Kermesite
Encyclopedia
Kermesite or antimony
Antimony
Antimony is a toxic chemical element with the symbol Sb and an atomic number of 51. A lustrous grey metalloid, it is found in nature mainly as the sulfide mineral stibnite...

 oxysulfide is also known as red antimony (Sb2S2O) . The mineral’s color ranges from cherry red to a dark red to a black. Kermesite is the result of partial oxidation between stibnite
Stibnite
Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony...

 (Sb2S3) and other antimony oxides such as valentinite
Valentinite
Valentinite is an antimony oxide mineral with formula Sb2O3. Valentinite crystallizes in the orthorhombic system and typically forms as radiating clusters of euhedral crystals or as fibrous masses. It is colorless to white with occasional shades or tints of yellow and red. It has a Mohs hardness of...

 (Sb2O3) or stibiconite
Stibiconite
Stibiconite is an antimony oxide mineral with formula: Sb3O6. Its name originates from Greek "stibi" and "konis" , alluding to its composition and habit...

 (Sb3O6(OH)). Under certain conditions with oxygenated fluids the transformation of all sulfur to oxygen would occur but kermesite occurs when that transformation is halted.

Mining and specimens

Deposits of this mineral have been found all over the world, however notable deposits have been found in Braunsdorf, near Freiberg
Freiberg, Saxony
Freiberg is a city in the Free State of Saxony, Germany, administrative center of the Mittelsachsen district.-History:The city was founded in 1186, and has been a center of the mining industry in the Ore Mountains for centuries...

, Saxony
Saxony
The Free State of Saxony is a landlocked state of Germany, contingent with Brandenburg, Saxony Anhalt, Thuringia, Bavaria, the Czech Republic and Poland. It is the tenth-largest German state in area, with of Germany's sixteen states....

, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...

; Pernek, Pezinok, and Pribram, Czechoslovakia
Czechoslovakia
Czechoslovakia or Czecho-Slovakia was a sovereign state in Central Europe which existed from October 1918, when it declared its independence from the Austro-Hungarian Empire, until 1992...

; the Lac Nicolet mine, South Ham Township, Wolfe County, Quebec
Quebec
Quebec or is a province in east-central Canada. It is the only Canadian province with a predominantly French-speaking population and the only one whose sole official language is French at the provincial level....

, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...

; Sombrerete, Zacatecas
Zacatecas
Zacatecas officially Estado Libre y Soberano de Zacatecas is one of the 31 states which, with the Federal District, comprise the 32 Federal Entities of Mexico. It is divided in 58 municipalities and its capital city is Zacatecas....

, Mexico
Mexico
The United Mexican States , commonly known as Mexico , is a federal constitutional republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of...

; Santa Cruz and San Francisco mines, Poopo, Oruro, Bolivia
Bolivia
Bolivia officially known as Plurinational State of Bolivia , is a landlocked country in central South America. It is the poorest country in South America...

; Que Que, Zimbabwe
Zimbabwe
Zimbabwe is a landlocked country located in the southern part of the African continent, between the Zambezi and Limpopo rivers. It is bordered by South Africa to the south, Botswana to the southwest, Zambia and a tip of Namibia to the northwest and Mozambique to the east. Zimbabwe has three...

; Djebel Haminate, Algeria
Algeria
Algeria , officially the People's Democratic Republic of Algeria , also formally referred to as the Democratic and Popular Republic of Algeria, is a country in the Maghreb region of Northwest Africa with Algiers as its capital.In terms of land area, it is the largest country in Africa and the Arab...

; Broken Hill, New South Wales
New South Wales
New South Wales is a state of :Australia, located in the east of the country. It is bordered by Queensland, Victoria and South Australia to the north, south and west respectively. To the east, the state is bordered by the Tasman Sea, which forms part of the Pacific Ocean. New South Wales...

, Australia
Australia
Australia , officially the Commonwealth of Australia, is a country in the Southern Hemisphere comprising the mainland of the Australian continent, the island of Tasmania, and numerous smaller islands in the Indian and Pacific Oceans. It is the world's sixth-largest country by total area...

