Isotopes of germanium
Encyclopedia
Germanium
(Ge) has five naturally occurring isotope
s, 70Ge, 72Ge, 73Ge, 74Ge, and 76Ge. Of these, 76Ge is very slightly radioactive, decaying by double beta decay
with a half-life
of 1.78 × 1021 years (130 million million times the age of the universe), giving it the distinction of being the nuclide with the longest directly measured half-life (tellurium-128 has a half-life > 1000 times longer, but it has been indirectly measured by decay products in ancient rocks).
Stable 74Ge is the most common isotope, having a natural abundance
of approximately 36%. 76Ge is the least common with a natural abundance of approximately 7%. When bombarded with alpha particles, the isotopes 72Ge and 76Ge will generate stable 75As and 77Se, releasing high energy electrons in the process.
At least 27 radioisotopes have also been synthesized ranging in atomic mass from 58 to 89. The most stable of these is 68Ge, decaying by electron capture
with a half-life of 270.95 d. It decays to the medically useful positron-emitting isotope 68Ga. (See gallium-68 generator
for notes on the source of this isotope, and its medical use). The least stable known germanium stable is 60Ge with a half-life of 30 ms.
While most of germanium's radioisotopes decay by beta decay
, 61Ge and 64Ge decay by β+
delayed proton emission
. 84Ge through 87Ge also have minor β-
delayed neutron emission
decay paths.
Standard atomic mass: 72.64(1) u
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....
(Ge) has five naturally occurring isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...
s, 70Ge, 72Ge, 73Ge, 74Ge, and 76Ge. Of these, 76Ge is very slightly radioactive, decaying by double beta decay
Double beta decay
Double beta decay is a radioactive decay process where a nucleus releases two beta rays as a single process.In double-beta decay, two neutrons in the nucleus are converted to protons, and two electrons and two electron antineutrinos are emitted...
with a half-life
Half-life
Half-life, abbreviated t½, is the period of time it takes for the amount of a substance undergoing decay to decrease by half. The name was originally used to describe a characteristic of unstable atoms , but it may apply to any quantity which follows a set-rate decay.The original term, dating to...
of 1.78 × 1021 years (130 million million times the age of the universe), giving it the distinction of being the nuclide with the longest directly measured half-life (tellurium-128 has a half-life > 1000 times longer, but it has been indirectly measured by decay products in ancient rocks).
Stable 74Ge is the most common isotope, having a natural abundance
Natural abundance
In chemistry, natural abundance refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass of these isotopes is the atomic weight listed for the element in the periodic table...
of approximately 36%. 76Ge is the least common with a natural abundance of approximately 7%. When bombarded with alpha particles, the isotopes 72Ge and 76Ge will generate stable 75As and 77Se, releasing high energy electrons in the process.
At least 27 radioisotopes have also been synthesized ranging in atomic mass from 58 to 89. The most stable of these is 68Ge, decaying by electron capture
Electron capture
Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino...
with a half-life of 270.95 d. It decays to the medically useful positron-emitting isotope 68Ga. (See gallium-68 generator
Gallium-68 generator
A gallium-68 generator is a device used to extract the positron-emitting isotope 68Ga of gallium from a source of decaying germanium-68. The parent isotope 68Ge has a half-life of 271 days and can be easily sent to hospitals within the generator, where it is storable for almost a year...
for notes on the source of this isotope, and its medical use). The least stable known germanium stable is 60Ge with a half-life of 30 ms.
While most of germanium's radioisotopes decay by beta decay
Beta decay
In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a...
, 61Ge and 64Ge decay by β+
Positron emission
Positron emission or beta plus decay is a type of beta decay in which a proton is converted, via the weak force, to a neutron, releasing a positron and a neutrino....
delayed proton emission
Proton emission
Proton emission is a type of radioactive decay in which a proton is ejected from a nucleus. Proton emission can occur from high-lying excited states in a nucleus following a beta decay, in which case the process is known as beta-delayed proton emission, or can occur from the ground state of very...
