Sacrificial metal
Encyclopedia
A sacrificial metal is a metal used as a sacrificial anode in cathodic protection
Cathodic protection
Cathodic protection is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. The simplest method to apply CP is by connecting the metal to be protected with another more easily corroded "sacrificial metal" to act as the anode of the...

 that corrodes to prevent a primary metal from corrosion, galvanization or rust
Rust
Rust is a general term for a series of iron oxides. In colloquial usage, the term is applied to red oxides, formed by the reaction of iron and oxygen in the presence of water or air moisture...

ing.

Equation

When two metals touch each other and water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 is present, electrolysis
Electrolysis
In chemistry and manufacturing, electrolysis is a method of using a direct electric current to drive an otherwise non-spontaneous chemical reaction...

 occurs. One well known example is the reaction between zinc
Zinc
Zinc , or spelter , is a metallic chemical element; it has the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. Zinc is, in some respects, chemically similar to magnesium, because its ion is of similar size and its only common oxidation state is +2...

 (Zn) and iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 (Fe). Zn atom
Atom
The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons...

s ionize
Ionization
Ionization is the process of converting an atom or molecule into an ion by adding or removing charged particles such as electrons or other ions. This is often confused with dissociation. A substance may dissociate without necessarily producing ions. As an example, the molecules of table sugar...

 as it is more electropositive and is oxidized
Redox
Redox reactions describe all chemical reactions in which atoms have their oxidation state changed....

 and corrodes.

Zn(s)→(aq) +2e (oxidation)

Uses

Sacrificial metals are widely used to prevent other metals from rusting, for example food cans. Most of the food can is coated with a layer of metal that is more electropositive than the metal (mostly iron) inside the food can, preventing the iron contaminating the food with ion
Ion
An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. The name was given by physicist Michael Faraday for the substances that allow a current to pass between electrodes in a...

s.
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