Polycaprolactone
Overview
Polycaprolactone is a biodegradable polyester
with a low melting point
of around 60°C and a glass transition temperature of about −60°C. PCL is prepared by ring opening polymerization
of ε-caprolactone
using a catalyst such as stannous octoate. Recently a wide range of catalysts for the ring opening polymerization of caprolactone have been reviewed. The most common use of polycaprolactone is in the manufacture of speciality polyurethane
s.
Polyester
Polyester is a category of polymers which contain the ester functional group in their main chain. Although there are many polyesters, the term "polyester" as a specific material most commonly refers to polyethylene terephthalate...
with a low melting point
Melting point
The melting point of a solid is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at standard atmospheric pressure...
of around 60°C and a glass transition temperature of about −60°C. PCL is prepared by ring opening polymerization
Ring-opening polymerization
In polymer chemistry, ring-opening polymerization is a form of chain-growth polymerization, in which the terminal end of a polymer acts as a reactive center, where further cyclic monomers join to form a larger polymer chain through ionic propagation...
of ε-caprolactone
Caprolactone
ε-Caprolactone or simply caprolactone is a cyclic ester, a member of the lactone family, with a seven-membered ring with the formula 5CO2. This colorless liquid is miscible with most organic solvents...
using a catalyst such as stannous octoate. Recently a wide range of catalysts for the ring opening polymerization of caprolactone have been reviewed. The most common use of polycaprolactone is in the manufacture of speciality polyurethane
Polyurethane
A polyurethane is any polymer composed of a chain of organic units joined by carbamate links. Polyurethane polymers are formed through step-growth polymerization, by reacting a monomer with another monomer in the presence of a catalyst.Polyurethanes are...
s.