Rouging
Encyclopedia
Rouging refers to a form of corrosion
Corrosion
Corrosion is the disintegration of an engineered material into its constituent atoms due to chemical reactions with its surroundings. In the most common use of the word, this means electrochemical oxidation of metals in reaction with an oxidant such as oxygen...

 found in stainless steel
Stainless steel
In metallurgy, stainless steel, also known as inox steel or inox from French "inoxydable", is defined as a steel alloy with a minimum of 10.5 or 11% chromium content by mass....

. It can be due to iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 contamination of the stainless steel surface due to welding of ferrous
Ferrous
Ferrous , in chemistry, indicates a divalent iron compound , as opposed to ferric, which indicates a trivalent iron compound ....

 steel
Steel
Steel is an alloy that consists mostly of iron and has a carbon content between 0.2% and 2.1% by weight, depending on the grade. Carbon is the most common alloying material for iron, but various other alloying elements are used, such as manganese, chromium, vanadium, and tungsten...

for support columns, or other temporary means, which when welded off, leaving a low chromium area.

There are three classes of rouging: Class I, Class II, and Class III.

Class I - stainless steel surface and the Cr/Fe ratio of the metal surface beneath such deposits usually remain unaltered.

Class II - Iron particles originating in-situ on unpassivated or improperly passivated stainless steel surfaces. By their formation the Cr/Fe ratio of the metal surface is altered.

Class III - Iron oxide (or scale) which forms on surfaces in high temperature steam systems. The Cr/Fe ratio of the protective film is usually altered.

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