. 84Ge through 87Ge also have minor β-
Beta decay
In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a...
delayed neutron emission
Neutron emission
Neutron emission is a type of radioactive decay of atoms containing excess neutrons, in which a neutron is simply ejected from the nucleus. Two examples of isotopes which emit neutrons are helium-5 and beryllium-13...
decay paths.
Standard atomic mass: 72.64(1) u
Table
nuclide symbol |
Z(p Proton The proton is a subatomic particle with the symbol or and a positive electric charge of 1 elementary charge. One or more protons are present in the nucleus of each atom, along with neutrons. The number of protons in each atom is its atomic number.... ) |
N(n Neutron The neutron is a subatomic hadron particle which has the symbol or , no net electric charge and a mass slightly larger than that of a proton. With the exception of hydrogen, nuclei of atoms consist of protons and neutrons, which are therefore collectively referred to as nucleons. The number of... ) |
isotopic mass (u) |
half-lifeBold for isotopes with half-lives longer than the age of the universe (nearly stable) | decay mode(s)Abbreviations: EC: Electron capture Electron capture Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino... IT: Isomeric transition Isomeric transition An isomeric transition is a radioactive decay process that involves emission of a gamma ray from an atom where the nucleus is in an excited metastable state, referred to in its excited state, as a nuclear isomer.... |
daughter isotope(s)Bold for stable isotopes |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
58Ge | 32 | 26 | 57.99101(34)# | 2p Proton decay In particle physics, proton decay is a hypothetical form of radioactive decay in which the proton decays into lighter subatomic particles, such as a neutral pion and a positron... |
56Zn | 0+ | |||
59Ge | 32 | 27 | 58.98175(30)# | 2p | 57Zn | 7/2-# | |||
60Ge | 32 | 28 | 59.97019(25)# | 30# ms | β+ Beta decay In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a... |
60Ga | 0+ | ||
2p | 58Zn | ||||||||
61Ge | 32 | 29 | 60.96379(32)# | 39(12) ms | β+, p (80%) | 60Zn | (3/2-)# | ||
β+ (20%) | 61Ga | ||||||||
62Ge | 32 | 30 | 61.95465(15)# | 129(35) ms | β+ | 62Ga | 0+ | ||
63Ge | 32 | 31 | 62.94964(21)# | 142(8) ms | β+ | 63Ga | (3/2-)# | ||
64Ge | 32 | 32 | 63.94165(3) | 63.7(25) s | β+ | 64Ga | 0+ | ||
65Ge | 32 | 33 | 64.93944(11) | 30.9(5) s | β+ (99.99%) | 65Ga | (3/2)- | ||
β+, p (.01%) | 64Zn | ||||||||
66Ge | 32 | 34 | 65.93384(3) | 2.26(5) h | β+ | 66Ga | 0+ | ||
67Ge | 32 | 35 | 66.932734(5) | 18.9(3) min | β+ | 67Ga | 1/2- | ||
67m1Ge | 18.20(5) keV | 13.7(9) µs | 5/2- | ||||||
67m2Ge | 751.70(6) keV | 110.9(14) ns | 9/2+ | ||||||
68GeUsed to generate Gallium-68 generator A gallium-68 generator is a device used to extract the positron-emitting isotope 68Ga of gallium from a source of decaying germanium-68. The parent isotope 68Ge has a half-life of 271 days and can be easily sent to hospitals within the generator, where it is storable for almost a year... 68Ga |
32 | 36 | 67.928094(7) | 270.95(16) d | EC Electron capture Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino... |
68Ga | 0+ | ||
69Ge | 32 | 37 | 68.9279645(14) | 39.05(10) h | β+ | 69Ga | 5/2- | ||
69m1Ge | 86.765(14) keV | 5.1(2) µs | 1/2- | ||||||
