Chromium nitrate
Encyclopedia
Chromium nitrate describes several inorganic compound
Inorganic compound
Inorganic compounds have traditionally been considered to be of inanimate, non-biological origin. In contrast, organic compounds have an explicit biological origin. However, over the past century, the classification of inorganic vs organic compounds has become less important to scientists,...

s consisting of chromium, nitrate and varying amounts of water. Most common is the dark violet hydrated solid, but an anhydrous
Anhydrous
As a general term, a substance is said to be anhydrous if it contains no water. The way of achieving the anhydrous form differs from one substance to another...

 green form is also known. These compounds are not important commercially but are commonly found in academic laboratories.

Structure

The relatively complicated formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 - [Cr(H2O)6](NO3)3•3H2O - highlights the complicated structure of this material. The chromium centers are bound to six water ligand
Ligand
In coordination chemistry, a ligand is an ion or molecule that binds to a central metal atom to form a coordination complex. The bonding between metal and ligand generally involves formal donation of one or more of the ligand's electron pairs. The nature of metal-ligand bonding can range from...

s, and the remaining volume of the solid is occupied by three nitrate anions and three molecules of water of crystallization
Water of crystallization
In crystallography, water of crystallization or water of hydration or crystallization water is water that occurs in crystals. Water of crystallization is necessary for the maintenance of crystalline properties, but capable of being removed by sufficient heat...

. Such complicated formulas typify hydrate
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....

d metal salts.

Properties

The anhydrous
Anhydrous
As a general term, a substance is said to be anhydrous if it contains no water. The way of achieving the anhydrous form differs from one substance to another...

 salt forms green crystals and very soluble in water. At 100 °C it decomposes. The red-violet hydrate is highly soluble in water. Chromium nitrate is used in the production of alkali metal
Alkali metal
The alkali metals are a series of chemical elements in the periodic table. In the modern IUPAC nomenclature, the alkali metals comprise the group 1 elements, along with hydrogen. The alkali metals are lithium , sodium , potassium , rubidium , caesium , and francium...

-free catalysts and in pickling
Pickling (metal)
Tarnision is a metal surface treatment used to remove impurities, such as stains, inorganic contaminants, rust or scale from ferrous metals, copper, and aluminum alloys. A solution called Tarnision liquor, which contains strong acids, is used to remove the surface impurities...

.

Preparation

Chromium nitrate can be prepared by dissolving chromium oxide
Chromium oxide
Chromium oxide may refer to:* Chromium oxide, CrO* Chromium oxide, Cr2O3* Chromium dioxide , CrO2* Chromium trioxide , CrO3* Chromium oxide peroxide, CrO5* Mixed valence species, such as Cr8O21...

 in nitric acid
Nitric acid
Nitric acid , also known as aqua fortis and spirit of nitre, is a highly corrosive and toxic strong acid.Colorless when pure, older samples tend to acquire a yellow cast due to the accumulation of oxides of nitrogen. If the solution contains more than 86% nitric acid, it is referred to as fuming...

.
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