Marula oil
Encyclopedia
Marula oil is extracted from the kernels (nuts) of the Marula tree (Sclerocarya birrea
Sclerocarya birrea
The Marula is a medium-sized dioecious tree, indigenous to the miombo woodlands of Southern Africa and the Sudano-Sahelian range of West Africa. The tree is a single stemmed tree with a wide spreading crown...

), from the Anacardiaceae
Anacardiaceae
Anacardiaceae are a family of flowering plants bearing fruits that are drupes and in some cases producing urushiol, an irritant. Anacardiaceae include numerous genera with several of economic importance. Notable plants in this family include cashew , mango, poison ivy, sumac, smoke tree, and marula...

 family. Marula oil is traditionally used in cosmetics
Cosmetics
Cosmetics are substances used to enhance the appearance or odor of the human body. Cosmetics include skin-care creams, lotions, powders, perfumes, lipsticks, fingernail and toe nail polish, eye and facial makeup, towelettes, permanent waves, colored contact lenses, hair colors, hair sprays and...

, in food as a cooking oil
Cooking oil
Cooking oil is purified fat of plant origin, which is usually liquid at room temperature ....

 and as a meat preservative and to treat leather.

Chemical structure

Marula oil contains a large proportion of monounsaturated fatty acids
Monounsaturated fat
In biochemistry and nutrition, monounsaturated fats or MUFA are fatty acids that have one double bond in the fatty acid chain and all of the remainder of the carbon atoms in the chain are single-bonded...

 and natural antioxidants which make the oil very stable. The fatty acid composition of marula oil includes:

Mono-unsaturated Fatty Acids:
  • Oleic acid
    Oleic acid
    Oleic acid is a monounsaturated omega-9 fatty acid found in various animal and vegetable fats. It has the formula CH37CH=CH7COOH. It is an odorless, colourless oil, although commercial samples may be yellowish. The trans isomer of oleic acid is called elaidic acid...

     (70-78 %)


Poly-unsaturated Fatty Acids:
  • Linoleic acid
    Linoleic acid
    Linoleic acid is an unsaturated n-6 fatty acid. It is a colorless liquid at room temperature. In physiological literature, it has a lipid number of 18:2...

     (4.0-7.0 %)
  • Alpha-linolenic acid
    Alpha-linolenic acid
    α-Linolenic acid is an organic compound found in many common vegetable oils. In terms of its structure, it is named all-cis-9,12,15-octadecatrienoic acid. In physiological literature, it is given the name 18:3 ....

     (0.1-0.7 %)


Saturated Fatty Acids:
  • Palmitic acid
    Palmitic acid
    Palmitic acid, or hexadecanoic acid in IUPAC nomenclature, is one of the most common saturated fatty acids found in animals and plants. Its molecular formula is CH314CO2H. As its name indicates, it is a major component of the oil from palm trees . Palmitate is a term for the salts and esters of...

     (9-12 %)
  • Stearic acid
    Stearic acid
    Stearic acid is the saturated fatty acid with an 18 carbon chain and has the IUPAC name octadecanoic acid. It is a waxy solid, and its chemical formula is CH316CO2H. Its name comes from the Greek word στέαρ "stéatos", which means tallow. The salts and esters of stearic acid are called stearates...

     (5.0-8.0 %)
  • Arachidonic acid
    Arachidonic acid
    Arachidonic acid is a polyunsaturated omega-6 fatty acid 20:4.It is the counterpart to the saturated arachidic acid found in peanut oil, Arachidonic acid (AA, sometimes ARA) is a polyunsaturated omega-6 fatty acid 20:4(ω-6).It is the counterpart to the saturated arachidic acid found in peanut oil,...

     (0.3-0.7 %)


Tocopherol
Tocopherol
Tocopherols are a class of chemical compounds of which many have vitamin E activity. It is a series of organic compounds consisting of various methylated phenols...

s, sterol
Sterol
Sterols, also known as steroid alcohols, are a subgroup of the steroids and an important class of organic molecules. They occur naturally in plants, animals, and fungi, with the most familiar type of animal sterol being cholesterol...

s and lavonoid]s], with antioxidant action, procyanidin
Procyanidin
Procyanidins are members of the proanthocyanidin class of flavonoids. They are oligomeric compounds, formed from catechin and epicatechin molecules....

