Spontaneous absolute asymmetric synthesis
Encyclopedia
Spontaneous absolute asymmetric synthesis is a chemical phenomenon that stochastically
Stochastic
Stochastic refers to systems whose behaviour is intrinsically non-deterministic. A stochastic process is one whose behavior is non-deterministic, in that a system's subsequent state is determined both by the process's predictable actions and by a random element. However, according to M. Kac and E...

generates chirality
Chirality
Chirality is a property of asymmetry important in several branches of science. It may refer to:* Chirality , a property of molecules having a non-superimposable mirror image...

 based on fluctuations and autocatalysis
Autocatalysis
A single chemical reaction is said to have undergone autocatalysis, or be autocatalytic, if the reaction product itself is the catalyst for that reaction....

. In certain reactions which initially do not contain chiral information, stochastically distributed enantiomeric excess
Enantiomeric excess
The enantiomeric excess of a substance is a measure of how pure it is. In this case, the impurity is the undesired enantiomer .-Definition:...

 can be observed. The phenomenon is different from chiral amplification, where enantiomeric excess is present from the beginning and not stochastically distributed. Hence, when the experiment is repeated many times, the average enantiomeric excess approaches 0%. The phenomenon has important implications concerning the origin of homochirality
Homochirality
Homochirality is a term used to refer to a group of molecules that possess the same sense of chirality. Molecules involved are not necessarily the same compound, but similar groups are arranged in the same way around a central atom. In biology homochirality is found in the chemical building blocks...

in nature.
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