Avogadrite
Encyclopedia
Avogadrite is a potassium
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...

-caesium
Caesium
Caesium or cesium is the chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-gold alkali metal with a melting point of 28 °C , which makes it one of only five elemental metals that are liquid at room temperature...

 tetrafluoroborate
Tetrafluoroborate
Tetrafluoroborate is the anion BF4−. This tetrahedral species is isoelectronic with tetrafluoromethane, CF4 and tetrafluoroammonium NF4+, and is valence isoelectronic with many stable and important species including the closely related anion perchlorate, ClO4−...

. Avogadrite crystallizes in the orthorhombic system (space group
Space group
In mathematics and geometry, a space group is a symmetry group, usually for three dimensions, that divides space into discrete repeatable domains.In three dimensions, there are 219 unique types, or counted as 230 if chiral copies are considered distinct...

 Pnma) with cell parameters a 8.66 Å, b 5.48 Å and c Å 7.03. The mineral is only found as a sublimation product around volcanic
Volcano
2. Bedrock3. Conduit 4. Base5. Sill6. Dike7. Layers of ash emitted by the volcano8. Flank| 9. Layers of lava emitted by the volcano10. Throat11. Parasitic cone12. Lava flow13. Vent14. Crater15...

 fumarole
Fumarole
A fumarole is an opening in a planet's crust, often in the neighborhood of volcanoes, which emits steam and gases such as carbon dioxide, sulfur dioxide, hydrochloric acid, and hydrogen sulfide. The steam is created when superheated water turns to steam as its pressure drops when it emerges from...

s.

History

The mineral was discovered by the Italian
Italy
Italy , officially the Italian Republic languages]] under the European Charter for Regional or Minority Languages. In each of these, Italy's official name is as follows:;;;;;;;;), is a unitary parliamentary republic in South-Central Europe. To the north it borders France, Switzerland, Austria and...

 mineralogist Ferruccio Zambonini
Ferruccio Zambonini
Ferruccio Zambonini was an Italian mineralogist and geologist. Most of his time he worked on the geology and mineralogy of Mount Vesuvius.-Life and work:...


in 1926. He analyzed several samples from the volcanic fumaroles close to Mount Vesuvius
Mount Vesuvius
Mount Vesuvius is a stratovolcano in the Gulf of Naples, Italy, about east of Naples and a short distance from the shore. It is the only volcano on the European mainland to have erupted within the last hundred years, although it is not currently erupting...

 and from the Lipari
Lipari
Lipari is the largest of the Aeolian Islands in the Tyrrhenian Sea off the north coast of Sicily, and the name of the island's main town. It has a permanent population of 11,231; during the May–September tourist season, its population may reach up to 20,000....

 islands. He named it after the Italian scientist Amedeo Avogadro
Amedeo Avogadro
Lorenzo Romano Amedeo Carlo Avogadro di Quaregna e di Cerreto, Count of Quaregna and Cerreto was an Italian savant. He is most noted for his contributions to molecular theory, including what is known as Avogadro's law...

.
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