a branch of chemistry that studies chemical reactions which take place in a solution at the interface of an electron conductor and an ionic conductor , and which involve electron transfer between the electrode and the electrolyte or species in solution.If a chemical reaction is...

, member of the Russian Academy of Sciences
Russian Academy of Sciences
The Russian Academy of Sciences consists of the national academy of Russia and a network of scientific research institutes from across the Russian Federation as well as auxiliary scientific and social units like libraries, publishers and hospitals....

 since 1932, founder of the Russian Journal of Electrochemistry Elektrokhimiya and receiver of the Hero of Socialist Labor
Hero of Socialist Labor
Hero of Socialist Labour was an honorary title in the Soviet Union and other Warsaw Pact countries. It was the highest degree of distinction for exceptional achievements in national economy and culture...

 award. The Russian Academy of Sciences
Russian Academy of Sciences
The Russian Academy of Sciences consists of the national academy of Russia and a network of scientific research institutes from across the Russian Federation as well as auxiliary scientific and social units like libraries, publishers and hospitals....

' A.N. Frumkin Institute of Physical Chemistry and Electrochemistry is named after him.

Frumkin was born in Kishinev to a Jewish family; his father was an insurance salesman. His family moved to Odessa
Odessa
Odessa or Odesa is the administrative center of the Odessa Oblast located in southern Ukraine. The city is a major seaport located on the northwest shore of the Black Sea and the fourth largest city in Ukraine with a population of 1,029,000 .The predecessor of Odessa, a small Tatar settlement,...

, where he received his primary schooling; he continued his education in Strasbourg, and then at the University of Bern. Frumkin's first published articles appeared in 1914, when he was only 19; in 1915, he received his first degree, back in Odessa. Two years later, the seminal article "Electrocapillary Phenomena and Electrode Potentials" was published.

Frumkin moved to Moscow in 1922 to work at the Karpov Institute, under A.N. Bakh. In 1930 Frumkin joined the faculty of Moscow University, where in 1933 he founded—and would head until his death—the department of electrochemistry.

Frumkin's most fundamental achievement was the fundamental theory of electrode
Electrode
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit...

 reaction
Chemical reaction
A chemical reaction is a process that leads to the transformation of one set of chemical substances to another. Chemical reactions can be either spontaneous, requiring no input of energy, or non-spontaneous, typically following the input of some type of energy, such as heat, light or electricity...

s, which describes the influence of the structure of the interface between electrode and solution on the rate of electron transfer
Electron transfer
Electron transfer is the process by which an electron moves from an atom or a chemical species to another atom or chemical species...

. This theory has been confirmed and extended within the framework of contemporary physical electron transfer models. Frumkin introduced the concept of the zero charge potential, the most important characteristic of a metal surface. Alessandro Volta
Alessandro Volta
Count Alessandro Giuseppe Antonio Anastasio Gerolamo Umberto Volta was a Lombard physicist known especially for the invention of the battery in 1800.-Early life and works:...

's question—a topic of discussion for over 120 years—about the nature of the EMF of electrochemical circuits was resolved using Frumkin's approach. Frumkin developed the Frumkin isotherm, an extension of the Langmuir isotherm in describing certain adsorption
Adsorption
Adsorption is the adhesion of atoms, ions, biomolecules or molecules of gas, liquid, or dissolved solids to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. It differs from absorption, in which a fluid permeates or is dissolved by a liquid or solid...

 phenomena. Frumkin's students developed novel experimental methods that would, in time, become standard. Several applied electrochemical processes, including ones related to chemical sources of electrical power, industrial electrolysis
Electrolysis
In chemistry and manufacturing, electrolysis is a method of using a direct electric current to drive an otherwise non-spontaneous chemical reaction...

, and anti-corrosion
Corrosion
Corrosion is the disintegration of an engineered material into its constituent atoms due to chemical reactions with its surroundings. In the most common use of the word, this means electrochemical oxidation of metals in reaction with an oxidant such as oxygen...

 protection, were successfully developed under Frumkin's supervision.

Frumkin was married three times, including a brief first marriage to Vera Inber
Vera Inber
Vera Mikhailovna Inber, born Shpenzer, was a Russian-Soviet poet and writer.-Biography:...

.

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