Cryogenic storage dewar
Encyclopedia
Vacuum flask
A vacuum flask is an insulating storage vessel which keeps its contents hotter or cooler than its surroundings. Invented by Sir James Dewar in 1892, the vacuum flask consists of two flasks, placed one within the other and joined at the neck...
used for storing cryogens (such as liquid nitrogen
Liquid nitrogen
Liquid nitrogen is nitrogen in a liquid state at a very low temperature. It is produced industrially by fractional distillation of liquid air. Liquid nitrogen is a colourless clear liquid with density of 0.807 g/mL at its boiling point and a dielectric constant of 1.4...
or liquid helium
Liquid helium
Helium exists in liquid form only at extremely low temperatures. The boiling point and critical point depend on the isotope of the helium; see the table below for values. The density of liquid helium-4 at its boiling point and 1 atmosphere is approximately 0.125 g/mL Helium-4 was first liquefied...
), whose boiling points
Boiling Points
Boiling Points is a prank reality television show, much like the format used on Candid Camera. It is broadcast on MTV in the United States. In each half-hour episode, annoying situations are set up and deliberately inflicted on one or more young adults who are unaware that they are being tested...
are much lower than room temperature
Room temperature
-Comfort levels:The American Society of Heating, Refrigerating and Air-Conditioning Engineers has listings for suggested temperatures and air flow rates in different types of buildings and different environmental circumstances. For example, a single office in a building has an occupancy ratio per...
. Cryogenic storage dewars may take several different forms including open bucket
Bucket
A bucket, also called a pail, is typically a watertight, vertical cylinder or truncated cone, with an open top and a flat bottom, usually attached to a semicircular carrying handle called the bail. A pail can have an open top or can have a lid....
s, flasks with loose-fitting stoppers and self-pressurising tanks. All dewars have walls constructed from two or more layers, with a high vacuum
Vacuum
In everyday usage, vacuum is a volume of space that is essentially empty of matter, such that its gaseous pressure is much less than atmospheric pressure. The word comes from the Latin term for "empty". A perfect vacuum would be one with no particles in it at all, which is impossible to achieve in...
maintained between the layers. This provides very good thermal insulation
Thermal insulation
Thermal insulation is the reduction of the effects of the various processes of heat transfer between objects in thermal contact or in range of radiative influence. Heat transfer is the transfer of thermal energy between objects of differing temperature...
between the interior and exterior of the dewar, which reduces the rate at which the contents boils away. Precautions are taken in the design of dewars to safely manage the gas which is released as the liquid slowly boils. The simplest dewars allow the gas to escape either through an open top or past a loose-fitting stopper to prevent the risk of explosion. More sophisticated dewars trap the gas above the liquid, and hold it at high pressure. This increases the boiling point of the liquid, allowing it to be stored for extended periods. Excessive vapour pressure is released automatically through safety valves. The method of decanting liquid from a dewar depends upon its design. Simple dewars may be tilted, to pour liquid from the neck. Self-pressurising designs use the gas pressure in the top of the dewar to force the liquid upward through a pipe leading to the neck.
Safety
Cryogens present several safety hazards and storage vessels are designed to reduce the associated risk. Firstly, no dewar can provide perfect thermal insulation and the cryogenic liquid slowly boils away, which yields an enormous quantity of gas. For example, the expansion ratioExpansion ratio
The expansion ratio of a liquefied and cryogenic substance is the volume of a given amount of that substance in liquid form compared to the volume of the same amount of substance in gaseous form, at a given temperature and pressure....
of cryogenic argon
Argon
Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide...
from the boiling point
Boiling point
The boiling point of an element or a substance is the temperature at which the vapor pressure of the liquid equals the environmental pressure surrounding the liquid....
to ambient is 1 to 847, liquid hydrogen
Liquid hydrogen
Liquid hydrogen is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form.To exist as a liquid, H2 must be pressurized above and cooled below hydrogen's Critical point. However, for hydrogen to be in a full liquid state without boiling off, it needs to be...
1 to 851, liquid helium
Liquid helium
Helium exists in liquid form only at extremely low temperatures. The boiling point and critical point depend on the isotope of the helium; see the table below for values. The density of liquid helium-4 at its boiling point and 1 atmosphere is approximately 0.125 g/mL Helium-4 was first liquefied...
1 to 757, liquid nitrogen
Liquid nitrogen
Liquid nitrogen is nitrogen in a liquid state at a very low temperature. It is produced industrially by fractional distillation of liquid air. Liquid nitrogen is a colourless clear liquid with density of 0.807 g/mL at its boiling point and a dielectric constant of 1.4...
1 to 696, and liquid oxygen
Liquid oxygen
Liquid oxygen — abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries — is one of the physical forms of elemental oxygen.-Physical properties:...
1 to 860; Neon
Neon
Neon is the chemical element that has the symbol Ne and an atomic number of 10. Although a very common element in the universe, it is rare on Earth. A colorless, inert noble gas under standard conditions, neon gives a distinct reddish-orange glow when used in either low-voltage neon glow lamps or...
has the highest expansion ratio with 1 to 1438. In dewars with an open top, the gas simply escapes into the surrounding area. However, very high pressures can build up inside sealed dewars, and precautions are taken to minimise the risk of explosion. One or more pressure-relief valves allow gas to vent away from the dewar whenever the pressure becomes excessively large. In an incident in 2006 at Texas A&M University
Texas A&M University
Texas A&M University is a coeducational public research university located in College Station, Texas . It is the flagship institution of the Texas A&M University System. The sixth-largest university in the United States, A&M's enrollment for Fall 2011 was over 50,000 for the first time in school...
, the pressure-relief devices of a tank of liquid nitrogen were sealed with brass plugs. As a result, the tank failed catastrophically, and exploded.
Air can be cryopump
Cryopump
A cryopump is a vacuum pump that traps gases and vapours by condensing them on a cold surface. They are only effective on some gases, depending on the freezing and boiling points of the gas relative to the cryopump's temperature...
ed into a dewar if it is left open for a prolonged period. This leads to the formation of ice
Water ice
Water ice could refer to:# Ice formed by water # Italian ice, fruit flavoured deserts, sorbet# Ice made from flowing water in Ice climbing...
on the inside of the dewar. In self-pressurising dewars, this is extremely dangerous as the pressure-relief valves can become blocked leading to the risk of explosion.
The gas escaping from a dewar can gradually displace the oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
from the air in the surrounding area, which presents an asphyxiation hazard. Users are trained to only store dewars in a well-ventilated area and before transporting dewars in an elevator
Elevator
An elevator is a type of vertical transport equipment that efficiently moves people or goods between floors of a building, vessel or other structures...
, the excess gas pressure is vented away and the dewars are sent unaccompanied to their destination.