Flash point
The flash point of a volatile
Volatility (chemistry)
In chemistry and physics, volatility is the tendency of a substance to vaporize. Volatility is directly related to a substance's vapor pressure. At a given temperature, a substance with higher vapor pressure vaporizes more readily than a substance with a lower vapor pressure.The term is primarily...

 material is the lowest temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

 at which it can vaporize to form an ignitable mixture in air. Measuring a flash point requires an ignition source. At the flash point, the vapor may cease to burn when the source of ignition is removed.

The flash point is not to be confused with the autoignition temperature
Autoignition temperature
The autoignition temperature or kindling point of a substance is the lowest temperature at which it will spontaneously ignite in a normal atmosphere without an external source of ignition, such as a flame or spark. This temperature is required to supply the activation energy needed for combustion...

, which does not require an ignition source.

The fire point
Fire point
The fire point of a fuel is the temperature at which it will continue to burn for at least 5 seconds after ignition by an open flame. At the flash point, a lower temperature, a substance will ignite briefly, but vapor might not be produced at a rate to sustain the fire...

, a higher temperature, is defined as the temperature at which the vapor continues to burn after being ignited.