Niobium-tin
Encyclopedia
Niobium-tin or triniobium-tin is a metal
Metal
A metal , is an element, compound, or alloy that is a good conductor of both electricity and heat. Metals are usually malleable and shiny, that is they reflect most of incident light...

lic chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 of niobium
Niobium
Niobium or columbium , is a chemical element with the symbol Nb and atomic number 41. It's a soft, grey, ductile transition metal, which is often found in the pyrochlore mineral, the main commercial source for niobium, and columbite...

 (Nb) and tin
Tin
Tin is a chemical element with the symbol Sn and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows chemical similarity to both neighboring group 14 elements, germanium and lead and has two possible oxidation states, +2 and the slightly more stable +4...

 (Sn), used industrially as a type II superconductor
Superconductivity
Superconductivity is a phenomenon of exactly zero electrical resistance occurring in certain materials below a characteristic temperature. It was discovered by Heike Kamerlingh Onnes on April 8, 1911 in Leiden. Like ferromagnetism and atomic spectral lines, superconductivity is a quantum...

. This intermetallic compound
is a A15 phases
A15 phases
The A15 phases are series of intermetallic compounds with the chemical formula A3B and a specific structure...

 superconductor. It is more expensive than niobium-titanium
Niobium-titanium
Niobium-titanium is an alloy of niobium and titanium, used industrially as a type II superconductor wire for superconducting magnets...

 (NbTi), but can withstand magnetic field intensity
Field strength
In physics, the field strength of a field is the magnitude of its vector value.In theoretical physics, field strength is another name for the curvature form...

 values up to 30 teslas (T)
Tesla (unit)
The tesla is the SI derived unit of magnetic field B . One tesla is equal to one weber per square meter, and it was defined in 1960 in honour of the inventor, physicist, and electrical engineer Nikola Tesla...

, whereas NbTi can withstand only up to roughly 15 T.

Nb3Sn was discovered to be a superconductor in 1954.

Its critical temperature is 18.3 kelvin
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...

s (K). It is usually used at 4.2 K, the boiling point of liquid helium
Liquid helium
Helium exists in liquid form only at extremely low temperatures. The boiling point and critical point depend on the isotope of the helium; see the table below for values. The density of liquid helium-4 at its boiling point and 1 atmosphere is approximately 0.125 g/mL Helium-4 was first liquefied...

.

In April 2008 a record non-copper current density
Current density
Current density is a measure of the density of flow of a conserved charge. Usually the charge is the electric charge, in which case the associated current density is the electric current per unit area of cross section, but the term current density can also be applied to other conserved...

 was claimed of 2643 A/mm² at 12 T and 4.2 K

Practical use

Mechanically, Nb3Sn is extremely brittle
Brittle
A material is brittle if, when subjected to stress, it breaks without significant deformation . Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Breaking is often accompanied by a snapping sound. Brittle materials include most ceramics and glasses ...

 and thus can not be easily drawn into a wire, which is necessary for winding superconducting magnet
Superconducting magnet
A superconducting magnet is an electromagnet made from coils of superconducting wire. They must be cooled to cryogenic temperatures during operation. In its superconducting state the wire can conduct much larger electric currents than ordinary wire, creating intense magnetic fields...

s. To overcome this, wire manufacturers typically draw down composite wires containing ductile precursors. The "internal tin" process include separate alloys of Nb, Cu and Sn. The "bronze" process contains Nb in a copper
Copper
Copper is a chemical element with the symbol Cu and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is soft and malleable; an exposed surface has a reddish-orange tarnish...

-tin bronze
Bronze
Bronze is a metal alloy consisting primarily of copper, usually with tin as the main additive. It is hard and brittle, and it was particularly significant in antiquity, so much so that the Bronze Age was named after the metal...

 matrix. With both processes the strand is typically drawn to final size and coiled into a solenoid or cable before heat treatment. It is only during the heat treatment that the Sn reacts with the Nb to form the brittle, superconducting niobium-tin compound.

The powder-in-tube process is also used .

The high field section of modern NMR
NMR
NMR may refer to:Applications of Nuclear Magnetic Resonance:* Nuclear magnetic resonance* NMR spectroscopy* Solid-state nuclear magnetic resonance* Protein nuclear magnetic resonance spectroscopy* Proton NMR* Carbon-13 NMR...

 magnets are composed of niobium-tin wire.

Some niobium-tin wires can be wound after heat treatment.

History

Nb3Sn was discovered to be a superconductor in 1954, one year after the discovery of the first type of A3B superconductors V3Si. In 1961 it was discovered that niobium-tin still exhibits superconductivity at large currents and strong magnetic fields, thus becoming the first known material to support the high currents and fields necessary for making useful high-power magnets and electric power machinery.

Notable uses

The central solenoid
Solenoid
A solenoid is a coil wound into a tightly packed helix. In physics, the term solenoid refers to a long, thin loop of wire, often wrapped around a metallic core, which produces a magnetic field when an electric current is passed through it. Solenoids are important because they can create...

 and toroidal field superconducting magnet
Superconducting magnet
A superconducting magnet is an electromagnet made from coils of superconducting wire. They must be cooled to cryogenic temperatures during operation. In its superconducting state the wire can conduct much larger electric currents than ordinary wire, creating intense magnetic fields...

s for the ITER
ITER
ITER is an international nuclear fusion research and engineering project, which is currently building the world's largest and most advanced experimental tokamak nuclear fusion reactor at Cadarache in the south of France...

 fusion
Nuclear fusion
Nuclear fusion is the process by which two or more atomic nuclei join together, or "fuse", to form a single heavier nucleus. This is usually accompanied by the release or absorption of large quantities of energy...

 reactor use niobium-tin as a superconductor . The central solenoid coil will produce a field of 13.5 teslas. The toroidal field coils will operate at a maximum field of 11.8 T.

The International Thermonuclear Experimental Reactor is estimated to use 600 metric tonnes of Nb3Sn strands and 250 metric tonnes of NbTi
Niobium-titanium
Niobium-titanium is an alloy of niobium and titanium, used industrially as a type II superconductor wire for superconducting magnets...

strands..

The LHC upgrade will use superconducting magnets made of niobium-tin.
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