, galattotannin and catechins
Flavan-3-ol
Flavan-3-ols are a class of flavonoids that use the 2-phenyl-3,4-dihydro-2H-chromen-3-ol skeleton. These compounds include the catechins and the catechin gallates....

 are also found in marula oil.

Physical properties

Marula oil has a clear, light yellow colour and a nutty aroma. It has a saponification value
Saponification value
Saponification value represents the number of milligrams of potassium hydroxide required to saponify 1g of fat under the conditions specified. It is a measure of the average molecular weight of all the fatty acids present...

 of approximately 188-199 and a specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 of 0.91-0.92 (at 15°C).

Traditional uses

The Tsonga people of South Africa
South Africa
The Republic of South Africa is a country in southern Africa. Located at the southern tip of Africa, it is divided into nine provinces, with of coastline on the Atlantic and Indian oceans...

 and Mozambique
Mozambique
Mozambique, officially the Republic of Mozambique , is a country in southeastern Africa bordered by the Indian Ocean to the east, Tanzania to the north, Malawi and Zambia to the northwest, Zimbabwe to the west and Swaziland and South Africa to the southwest...

 have used the oil as a moisturising body lotion for women and also as a massage oil for babies. In the past, women used Marula oil rather than water to clean themselves.

Marula oil forms also an important part of people's diets, especially for people of the Inhambane Province in Mozambique, Owambo
Ovamboland
Ovamboland was the name given by English-speaking visitors to the land occupied by the Ovambo people in what is now northern Namibia and southern Angola...

 in north central Namibia
Namibia
Namibia, officially the Republic of Namibia , is a country in southern Africa whose western border is the Atlantic Ocean. It shares land borders with Angola and Zambia to the north, Botswana to the east and South Africa to the south and east. It gained independence from South Africa on 21 March...

, Northern KwaZulu-Natal
KwaZulu-Natal
KwaZulu-Natal is a province of South Africa. Prior to 1994, the territory now known as KwaZulu-Natal was made up of the province of Natal and the homeland of KwaZulu....

 in South Africa and the Zvishavane district of Zimbabwe
Zimbabwe
Zimbabwe is a landlocked country located in the southern part of the African continent, between the Zambezi and Limpopo rivers. It is bordered by South Africa to the south, Botswana to the southwest, Zambia and a tip of Namibia to the northwest and Mozambique to the east. Zimbabwe has three...

. Furthermore, marula plays an important role in the diet of Bushmen
Bushmen
The indigenous people of Southern Africa, whose territory spans most areas of South Africa, Zimbabwe, Lesotho, Mozambique, Swaziland, Botswana, Namibia, and Angola, are variously referred to as Bushmen, San, Sho, Barwa, Kung, or Khwe...

 and Bantu tribes. The Venda
Venda
Venda was a bantustan in northern South Africa, now part of Limpopo province. It was founded as a homeland for the Venda people, speakers of the Venda language. It bordered modern Zimbabwe and South Africa, and is now part of Limpopo in South Africa....

 utilise the oil from the kernels to preserve meat, which enables it to last up to a year. Today, Marula oil is still considered a delicacy by local people, and is added to a wide variety of traditional and modern recipes.

Applications

Studies have looked at the oxidation stability, induction period
Induction period
An induction period in chemical kinetics is an initial slow stage of a chemical reaction; after the induction period, the reaction accelerates. Ignoring induction periods can lead to runaway reactions....

 (34 hours), polar compounds, free fatty acids of Marula oil as a frying
Frying
Frying is the cooking of food in oil or another fat, a technique that originated in ancient Egypt around 2500 BC. Chemically, oils and fats are the same, differing only in melting point, but the distinction is only made when needed. In commerce, many fats are called oils by custom, e.g...

oil.
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