Isotope electrochemistry
Encyclopedia
Isotope electrochemistry is a field within electrochemistry
concerned with various topics like electrochemical separation of isotopes, electrochemical estimation of isotopic exchange equilibrium constants , electrochemical kinetic isotope effect
, electrochemical isotope
sensors, etc.
It is an active domain of investigation. It overlaps with many other domains of both theoretical and practical importance like nuclear engineering
, electrochemical technology, geochemistry, sensors and instrumentation.
Electrochemistry
Electrochemistry is a branch of chemistry that studies chemical reactions which take place in a solution at the interface of an electron conductor and an ionic conductor , and which involve electron transfer between the electrode and the electrolyte or species in solution.If a chemical reaction is...
concerned with various topics like electrochemical separation of isotopes, electrochemical estimation of isotopic exchange equilibrium constants , electrochemical kinetic isotope effect
Kinetic isotope effect
The kinetic isotope effect is the ratio of reaction rates of two different isotopically labeled molecules in a chemical reaction. It is also called "isotope fractionation," although this term is somewhat broader in meaning...
, electrochemical isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...
sensors, etc.
It is an active domain of investigation. It overlaps with many other domains of both theoretical and practical importance like nuclear engineering
Nuclear engineering
Nuclear engineering is the branch of engineering concerned with the application of the breakdown as well as the fusion of atomic nuclei and/or the application of other sub-atomic physics, based on the principles of nuclear physics...
, electrochemical technology, geochemistry, sensors and instrumentation.
See also
- Equilibrium fractionationEquilibrium fractionationEquilibrium isotope fractionation is the partial separation of isotopes between two or more substances in chemical equilibrium. Equilibrium fractionation is strongest at low temperatures, and forms the basis of the most widely used isotopic paleothermometers : D/H and 18O/16O records from ice...
- Bioelectrochemical reactorBioelectrochemical reactorBioelectrochemical reactors are a type of bioreactor where bioelectrochemical processes can take place. They are used in bioelectrochemical syntheses, environmental remediation and electrochemical energy conversion...
- Electrochemical cellElectrochemical cellAn electrochemical cell is a device capable of either deriving electrical energy from chemical reactions, or facilitating chemical reactions through the introduction of electrical energy. A common example of an electrochemical cell is a standard 1.5-volt "battery"...
- Electrochemical engineeringElectrochemical engineeringElectrochemical engineering is the branch of engineering dealing with the technological applications of electrochemical phenomena...
- Transient kinetic isotope fractionationTransient kinetic isotope fractionationTransient kinetic isotope effects occur when the reaction leading to isotope fractionation does not follow pure first-order kinetics and therefore isotopic effects cannot be described with the classical equilibrium fractionation equations or with steady-state kinetic fractionation equations...
External links
- electrochemical investigation using isotopic effects
- http://hydrobor.com.tr/bilgi-bankasi/.../Ti%20Ni%20intermetallic%20phases.pdf
- http://docs.google.com/viewer?a=v&q=cache:nlHspSbjz00J:hydrobor.com.tr/bilgi-bankasi/depo/Hidrojenin%2520Sudan%2520Elektroliz/Ti%2520Ni%2520intermetallic%2520phases.pdf+isotope+electrochemistry&hl=en&pid=bl&srcid=ADGEESj7bV-5mb7RubgmbUsVzwcbVqnkdlQv1vUlAFjS1lnz8Du6JrGzHez27WeTLc_kIT7yv-o8VfKpNAf8MeKkDpBnUdNKpR1-GISZA2oplpA4hpHbCPpGWmaKL7VeE4cpzSLWgnng&sig=AHIEtbSDruC14NdVyU7dukfw9qSiUOB34Aelectrochemical isotope separation]
- electrochemical isotope cell
- electroplating isotope effects
- JES electrochemical pumping isotope effects
- http://docs.google.com/viewer?a=v&q=cache:KmY3_wYaFbQJ:www.igpp.ucla.edu/people/jblack/Site/Home_files/The%2520Electrochemical%2520Isotope%2520Effect.pdf+isotope+electrochemistry&hl=en&pid=bl&srcid=ADGEEShyDfMcviTBqcrItse6rR_Xct3Kwg1kIRiucpvAci8OhQGtseYs4WqpXz7yPSTp9nGaectISpMJX2M9AczdOVRCB7SyNIIId_cgyIJAt3Lde-jyCJlaOrEh0s2K2uCOd3vPwfDs&sig=AHIEtbRCsiYfI9rTuMgE00CEm7OySR6oDwelectrochemical isotope fractionation]
- http://wwwsoc.nii.ac.jp/aesj/publication/JNST2002/No.4/39_367-370.pdf
- http://www.springerlink.com/content/u0x0t427w1146146/
- http://onlinelibrary.wiley.com/doi/10.1002/anie.196707571/abstract