Nickel(II) bromide
Encyclopedia
Nickel bromide, NiBr2, is the nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

 salt
Salt
In chemistry, salts are ionic compounds that result from the neutralization reaction of an acid and a base. They are composed of cations and anions so that the product is electrically neutral...

 of hydrobromic acid
Hydrobromic acid
Hydrobromic acid is a strong acid formed by dissolving the diatomic molecule hydrogen bromide in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C and contains 47.6% HBr by weight, which is 8.89 mol/L. Hydrobromic acid has a pKa of −9, making it a...

. It can be made by reacting nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

, nickel(II) oxide
Nickel(II) oxide
Nickel oxide is the chemical compound with the formula NiO. It is notable as being the only well characterized oxide of nickel . The mineralogical form of NiO, bunsenite, is very rare. It is classified as a basic metal oxide...

, nickel(II) carbonate
Nickel(II) carbonate
Nickel carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, the most important nickel carbonate is basic nickel carbonate with the formula Ni4CO364. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO3...

, or nickel(II) hydroxide
Nickel(II) hydroxide
Nickel hydroxide Ni2 is an insoluble compound commonly used in rechargeable battery electrodes. When charged these electrodes form nickel oxide-hydroxide. Nickel hydroxide is a precipitate formed when the hexaaquanickel ion is mixed with aqueous alkali...

 with hydrobromic acid. It can also be made by reacting nickel with bromine
Bromine
Bromine ") is a chemical element with the symbol Br, an atomic number of 35, and an atomic mass of 79.904. It is in the halogen element group. The element was isolated independently by two chemists, Carl Jacob Löwig and Antoine Jerome Balard, in 1825–1826...

. It is a weak reducing agent
Reducing agent
A reducing agent is the element or compound in a reduction-oxidation reaction that donates an electron to another species; however, since the reducer loses an electron we say it is "oxidized"...

.

It is yellow-brown, rhombohedral, hygroscopic, and is soluble in water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 and in ethanol
Ethanol
Ethanol, also called ethyl alcohol, pure alcohol, grain alcohol, or drinking alcohol, is a volatile, flammable, colorless liquid. It is a psychoactive drug and one of the oldest recreational drugs. Best known as the type of alcohol found in alcoholic beverages, it is also used in thermometers, as a...

. It dissolves in water to make a blue-green solution typical of soluble nickel(II) compounds. It can be used as a source of the bromide
Bromide
A bromide is a chemical compound containing bromide ion, that is bromine atom with effective charge of −1. The class name can include ionic compounds such as caesium bromide or covalent compounds such as sulfur dibromide.-Natural occurrence:...

 ion. It reacts with bases
Base (chemistry)
For the term in genetics, see base A base in chemistry is a substance that can accept hydrogen ions or more generally, donate electron pairs. A soluble base is referred to as an alkali if it contains and releases hydroxide ions quantitatively...

to make nickel(II) hydroxide.

Nickel(II) bromide, like most nickel compounds, is toxic and a suspected carcinogen. It can cause contact dermatitis in skin. The bromide ion is also mildly toxic.
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