Superionic Water
Encyclopedia
Superionic water is a theoretical phase
Phase
-In physics:*Phase , a physically distinctive form of a substance, such as the solid, liquid, and gaseous states of ordinary matter**Phase transition is the transformation of a thermodynamic system from one phase to another*Phase...

 of water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 under extreme heat and pressure which has properties of both a solid and a liquid.

At high temperatures and pressures, such as in the interior of giant planets, it is argued that water exists as ionic water in which the molecules break down into a soup of hydrogen and oxygen ions, and at even higher pressures as superionic water in which the oxygen crystallises but the hydrogen ions float around freely within the oxygen lattice.

Properties

Superionic water is thus far theoretical, but predictions have been made about its properties. If it were present on earth, it would rapidly decompress and explode. Under the conditions it is theorized would cause water to enter the phase, it is believed that superionic water would be as hard as iron and would glow yellow.

History of theoretical and experimental evidence

In 1999 Cavazzoni, et al. predicted that such a state would exist for ammonia
Ammonia
Ammonia is a compound of nitrogen and hydrogen with the formula . It is a colourless gas with a characteristic pungent odour. Ammonia contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to food and fertilizers. Ammonia, either directly or...

 and water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

 in conditions such as those existing on Uranus
Uranus
Uranus is the seventh planet from the Sun. It has the third-largest planetary radius and fourth-largest planetary mass in the Solar System. It is named after the ancient Greek deity of the sky Uranus , the father of Cronus and grandfather of Zeus...

 and Neptune
Neptune
Neptune is the eighth and farthest planet from the Sun in the Solar System. Named for the Roman god of the sea, it is the fourth-largest planet by diameter and the third largest by mass. Neptune is 17 times the mass of Earth and is slightly more massive than its near-twin Uranus, which is 15 times...

. In 2005 Laurence Fried led a team at Lawrence Livermore National Laboratory
Lawrence Livermore National Laboratory
The Lawrence Livermore National Laboratory , just outside Livermore, California, is a Federally Funded Research and Development Center founded by the University of California in 1952...

 in California
California
California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...

 to recreate the formative conditions of superionic water. Using a technique involving smashing water molecules between diamonds and super heating it with lasers they observed frequency shifts which indicated that a phase transition had taken place. The team also created computer models which indicated that they had indeed created superionic water.

Existence in gas giants

It is theorized that the gas giant
Gas giant
A gas giant is a large planet that is not primarily composed of rock or other solid matter. There are four gas giants in the Solar System: Jupiter, Saturn, Uranus, and Neptune...

 planets Uranus
Uranus
Uranus is the seventh planet from the Sun. It has the third-largest planetary radius and fourth-largest planetary mass in the Solar System. It is named after the ancient Greek deity of the sky Uranus , the father of Cronus and grandfather of Zeus...

 and Neptune
Neptune
Neptune is the eighth and farthest planet from the Sun in the Solar System. Named for the Roman god of the sea, it is the fourth-largest planet by diameter and the third largest by mass. Neptune is 17 times the mass of Earth and is slightly more massive than its near-twin Uranus, which is 15 times...

hold a layer of superionic water.
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