Pensky-Martens closed cup
Encyclopedia
In the Pensky–Martens closed-cup flash-point test, a brass
Brass
Brass is an alloy of copper and zinc; the proportions of zinc and copper can be varied to create a range of brasses with varying properties.In comparison, bronze is principally an alloy of copper and tin...

 test cup is filled with a test specimen and fitted with a cover. The sample is heated and stirred at specified rates depending on what it is that is being tested. An ignition
Combustion
Combustion or burning is the sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat and conversion of chemical species. The release of heat can result in the production of light in the form of either glowing or a flame...

 source is directed into the cup at regular intervals with simultaneous interruption of stirring until a flash that spreads throughout the inside of the cup is seen. The corresponding temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

 is its flash point
Flash point
The flash point of a volatile material is the lowest temperature at which it can vaporize to form an ignitable mixture in air. Measuring a flash point requires an ignition source...

.

Pensky–Martens closed cup is sealed with a lid through which the ignition source can be introduced periodically. The vapour above the liquid is assumed to be in reasonable equilibrium with the liquid. Closed cup testers give lower values for the flashpoint (typically 5–10 K) and are a better approximation to the temperature at which the vapour pressure reaches the "lower flammable limit" (LFL).
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