In the manufacture of Portland cement

Portland cement

Portland cement is the most common type of cement in general use around the world because it is a basic ingredient of concrete, mortar, stucco and most non-specialty grout...

, clinker is lumps or nodules, usually 3-25 mm in diameter, produced by sintering

Sintering

Sintering is a method used to create objects from powders. It is based on atomic diffusion. Diffusion occurs in any material above absolute zero, but it occurs much faster at higher temperatures. In most sintering processes, the powdered material is held in a mold and then heated to a temperature...

 limestone

Limestone

Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....

 and alumino-silicate during the cement kiln

Cement kiln

Cement kilns are used for the pyroprocessing stage of manufacture of Portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates...

 stage.

Uses

Clinker is ground

Grinding operations

Grinding is an abrasive machining process that uses a grinding wheel as the cutting tool.A wide variety of machines are used for grinding:* Hand-cranked knife-sharpening stones * Handheld power tools such as angle grinders and die grinders...

 (usually with the addition of a little gypsum

Gypsum

Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...

, that is, calcium sulfate

Calcium sulfate

Calcium sulfate is a common laboratory and industrial chemical. In the form of γ-anhydrite , it is used as a desiccant. It is also used as a coagulant in products like tofu. In the natural state, unrefined calcium sulfate is a translucent, crystalline white rock...

 dihydrate) to become Portland cement. It may also be combined with other active ingredients or chemical admixtures to produce:

• ground granulated blast furnace slag
  Ground granulated blast furnace slag
  Ground-granulated blast-furnace slag is obtained by quenching molten iron slag from a blast furnace in water or steam, to produce a glassy, granular product that is then dried and ground into a fine powder.-Applications:GGBS is used to make durable concrete structures in combination with ordinary...
  
   cement
  Cement
  In the most general sense of the word, a cement is a binder, a substance that sets and hardens independently, and can bind other materials together. The word "cement" traces to the Romans, who used the term opus caementicium to describe masonry resembling modern concrete that was made from crushed...
  
  
• pozzolana
  Pozzolana
  Pozzolana, also known as pozzolanic ash , is a fine, sandy volcanic ash. Pozzolanic ash was first discovered and dug in Italy, at Pozzuoli. It was later discovered at a number of other sites as well...
  
   cement
  Cement
  In the most general sense of the word, a cement is a binder, a substance that sets and hardens independently, and can bind other materials together. The word "cement" traces to the Romans, who used the term opus caementicium to describe masonry resembling modern concrete that was made from crushed...
  
  
• silica fume
  Silica fume
  Silica fume, also known as microsilica, is a fine-grain, thin, and very high surface area silica.It is sometimes confused with fumed silica and colloidal silica...
  
   cement
  Cement
  In the most general sense of the word, a cement is a binder, a substance that sets and hardens independently, and can bind other materials together. The word "cement" traces to the Romans, who used the term opus caementicium to describe masonry resembling modern concrete that was made from crushed...
  
  

Clinker, if stored in dry conditions, can be kept for several months without appreciable loss of quality. Because of this, and because it can easily be handled by ordinary mineral handling equipment, clinker is traded internationally in large quantities. Cement manufacturers purchasing clinker grind it as an addition to their own clinker at their cement plants. Manufacturers also ship clinker to grinding plants in areas where cement-making raw materials are not available.

Clinker grinding aids

Gypsum

Gypsum

Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...

 is added to clinker primarily as an additive preventing the flash settings of cement, but it is also very effective to facilitate the grinding of clinker by preventing agglomeration and coating of the powder at the surface of balls and mill wall.

Organic compounds are also often added as grinding aids to avoid powder agglomeration. Triethanolamine

Triethanolamine

Triethanolamine, often abbreviated as TEA, is an organic chemical compound which is both a tertiary amine and a triol. A triol is a molecule with three alcohol groups. Like other amines, triethanolamine is a strong base due to the lone pair of electrons on the nitrogen atom. Triethanolamine can...

 (TEA) is commonly used at 0.1 wt. % and is proved to be very effective. Other additives are sometimes used, such as ethylene glycol

Ethylene glycol

Ethylene glycol is an organic compound widely used as an automotive antifreeze and a precursor to polymers. In its pure form, it is an odorless, colorless, syrupy, sweet-tasting liquid...

