Plutonium oxide is the chemical compound

Chemical compound

A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 with the formula

Chemical formula

A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 PuO₂. This high melting point solid is a principal compound of plutonium

Plutonium

Plutonium is a transuranic radioactive chemical element with the chemical symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, forming a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation...

. It can vary in color from yellow to olive green, depending on the particle size, temperature and method of production.
PuO₂ crystallizes in the fluorite

Fluorite

Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...

 motif, with the Pu⁴⁺ centers organized in a face-centered cubic array and oxide ions occupying tetrahedral holes.