Mackinawite is an iron

Iron

Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 nickel

Nickel

Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

 sulfide mineral

Sulfide mineral

The sulfide minerals are a class of minerals containing sulfide as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts...

 with formula (Fe,Ni)_{1 + x}S (where x = 0 to 0.11). It crystallizes in the tetragonal crystal system

Crystal system

In crystallography, the terms crystal system, crystal family, and lattice system each refer to one of several classes of space groups, lattices, point groups, or crystals...

 and occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity

Specific gravity

Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 of 4.17.

Occurrence

It occurs in serpentinized

Serpentinite

Serpentinite is a rock composed of one or more serpentine group minerals. Minerals in this group are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle...

 peridotite

Peridotite

A peridotite is a dense, coarse-grained igneous rock, consisting mostly of the minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium, reflecting the high proportions of magnesium-rich olivine, with appreciable iron...

s as a hydrothermal alteration product. It also is found in the reducing

Redox

Redox reactions describe all chemical reactions in which atoms have their oxidation state changed....

 environment of fine grained river sediments, possibly produced by the action of magnetotactic

Magnetotactic bacteria

Magnetotactic bacteria are a polyphyletic group of bacteria discovered by Richard P. Blakemore in 1975, that orient along the magnetic field lines of Earth's magnetic field. To perform this task, these bacteria have organelles called magnetosomes that contain magnetic crystals...

 and sulfate-reducing bacteria

Bacteria

Bacteria are a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria have a wide range of shapes, ranging from spheres to rods and spirals...

. It has also been reported from meteorite

Meteorite

A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

 occurrences. It occurs in association with chalcopyrite

Chalcopyrite

Chalcopyrite is a copper iron sulfide mineral that crystallizes in the tetragonal system. It has the chemical composition CuFeS2. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.On exposure to air, chalcopyrite...

, cubanite

Cubanite

Cubanite is a yellow mineral of copper, iron, and sulfur, CuFe2S3.Cubanite was first described in 1843 for an occurrence in the Mayarí-Baracoa Belt, Oriente Province, Cuba....

, pentlandite

Pentlandite

Pentlandite is an iron-nickel sulfide, 9S8. Pentlandite usually has a Ni:Fe ratio of close to 1:1. It also contains minor cobalt.Pentlandite forms isometric crystals, but is normally found in massive granular aggregates. It is brittle with a hardness of 3.5 - 4 and specific gravity of 4.6 - 5.0 and...

, pyrrhotite

Pyrrhotite

Pyrrhotite is an unusual iron sulfide mineral with a variable iron content: FeS . The FeS endmember is known as troilite. Pyrrhotite is also called magnetic pyrite because the color is similar to pyrite and it is weakly magnetic...

, greigite

Greigite

Greigite is an iron sulfide mineral with formula Fe3S4. It is the sulfur equivalent of the iron oxide magnetite . It was first described in 1964 for an occurrence in San Bernardino County, California, and named after the mineralogist and physical chemist Joseph W...

, maucherite

Maucherite

Maucherite is a grey to reddish silver white nickel arsenide mineral. It crystallizes in the tetragonal crystal system. It occurs in hydrothermal veins alongside other nickel arsenide and sulfide minerals. It is metallic and opaque with a hardness of 5 and a specific gravity of 7.83. It is also...

 and troilite

Troilite

Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron rich endmember of the pyrrhotite group. Pyrrhotite has the formula FeS which is iron deficient...

.

It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington

Snohomish County, Washington

Snohomish County is a county located in the U.S. state of Washington. It is named after the Snohomish tribe. Since 2000, the county's population has grown from 606,024 to 713,335 residents , making it one of the fastest-growing in the state, ranking third in overall population after King and...

for which it was named.