In chemistry

Chemistry

Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties. Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds....

, bond strength is measured between two atom

Atom

The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons...

s joined in a chemical bond

Chemical bond

A chemical bond is an attraction between atoms that allows the formation of chemical substances that contain two or more atoms. The bond is caused by the electromagnetic force attraction between opposite charges, either between electrons and nuclei, or as the result of a dipole attraction...

. It is the degree to which each atom linked to another atom contributes to the valency of this other atom. Bond strength is intimately linked to bond order

Bond order

Bond order is the number of chemical bonds between a pair of atoms. For example, in diatomic nitrogen N≡N the bond order is 3, while in acetylene H−C≡C−H the bond order between the two carbon atoms is also 3, and the C−H bond order is 1. Bond order gives an indication to the stability of a bond....

.

Bond strength can be quantified by:

• bond energy
  Bond energy
  In chemistry, bond energy is the measure of bond strength in a chemical bond. It is the heat required to break one Mole of molecules into their individual atoms. For example, the carbon-hydrogen bond energy in methane E is the enthalpy change involved with breaking up one molecule of methane into...
  
  : requires lengthy calculations, even for the simplest bonds.
• bond-dissociation energy

Another criterion of bond strength is the qualitative relation between bond energies and the overlap of atomic orbital

Atomic orbital

An atomic orbital is a mathematical function that describes the wave-like behavior of either one electron or a pair of electrons in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus...

s of the bonds (Pauling

Linus Pauling

Linus Carl Pauling was an American chemist, biochemist, peace activist, author, and educator. He was one of the most influential chemists in history and ranks among the most important scientists of the 20th century...

 and Mulliken

Robert S. Mulliken

Robert Sanderson Mulliken was an American physicist and chemist, primarily responsible for the early development of molecular orbital theory, i.e. the elaboration of the molecular orbital method of computing the structure of molecules. Dr. Mulliken received the Nobel Prize for chemistry in 1966...

). The more these overlap, the more the bonding electron

Electron

The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...

s are to be found between the nuclei

Atomic nucleus

The nucleus is the very dense region consisting of protons and neutrons at the center of an atom. It was discovered in 1911, as a result of Ernest Rutherford's interpretation of the famous 1909 Rutherford experiment performed by Hans Geiger and Ernest Marsden, under the direction of Rutherford. The...

 and hence stronger will be the bond. Overlap is necessary for the formation of molecular orbitals. This overlap can be calculated and is called the overlap integral

Integral

Integration is an important concept in mathematics and, together with its inverse, differentiation, is one of the two main operations in calculus...

.