Super iron battery
Encyclopedia
The Super-iron battery is a new class of rechargeable electric battery
.
"Super-iron" is a moniker for a special kind of ferrate
salt (iron(VI)). Potassium ferrate
or barium ferrate
, used in this new class of batteries.
chemist Stuart Licht of the University of Massachusetts
was leading research into a Super-iron battery.
Use of ferrate cathodes was tested and patented by Amendola as well as other patents.
It uses the same zinc
anode
and electrolyte
as an alkaline battery
, but its capacity is around 50% higher.
is nontoxic, preferable over mercury
, cadmium
, manganese
and nickel oxide
s.
Battery (electricity)
An electrical battery is one or more electrochemical cells that convert stored chemical energy into electrical energy. Since the invention of the first battery in 1800 by Alessandro Volta and especially since the technically improved Daniell cell in 1836, batteries have become a common power...
.
"Super-iron" is a moniker for a special kind of ferrate
Ferrate
In chemistry, ferrate refers either to the anion , in which iron is in the +6 oxidation state, or to a salt containing this anion. The term ferrate is often used to mean ferrate, although according to IUPAC naming conventions, it may also refer to other iron-containing oxyanions, such as ferrate...
salt (iron(VI)). Potassium ferrate
Potassium ferrate
Potassium ferrate is the chemical compound with the formula K2FeO4. This purple salt is paramagnetic, and is a rare example of an iron compound. In most of its compounds, iron has the oxidation state +2 or +3...
or barium ferrate
Barium ferrate
Barium ferrate is the chemical compound of formula BaFeO4. This compound contains iron in the +6 oxidation state. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.-Preparation and chemistry:...
, used in this new class of batteries.
chemist Stuart Licht of the University of Massachusetts
University of Massachusetts
This article relates to the statewide university system. For the flagship campus often referred to as "UMass", see University of Massachusetts Amherst...
was leading research into a Super-iron battery.
Use of ferrate cathodes was tested and patented by Amendola as well as other patents.
- "...the new cathodeCathodeA cathode is an electrode through which electric current flows out of a polarized electrical device. Mnemonic: CCD .Cathode polarity is not always negative...
employs salts of an unusual ionic form of ironIronIron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
— hexavalent or superoxidized iron—that readily accept three electrons per ion, Licht explains. The more electrons the cathodeCathodeA cathode is an electrode through which electric current flows out of a polarized electrical device. Mnemonic: CCD .Cathode polarity is not always negative...
can accept, the more electricity the battery can supply." —Peter Weiss
It uses the same zinc
Zinc
Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...
anode
Anode
An anode is an electrode through which electric current flows into a polarized electrical device. Mnemonic: ACID ....
and electrolyte
Electrolyte
In chemistry, an electrolyte is any substance containing free ions that make the substance electrically conductive. The most typical electrolyte is an ionic solution, but molten electrolytes and solid electrolytes are also possible....
as an alkaline battery
Alkaline battery
Alkaline batteries are a type of primary batteries dependent upon the reaction between zinc and manganese dioxide . A rechargeable alkaline battery allows reuse of specially designed cells....
, but its capacity is around 50% higher.
Environment
Iron rustRust
Rust is a general term for a series of iron oxides. In colloquial usage, the term is applied to red oxides, formed by the reaction of iron and oxygen in the presence of water or air moisture...
is nontoxic, preferable over mercury
Mercury (element)
Mercury is a chemical element with the symbol Hg and atomic number 80. It is also known as quicksilver or hydrargyrum...
, cadmium
Cadmium
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, bluish-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Similar to zinc, it prefers oxidation state +2 in most of its compounds and similar to mercury it shows a low...
, manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...
and nickel oxide
Nickel oxide
Nickel oxide may refer to:* Nickel oxide, NiO, green, well-characterised oxide* Nickel oxide, Ni2O3, black, not well-characterised oxide...
s.
See also
- Lithium-ion battery
- NanotechnologyNanotechnologyNanotechnology is the study of manipulating matter on an atomic and molecular scale. Generally, nanotechnology deals with developing materials, devices, or other structures possessing at least one dimension sized from 1 to 100 nanometres...
- Nickel-cadmium batteryNickel-cadmium batteryThe nickel–cadmium battery ' is a type of rechargeable battery using nickel oxide hydroxide and metallic cadmium as electrodes....
- Nickel metal hydride batteryNickel metal hydride batteryA nickel–metal hydride cell, abbreviated NiMH, is a type of rechargeable battery similar to the nickel–cadmium cell. The NiMH battery uses a hydrogen-absorbing alloy for the negative electrode instead of cadmium. As in NiCd cells, the positive electrode is nickel oxyhydroxide...
Further reading
- Super Battery.
- Licht, S., and R. Tel-Vered. rechargeable Fe(III/VI) super-iron cathodes, Chemical Communications, vol. 6, p. 628-629, 10 March 2004
- Battery Bimonthly, http://translate.google.com/translate?hl=en&sl=zh-CN&u=http://www.wanfangdata.com.cn/qikan/periodical.Articles/dc/dc2004/0404/040405.htm&sa=X&oi=translate&resnum=5&ct=result&prev=/search%3Fq%3D%2522Battery%2BBimonthly%2522%2B%2522super-iron%2522%26hl%3Den%26lr%3D%26safe%3Doff%26client%3Dsafari%26rls%3Den%26sa%3DGNano-class performance research iron folate-iron batteries - Study on the performance of nano-sized ferrates super-iron battery], Vol.34 No. P.247-249. 2004
- Energetic Iron(VI) Chemistry: The Super-Iron Battery, Science, Volume 285, p. 1039, 13 August 1999.
- "Super-Iron" Comes to the Rescue of Batteries, Science, Volume 285, p. 995, 13 August 1999.
- Florida Institute of TechnologyFlorida Institute of TechnologyFlorida Institute of Technology, also known as Florida Tech, is an independent private technical research university located in Melbourne, Florida, United States. Founded in 1958 as Brevard Engineering College, the institute has been known by its present name since 1966. Florida Tech's curriculum...
website - research - news - vol. 1 iss. 2b - The originator of "Super-iron"