Germanabenzene
Encyclopedia
Germabenzene is the parent representative of a group of chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

s containing in their molecular structure a benzene
Benzene
Benzene is an organic chemical compound. It is composed of 6 carbon atoms in a ring, with 1 hydrogen atom attached to each carbon atom, with the molecular formula C6H6....

 ring with a carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...

 atom replaced by a germanium
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....

 atom. Germabenzene itself has been studied theoretically, but has not been synthesized. However, stable naphthalene
Naphthalene
Naphthalene is an organic compound with formula . It is a white crystalline solid with a characteristic odor that is detectable at concentrations as low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings...

 derivatives do exist in the laboratory such as the 2-germanaphthalene-containing substance represented below. The germanium to carbon bond in this compound is shielded from potential reactants by a 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl or Tbt group. This compound is aromatic just as the other carbon group
Carbon group
The carbon group is a periodic table group consisting of carbon , silicon , germanium , tin , lead , and ununquadium ....

 representatives silabenzene
Silabenzene
A silabenzene is a heteroaromatic compound containing one or more silicon atoms instead of carbon atom in benzene. A single substitution gives silabenzene proper; additional substitutions give a disilabenzene , trisilabenzene , etc.Silabenzenes have been the targets of many theoretical and...

 and stannabenzene
Stannabenzene
Stannabenzene is the parent representative of a group of organotin compounds that are related to benzene with a carbon atom replaced by a tin atom. Stannabenzene itself has been studied by computational chemistry, but has not been isolated....

.

See also

  • Other 6-membered aromatic rings with one carbon replaced by another group: borabenzene
    Borabenzene
    A borabenzene is a heteroaromatic compound that has a boron atom instead of the carbon atom of a benzene molecule. A free borabenzene, which has no donor ligand on the boron atom, has not yet been isolated despite its simple structure and the chemical robustness of boron-carbon bonds...

    , benzene
    Benzene
    Benzene is an organic chemical compound. It is composed of 6 carbon atoms in a ring, with 1 hydrogen atom attached to each carbon atom, with the molecular formula C6H6....

    , silabenzene
    Silabenzene
    A silabenzene is a heteroaromatic compound containing one or more silicon atoms instead of carbon atom in benzene. A single substitution gives silabenzene proper; additional substitutions give a disilabenzene , trisilabenzene , etc.Silabenzenes have been the targets of many theoretical and...

    , stannabenzene
    Stannabenzene
    Stannabenzene is the parent representative of a group of organotin compounds that are related to benzene with a carbon atom replaced by a tin atom. Stannabenzene itself has been studied by computational chemistry, but has not been isolated....

    , pyridine
    Pyridine
    Pyridine is a basic heterocyclic organic compound with the chemical formula C5H5N. It is structurally related to benzene, with one C-H group replaced by a nitrogen atom...

    , phosphorine
    Phosphorine
    Phosphorine is a heavier element analog of pyridine, containing a phosphorus atom instead of an aza- moiety. It is also called phosphabenzene and belongs to the phosphaalkene class. Phosphorine is a planar aromatic compound with 88% of the aromaticity of that of benzene...

    , pyrylium salt
    Pyrylium salt
    A pyrylium salt is a salt containing a pyrylium cation or a derivative of it. The pyrylium cation is a conjugated 6-membered carbon ring system with one carbon atom replaced by a positively charged oxygen atom. It is, like benzene, an aromatic compound...

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