, oleic acid

Oleic acid

Oleic acid is a monounsaturated omega-9 fatty acid found in various animal and vegetable fats. It has the formula CH37CH=CH7COOH. It is an odorless, colourless oil, although commercial samples may be yellowish. The trans isomer of oleic acid is called elaidic acid...

, dodecyl-benzene sulfonate, ... .
Portland cement

Portland cement

Portland cement is the most common type of cement in general use around the world because it is a basic ingredient of concrete, mortar, stucco and most non-specialty grout...

 clinker is made by heating in a rotary kiln

Rotary kiln

A Rotary kiln is a pyroprocessing device used to raise materials to a high temperature in a continuous process. Materials produced using rotary kilns include:* Cement* Lime* Refractories* Metakaolin* Titanium dioxide* Alumina* Vermiculite...

 at high temperature a homogeneous mixture of raw materials. The products of the chemical reaction aggregate together as molten minerals at the sintering

Sintering

Sintering is a method used to create objects from powders. It is based on atomic diffusion. Diffusion occurs in any material above absolute zero, but it occurs much faster at higher temperatures. In most sintering processes, the powdered material is held in a mold and then heated to a temperature...

 temperature. The sintering temperature for modern cements is about 1450 °C. Aluminium oxide

Aluminium oxide

Aluminium oxide is an amphoteric oxide with the chemical formula 23. It is commonly referred to as alumina, or corundum in its crystalline form, as well as many other names, reflecting its widespread occurrence in nature and industry...

 and iron oxide

Iron oxide

Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides.Iron oxides and oxide-hydroxides are widespread in nature, play an important role in many geological and biological processes, and are widely utilized by humans, e.g.,...

 are present as a flux

Flux (metallurgy)

In metallurgy, a flux , is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time...

 and contribute little to the cement strength

Strength

- Physical ability :*Physical strength, as in people or animals*Superhuman strength, as in fictional characters*A common character attribute in role-playing gamesConflict between persons or groups:*Virtue and moral uprightness...

. For special cements, such as Low Heat (LH) and Sulfate Resistant (SR) types, it is necessary to limit the amount of tricalciumaluminate (3 CaO·Al₂O₃) formed. The major raw material for the clinker-making is usually limestone

Limestone

Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....

 (CaCO₃) mixed with a second material containing clay

Clay

Clay is a general term including many combinations of one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are mostly composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure.- Formation :Clay minerals...

 as source of alumino-silicate. Normally, an impure limestone which contains clay or SiO₂ is used. The CaCO₃ content of these limestones can be as low as 80 %. Second raw materials (materials in the rawmix other than limestone) depend on the purity of the limestone. Some of the second raw materials used are: clay

Clay

Clay is a general term including many combinations of one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are mostly composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure.- Formation :Clay minerals...

, shale

Shale

Shale is a fine-grained, clastic sedimentary rock composed of mud that is a mix of flakes of clay minerals and tiny fragments of other minerals, especially quartz and calcite. The ratio of clay to other minerals is variable. Shale is characterized by breaks along thin laminae or parallel layering...

, sand

Sand

Sand is a naturally occurring granular material composed of finely divided rock and mineral particles.The composition of sand is highly variable, depending on the local rock sources and conditions, but the most common constituent of sand in inland continental settings and non-tropical coastal...

, iron ore, bauxite

Bauxite

Bauxite is an aluminium ore and is the main source of aluminium. This form of rock consists mostly of the minerals gibbsite Al3, boehmite γ-AlO, and diaspore α-AlO, in a mixture with the two iron oxides goethite and hematite, the clay mineral kaolinite, and small amounts of anatase TiO2...

, fly ash

Fly ash

Fly ash is one of the residues generated in combustion, and comprises the fine particles that rise with the flue gases. Ash which does not rise is termed bottom ash. In an industrial context, fly ash usually refers to ash produced during combustion of coal...

 and slag

Slag

Slag is a partially vitreous by-product of smelting ore to separate the metal fraction from the unwanted fraction. It can usually be considered to be a mixture of metal oxides and silicon dioxide. However, slags can contain metal sulfides and metal atoms in the elemental form...

.