Dunite
Encyclopedia
Igneous rock
Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava...
, plutonic rock
Rock (geology)
In geology, rock or stone is a naturally occurring solid aggregate of minerals and/or mineraloids.The Earth's outer solid layer, the lithosphere, is made of rock. In general rocks are of three types, namely, igneous, sedimentary, and metamorphic...
, of ultramafic composition, with coarse-grained or phaneritic
Phaneritic
Phaneritic is a term usually used to refer to igneous rock grain size. It means that the size of matrix grains in the rock are large enough to be distinguished with the unaided eye as opposed to aphanitic . This texture forms by slow cooling of magma deep underground in the plutonic environment...
texture. The mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...
assemblage is greater than 90% olivine
Olivine
The mineral olivine is a magnesium iron silicate with the formula 2SiO4. It is a common mineral in the Earth's subsurface but weathers quickly on the surface....
, with minor amounts of other minerals such as pyroxene
Pyroxene
The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. They share a common structure consisting of single chains of silica tetrahedra and they crystallize in the monoclinic and orthorhombic systems...
, chromite
Chromite
Chromite is an iron chromium oxide: FeCr2O4. It is an oxide mineral belonging to the spinel group. Magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite ; substitution of aluminium occurs leading to hercynite .-Occurrence:Chromite is found in...
and pyrope
Pyrope
The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek for fire and eye. Despite being less common than most garnets, it is a...
. Dunite is the olivine-rich end-member of the peridotite
Peridotite
A peridotite is a dense, coarse-grained igneous rock, consisting mostly of the minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium, reflecting the high proportions of magnesium-rich olivine, with appreciable iron...
group of mantle-derived rocks. Dunite and other peridotite rocks are considered the major constituents of the Earth's mantle
Mantle (geology)
The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiation by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core....
above a depth of about 400 kilometers. Dunite is rarely found within continental rocks, but where it is found, it typically occurs at the base of ophiolite sequences where slabs of mantle rock from a subduction zone have been thrust onto continental crust
Continental crust
The continental crust is the layer of igneous, sedimentary, and metamorphic rocks which form the continents and the areas of shallow seabed close to their shores, known as continental shelves. This layer is sometimes called sial due to more felsic, or granitic, bulk composition, which lies in...
by obduction
Obduction
Obduction is the overthrusting of continental crust by oceanic crust or mantle rocks at a convergent plate boundary. It can occur during an orogeny, or mountain-building episode....
during continental or island arc
Island arc
An island arc is a type of archipelago composed of a chain of volcanoes which alignment is arc-shaped, and which are situated parallel and close to a boundary between two converging tectonic plates....
collisions (orogeny
Orogeny
Orogeny refers to forces and events leading to a severe structural deformation of the Earth's crust due to the engagement of tectonic plates. Response to such engagement results in the formation of long tracts of highly deformed rock called orogens or orogenic belts...
). It is also found in alpine peridotite massifs that represent slivers of sub-continental mantle exposed during collisional orogeny. Dunite typically undergoes retrograde metamorphism
Metamorphism
Metamorphism is the solid-state recrystallization of pre-existing rocks due to changes in physical and chemical conditions, primarily heat, pressure, and the introduction of chemically active fluids. Mineralogical, chemical and crystallographic changes can occur during this process...
in near-surface environments and is altered to serpentinite
Serpentinite
Serpentinite is a rock composed of one or more serpentine group minerals. Minerals in this group are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle...
and soapstone
Soapstone
Soapstone is a metamorphic rock, a talc-schist. It is largely composed of the mineral talc and is thus rich in magnesium. It is produced by dynamothermal metamorphism and metasomatism, which occurs in the areas where tectonic plates are subducted, changing rocks by heat and pressure, with influx...
.
Dunite may represent the refractory residue left after the extraction of basalt
Basalt
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey...
ic magma
Magma
Magma is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and is expected to exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and dissolved gas and sometimes also gas bubbles. Magma often collects in...
s in the upper mantle. This is the type of dunite found in the lowermost parts of ophiolites, alpine peridotite massifs, and xenolith
Xenolith
A xenolith is a rock fragment which becomes enveloped in a larger rock during the latter's development and hardening. In geology, the term xenolith is almost exclusively used to describe inclusions in igneous rock during magma emplacement and eruption...
s. Dunite may also form by the accumulation of olivine crystals on the floor of large basaltic or picritic magma chambers. These "cumulate
Cumulate rock
Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks.-Formation:Cumulate rocks are the...
" dunites typically occur in thick layers in layered intrusions, associated with cumulate layers of wehrlite, olivine pyroxenite
Pyroxenite
Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite and diopside, hypersthene, bronzite or enstatite. They are classified into clinopyroxenites, orthopyroxenites, and the websterites which contain both pyroxenes...
, harzburgite
Harzburgite
The ultramafic igneous rock, harzburgite, is a variety of peridotite consisting mostly of the two minerals, olivine and low-calcium pyroxene ; it is named for occurrences in the Harz Mountains of Germany. It commonly contains a few percent chromium-rich spinel as an accessory mineral...
, and even chromitite
Chromitite
Chromitite is an igneous cumulate rock composed mostly of the mineral chromite. It is found in layered intrusions such as the Bushveld Igneous Complex in South Africa and the Stillwater igneous complex in Montana.-References:...
