Sec-Butyl acetate
Encyclopedia
sec-Butyl acetate, or s-butyl acetate, is a solvent
Solvent
A solvent is a liquid, solid, or gas that dissolves another solid, liquid, or gaseous solute, resulting in a solution that is soluble in a certain volume of solvent at a specified temperature...

 commonly used as a solvent in lacquer
Lacquer
In a general sense, lacquer is a somewhat imprecise term for a clear or coloured varnish that dries by solvent evaporation and often a curing process as well that produces a hard, durable finish, in any sheen level from ultra matte to high gloss and that can be further polished as required...

s and enamels
Enamel paint
Enamel paint is paint that air dries to a hard, usually glossy, finish, used for coating surfaces that are outdoors or otherwise subject to hard wear or variations in temperature; it should not be confused with decorated objects in "painted enamel", where vitreous enamel is applied with brushes and...

, where it is used in the production of acyclic polymers, vinyl resins, and nitrocellulose
Nitrocellulose
Nitrocellulose is a highly flammable compound formed by nitrating cellulose through exposure to nitric acid or another powerful nitrating agent. When used as a propellant or low-order explosive, it is also known as guncotton...

 . It is a clear flammable liquid
Flammable liquid
Generally, a flammable liquid is a liquid that can catch fire.In the USA, there is a precise definition of flammable liquid as one with a flash point below 100 degrees Fahrenheit. Less-flammable liquids are defined as combustible liquids...

 with a sweet smell.

sec-Butyl acetate has three isomers that are also acetate esters: n-butyl acetate
Butyl acetate
n-Butyl acetate, also known as butyl ethanoate, is an organic compound commonly used as a solvent in the production of lacquers and other products. It is also used as a synthetic fruit flavoring in foods such as candy, ice cream, cheeses, and baked goods. Butyl acetate is found in many types of...

, isobutyl acetate
Isobutyl acetate
The chemical compound isobutyl acetate, also known as 2-methylpropyl ethanoate or β-methylpropyl acetate, is a common solvent. It is produced from the esterification of isobutanol with acetic acid. It is used as a solvent for lacquer and nitrocellulose...

, and tert-butyl acetate
Tert-Butyl acetate
tert-Butyl acetate, or t-butyl acetate is a colourless flammable liquid with a camphor- or blueberry-like smell. It is used as a solvent in the production of lacquers, enamels, inks, adhesives, thinners and industrial cleaners...

.

History

The first method of production of sec-butyl acetate was the esterification of sec-butanol and acetic anhydride
Acetic anhydride
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula 2O. Commonly abbreviated Ac2O, it is the simplest isolatable acid anhydride and is a widely used reagent in organic synthesis...

 It was experimentally determined and published in 1946 by Rolf Altschul.

Toxicology

The LD50 for rats is 13 g/kg . Exposure in humans to significant quantities of sec-butyl acetate can cause irritation to the eyes, mouth, throat, nose, and skin. Ingestion and inhalation of sec-butyl acetate can cause central nervous system depression producing symptoms of dizziness and disorientation.

External links

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