69m2Ge | 397.944(18) keV | 2.81(5) µs | 9/2+ | ||||||
70Ge | 32 | 38 | 69.9242474(11) | Stable | 0+ | 0.2038(18) | |||
71Ge | 32 | 39 | 70.9249510(11) | 11.43(3) d | EC | 71Ga | 1/2- | ||
71mGe | 198.367(10) keV | 20.40(17) ms | IT Isomeric transition An isomeric transition is a radioactive decay process that involves emission of a gamma ray from an atom where the nucleus is in an excited metastable state, referred to in its excited state, as a nuclear isomer.... |
71Ge | 9/2+ | ||||
72Ge | 32 | 40 | 71.9220758(18) | Stable | 0+ | 0.2731(26) | |||
72mGe | 691.43(4) keV | 444.2(8) ns | 0+ | ||||||
73Ge | 32 | 41 | 72.9234589(18) | Stable | 9/2+ | 0.0776(8) | |||
73m1Ge | 13.2845(15) keV | 2.92(3) µs | 5/2+ | ||||||
73m2Ge | 66.726(9) keV | 499(11) ms | 1/2- | ||||||
74Ge | 32 | 42 | 73.9211778(18) | Stable | 0+ | 0.3672(15) | |||
75Ge | 32 | 43 | 74.9228589(18) | 82.78(4) min | β- | 75As | 1/2- | ||
75m1Ge | 139.69(3) keV | 47.7(5) s | IT (99.97%) | 75Ge | 7/2+ | ||||
β- | 75As | ||||||||
75m2Ge | 192.18(7) keV | 216(5) ns | 5/2+ | ||||||
76GePrimordial Primordial nuclide In geochemistry and geonuclear physics, primordial nuclides or primordial isotopes are nuclides found on the earth that have existed in their current form since before Earth was formed. Only 288 such nuclides are known... radionuclide Radionuclide A radionuclide is an atom with an unstable nucleus, which is a nucleus characterized by excess energy available to be imparted either to a newly created radiation particle within the nucleus or to an atomic electron. The radionuclide, in this process, undergoes radioactive decay, and emits gamma... |
32 | 44 | 75.9214026(18) | 1.78(8)×1021 aLongest directly measured half-life Half-life Half-life, abbreviated t½, is the period of time it takes for the amount of a substance undergoing decay to decrease by half. The name was originally used to describe a characteristic of unstable atoms , but it may apply to any quantity which follows a set-rate decay.The original term, dating to... of all known radioisotopes |
β-β- | 76Se | 0+ | 0.0783(7) | |
77Ge | 32 | 45 | 76.9235486(18) | 11.30(1) h | β- | 77As | 7/2+ | ||
77mGe | 159.70(10) keV | 52.9(6) s | β- (79%) | 77As | 1/2- | ||||
IT (21%) | 77Ge | ||||||||
78Ge | 32 | 46 | 77.922853(4) | 88(1) min | β- | 78As | 0+ | ||
79Ge | 32 | 47 | 78.9254(1) | 18.98(3) s | β- | 79As | (1/2)- | ||
79mGe | 185.95(4) keV | 39.0(10) s | β- (96%) | 79As | (7/2+)# | ||||
IT (4%) | 79Ge | ||||||||
80Ge | 32 | 48 | 79.92537(3) | 29.5(4) s | β- | 80As | 0+ | ||
81Ge | 32 | 49 | 80.92882(13) | 7.6(6) s | β- | 81As | 9/2+# | ||
81mGe | 679.13(4) keV | 7.6(6) s | β- (99%) | 81As | (1/2+) | ||||
IT (1%) | 81Ge | ||||||||
82Ge | 32 | 50 | 81.92955(26) | 4.55(5) s | β- | 82As | 0+ | ||
83Ge | 32 | 51 | 82.93462(21)# | 1.85(6) s | β- | 83As | (5/2+)# | ||
84Ge | 32 | 52 | 83.93747(32)# | 0.947(11) s | β- (89.2%) | 84As | 0+ | ||
β-, n (10.8%) | 83As | ||||||||
85Ge | 32 | 53 | 84.94303(43)# | 535(47) ms | β- (86%) | 85As | 5/2+# | ||
β-, n (14%) | 84As | ||||||||
86Ge | 32 | 54 | 85.94649(54)# | >150 ns | β-, n | 85As | 0+ | ||
β- | 86As | ||||||||
87Ge | 32 | 55 | 86.95251(54)# | 0.14# s | 5/2+# | ||||
88Ge | 32 | 56 | 87.95691(75)# | >=300 ns | 0+ | ||||
89Ge | 32 | 57 | 88.96383(97)# | >150 ns | 3/2+# |