(a cumulate rock consisting largely of chromite). Small layered intrusions may be of any geologic age, for example, the Triassic
Triassic
The Triassic is a geologic period and system that extends from about 250 to 200 Mya . As the first period of the Mesozoic Era, the Triassic follows the Permian and is followed by the Jurassic. Both the start and end of the Triassic are marked by major extinction events...
Palisades Sill
Palisades Sill
The Palisades Sill is a Triassic, 200 Ma diabase intrusion. It extends through portions of New York and New Jersey. It is most noteworthy for The Palisades, the cliffs that rise steeply above the western bank of the Hudson River...
in New York and the larger Eocene
Eocene
The Eocene Epoch, lasting from about 56 to 34 million years ago , is a major division of the geologic timescale and the second epoch of the Paleogene Period in the Cenozoic Era. The Eocene spans the time from the end of the Palaeocene Epoch to the beginning of the Oligocene Epoch. The start of the...
Skaergaard complex in Greenland. The largest layered mafic intrusions are tens of kilometers in size and almost all are Proterozoic
Proterozoic
The Proterozoic is a geological eon representing a period before the first abundant complex life on Earth. The name Proterozoic comes from the Greek "earlier life"...
in age, e.g., the Stillwater igneous complex
Stillwater igneous complex
The Stillwater igneous complex is a large layered intrusion located in southern Montana in Stillwater, Sweet Grass and Park Counties. The complex is exposed across 30 miles of the north flank of the Beartooth Mountain Range. The complex has extensive reserves of chromium ore and has a history of...
(Montana), the Muskox intrusion
Muskox intrusion
The Muskox intrusion is a layered intrusion in Nunavut, Canada. It is located northeast of Great Bear Lake and south of Kugluktuk on Coronation Gulf...
(Canada), and the Great Dyke
Great Dyke
The Great Dyke is a linear geological feature that trends nearly north-south through the centre of Zimbabwe passing just to the west of the capital, Harare. It consists of a band of short, narrow ridges and hills spanning for approximately . The hills become taller as the range goes north, and...
(Zimbabwe). Cumulate dunite may also be found in ophiolite complexes, associated with layers of wehrlite, pyroxenite, and gabbro
Gabbro
Gabbro refers to a large group of dark, coarse-grained, intrusive mafic igneous rocks chemically equivalent to basalt. The rocks are plutonic, formed when molten magma is trapped beneath the Earth's surface and cools into a crystalline mass....
.
Dunite was named by the Austrian geologist, Ferdinand von Hochstetter
Ferdinand von Hochstetter
Christian Gottlieb Ferdinand Ritter von Hochstetter was a German geologist.He was born at Esslingen, Württemberg, the son of Christian Ferdinand Friedrich Hochstetter , a clergyman and professor at Bonn, who was also a botanist and mineralogist...
in 1859 after Dun Mountain near Nelson
Nelson, New Zealand
Nelson is a city on the eastern shores of Tasman Bay, and is the economic and cultural centre of the Nelson-Tasman region. Established in 1841, it is the second oldest settled city in New Zealand and the oldest in the South Island....
, New Zealand
New Zealand
New Zealand is an island country in the south-western Pacific Ocean comprising two main landmasses and numerous smaller islands. The country is situated some east of Australia across the Tasman Sea, and roughly south of the Pacific island nations of New Caledonia, Fiji, and Tonga...
. Dunn Mountain was given its name because of the dun colour of the underlying ultramafic rocks. This color results from surface weathering
Weathering
Weathering is the breaking down of rocks, soils and minerals as well as artificial materials through contact with the Earth's atmosphere, biota and waters...
that oxidizes the iron in olivine in temperate climates (weathering in tropical climates creates a deep red soil). Dun Mountain is separated from its sister massif, Red Mountain, at the southern end of South Island, New Zealand, by the Alpine Fault
Alpine Fault
The Alpine Fault is a geological fault, more specifically known as a right-lateral strike-slip fault, that runs almost the entire length of New Zealand's South Island. It forms a transform boundary between the Pacific Plate and the Indo-Australian Plate. Earthquakes along the fault, and the...
, an approximately 600 km long right lateral strike slip fault similar to the San Andreas fault
San Andreas Fault
The San Andreas Fault is a continental strike-slip fault that runs a length of roughly through California in the United States. The fault's motion is right-lateral strike-slip...
in California
California
California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...
, USA. A massive exposure of dunite in the United States can be found as Twin Sisters Mountain
Twin Sisters Mountain
Twin Sisters Mountain, commonly called the Twin Sisters, is a mountain in the U.S. state of Washington. Part of the Cascade Range, it lies just southwest of Mount Baker. Of its two main peaks, South Twin is higher, at...
, near Mount Baker
Mount Baker
Mount Baker , also known as Koma Kulshan or simply Kulshan, is an active glaciated andesitic stratovolcano in the Cascade Volcanic Arc and the North Cascades of Washington State in the United States. It is the second-most active volcano in the range after Mount Saint Helens...
in the northern Cascade Range
Cascade Range
The Cascade Range is a major mountain range of western North America, extending from southern British Columbia through Washington and Oregon to Northern California. It includes both non-volcanic mountains, such as the North Cascades, and the notable volcanoes known as the High Cascades...
of Washington.
Dunite could be used to sequester CO2 and help mitigate global climate change via accelerated rock weathering. This would involve spreading large quantities of finely ground dunite in tropical regions known near sources of dunite. One significant environmental side effect would be a significant increase in the pH of nearby rivers.