Principle of least motion
Encyclopedia
In organic chemistry
Organic chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, composition, reactions, and preparation of carbon-based compounds, hydrocarbons, and their derivatives...

, the principle of least motion is the hypothesis that when multiple species with different nuclear structures could theoretically form as products of a given chemical reaction, the more likely to form tends to be the one requiring the least amount of change in nuclear structure or the smallest change in nuclear positions.

See also Principle of least action
Principle of least action
In physics, the principle of least action – or, more accurately, the principle of stationary action – is a variational principle that, when applied to the action of a mechanical system, can be used to obtain the equations of motion for that system...

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