; Mohave, Kern County, California
Kern County, California
Spreading across the southern end of the California Central Valley, Kern County is the fifth-largest county by population in California. Its economy is heavily linked to agriculture and to petroleum extraction, and there is a strong aviation and space presence. Politically, it has generally...

 and Burke, Shoshone County, Idaho
Shoshone County, Idaho
Shoshone County is a county located in the U.S. state of Idaho. The county was established in 1864, named for the Native American Shoshone tribe. The population was 12,765 at the 2010 census. Shoshone County is commonly referred to as the Silver Valley, due to its century-old mining history...

.

History and uses

Kermesite is named after a formerly used red dye, kermes (dye)
Kermes (dye)
Kermes is a red dye derived from the dried bodies the females of a scale insect in the genus Kermes, primarily Kermes vermilio. The insects live on the sap of certain trees, especially Kermes oak tree near the Mediterranean region...

, and was so named because of the grainy reddish color the mineral often has. The name dates from 1832. Earlier in English (17th and 18th centuries) certain antimony compounds were called "kermes mineral" for the same reason.

Kermesite or red antimony has been used as early as the Old Kingdom
Old Kingdom
Old Kingdom is the name given to the period in the 3rd millennium BC when Egypt attained its first continuous peak of civilization in complexity and achievement – the first of three so-called "Kingdom" periods, which mark the high points of civilization in the lower Nile Valley .The term itself was...

’s 6th Dynasty in ancient Egypt
Egypt
Egypt , officially the Arab Republic of Egypt, Arabic: , is a country mainly in North Africa, with the Sinai Peninsula forming a land bridge in Southwest Asia. Egypt is thus a transcontinental country, and a major power in Africa, the Mediterranean Basin, the Middle East and the Muslim world...

 (c.2345-2181 BCE
Common Era
Common Era ,abbreviated as CE, is an alternative designation for the calendar era originally introduced by Dionysius Exiguus in the 6th century, traditionally identified with Anno Domini .Dates before the year 1 CE are indicated by the usage of BCE, short for Before the Common Era Common Era...

) in lip cosmetics and in the 18th Dynasty Queen Hatshepsut (Maatkare) (1498-1483 BCE) negotiated with the Land of Punt
Land of Punt
The Land of Punt, also called Pwenet, or Pwene by the ancient Egyptians, was a trading partner known for producing and exporting gold, aromatic resins, African blackwood, ebony, ivory, slaves and wild animals...

 for it s colored antimony deposits. Besides stibnite
Stibnite
Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony...

 which was used for eye liner red, antimony is one of the oldest minerals used in cosmetics. Further archaeological evidence indicates that antimony
Antimony
Antimony is a toxic chemical element with the symbol Sb and an atomic number of 51. A lustrous grey metalloid, it is found in nature mainly as the sulfide mineral stibnite...

 levels were higher in ancient Egypt
Egypt
Egypt , officially the Arab Republic of Egypt, Arabic: , is a country mainly in North Africa, with the Sinai Peninsula forming a land bridge in Southwest Asia. Egypt is thus a transcontinental country, and a major power in Africa, the Mediterranean Basin, the Middle East and the Muslim world...

ian female remains which had exposure to both antimony compounds (Bencze, 1994). Because of its color, the precipitate of kermesite was used as a coloring agent and in alchemy
Alchemy
Alchemy is an influential philosophical tradition whose early practitioners’ claims to profound powers were known from antiquity. The defining objectives of alchemy are varied; these include the creation of the fabled philosopher's stone possessing powers including the capability of turning base...

. Because of alchemy’s focus on material transformation as evidenced by color, red antimony was used to produce the red state. Kermesite is the mineral state for Kermes mineral
Kermes mineral
Kermes mineral or Alkermes mineral was a compound of antimony oxides and sulfides, more specifically, antimony trioxide and trisulfide. It can be made or obtained in the laboratory by the actions of potassium carbonate on antimony sulfide. The compound is reddish brown in color and described as...

which was used extensively in the medical field for centuries

Presently, kermesite is collected for the beauty of its crystal metallic structure and not used in either cosmetics or the medical field any longer due to the toxic effects that it shares with antimony; less harmful substitutes have been found using both organic and pharamceutical production.

External links

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