Helmholtz theorem (classical mechanics)
Encyclopedia
The Helmholtz theorem of classical mechanics reads as follows:

Let


be the Hamiltonian
Hamiltonian (quantum mechanics)
In quantum mechanics, the Hamiltonian H, also Ȟ or Ĥ, is the operator corresponding to the total energy of the system. Its spectrum is the set of possible outcomes when one measures the total energy of a system...

 of a one-dimensional system, where


is the kinetic energy
Kinetic energy
The kinetic energy of an object is the energy which it possesses due to its motion.It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acceleration, the body maintains this kinetic energy unless its speed changes...

 and


is a "U-shaped" potential energy
Potential energy
In physics, potential energy is the energy stored in a body or in a system due to its position in a force field or due to its configuration. The SI unit of measure for energy and work is the Joule...

 profile which depends on a parameter .
Let denote the time average. Let





Then

Remarks

The thesis of this theorem of classical mechanics
Classical mechanics
In physics, classical mechanics is one of the two major sub-fields of mechanics, which is concerned with the set of physical laws describing the motion of bodies under the action of a system of forces...

 reads exactly as the heat theorem of thermodynamics
Thermodynamics
Thermodynamics is a physical science that studies the effects on material bodies, and on radiation in regions of space, of transfer of heat and of work done on or by the bodies or radiation...

. This fact shows that thermodynamic-like relations exist between certain mechanical quantities. This in turn allows to define the "thermodynamic state" of a one-dimensional mechanical system. In particular the temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

  is given by time average of the kinetic energy , and the entropy
Entropy
Entropy is a thermodynamic property that can be used to determine the energy available for useful work in a thermodynamic process, such as in energy conversion devices, engines, or machines. Such devices can only be driven by convertible energy, and have a theoretical maximum efficiency when...

  by the logarithm of the action
Action (physics)
In physics, action is an attribute of the dynamics of a physical system. It is a mathematical functional which takes the trajectory, also called path or history, of the system as its argument and has a real number as its result. Action has the dimension of energy × time, and its unit is...

 (i.e.).

The importance of this theorem has been recognized by Ludwig Boltzmann
Ludwig Boltzmann
Ludwig Eduard Boltzmann was an Austrian physicist famous for his founding contributions in the fields of statistical mechanics and statistical thermodynamics...

 who saw how to apply it to macroscopic systems (i.e. multidimensional systems), in order to provide a mechanical foundation of equilibrium thermodynamics
Equilibrium thermodynamics
Equilibrium Thermodynamics is the systematic study of transformations of matter and energy in systems as they approach equilibrium. The word equilibrium implies a state of balance. Equilibrium thermodynamics, in origins, derives from analysis of the Carnot cycle. Here, typically a system, as...

. This research activity was strictly related to his formulation of the ergodic hypothesis
Ergodic hypothesis
In physics and thermodynamics, the ergodic hypothesis says that, over long periods of time, the time spent by a particle in some region of the phase space of microstates with the same energy is proportional to the volume of this region, i.e., that all accessible microstates are equiprobable over a...

.
A multidimensional version of the Helmholtz theorem, based on the ergodic theorem of George David Birkhoff
George David Birkhoff
-External links:* − from National Academies Press, by Oswald Veblen....

 is known as generalized Helmholtz theorem.
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